Abstracts

Advanced Rotorcraft Materials Technologies

Advanced Rotocraft Materials Technologies I

Advanced Erosion Resistant Coatings for the V-22 Shaft Driven Compressor Impeller
M. McFarland1, J. Brown1, D. Alexander2, (1)Acree Technologies Incorporated, Concord, CA, (2)Patuxent Naval Air Station, Patuxent River, MD

The Shaft Driven Compressor (SDC) in the V-22 rotorcraft is a critical component that provides oxygen for the crew and inert gas for the fuel system to prevent explosions. Currently, the impellers in the SDC are experiencing significant levels of erosion due to particle impact from sand and dust and are wearing out much too quickly. Impellers are meeting only about 15% of expected design life. A very hard ceramic multilayer coating has been developed that significantly reduces impeller erosion, extending its life. Tests have shown that the coating has the potential to extend the life of the impeller to ~3,000 hours, exceeding specifications, and significantly reducing maintenance and replacement costs. The coating is thin, so dimensional tolerances are not affected. Because of its hardness, toughness and ease of application, this coating can be used on virtually any component suffering from erosion or wear. Complex shapes like impellers can be coated because the process is non-line-of-sight.

Improving Damage Limit of Ti-tubing for Hydraulic Systems
T. Butler1, C. Lei2, R. Taylor2, M. Yu2, (1)Ormond, LLC, Auburn, WA, (2)NAVAIR-Naval Air Systems Command, Patuxent River, MD

Titanium tubes are widely used for hydraulic lines due to their high strength/density ratio, high toughness and good corrosion resistance. However, the surface flaws induced during manufacturing, installation, or maintenance in the form of scratches, dents, chaffing, etc, lead to shortened fatigue life and potentially catastrophic aircraft damage.  Plus, the long lead time to acquire and increasing price of titanium affects readiness and maintainability.  An innovative surface treatment is needed to inhibit or block growth of the surface flaws.  A newly developed cavitation peening technology, which creates a high compressive residual stress layer on the surface, could be used to enhance the fatigue life of Ti-tubes.  The compressive stress stalls/eliminates the flaw growth, in turn improving the fatigue life of hydraulic systems.  Preliminary test data show that a cavitation peened tube passed 2.5 times tube design life. 

Metal Machining Process Improvements via Physics-Based Modeling
T. Marusich, Third Wave Systems, Minneapolis, MN

Machined monolithic aircraft components–components machined from one solid plate or forged structure–are the foundation for improved performance, and cost and part count reduction in the airframe industry. Components machined from plate are pervasive throughout the aircraft industry and commonly have start-to-finish machining weight ratios of 20:1 to 50:1, resulting in complicated CNC toolpaths and long cycle times. Migration to new and more advanced alloys to provide performance benefits is often at the expense of manufacturing time and cost. An emerging opportunity exists to dramatically improve CNC metal machining via physics-based optimization of both new and existing CNC part programs. Physic-based modeling allows detailed analysis of cutting tool/workpiece interaction for improved cutter design and thermal management of titanium and high temperature alloys. Physics-based modeling also allows analysis of forces, temperatures and tool stresses over entire part programs, quickly identifying opportunities for cycle time reduction and potential areas of part damage. In this paper, an approach for physics-based modeling of both detailed tool/workpiece interaction and CNC toolpath analysis will be detailed. An overview of modeling capabilities will be shown along with application to typical aerospace components.

The High-Performance Machining of Advanced Materials
J. C. Rozzi, J. K. Sanders, Creare Incorporated, Hanover, NH

Aerospace components are notoriously expensive and difficult to machine.  The high strength of advanced materials causes a significant temperature rise at the cutting edge, resulting in premature cutting tool failure and poor surface quality. For advanced materials, reducing the temperature at the cutting edge is the key element to increasing tool life and processing speed, with the concomitant decrease in processing cost.  Current methods to reduce the temperature of the cutting edge have only been moderately successful.  At Creare, we have developed a novel Indirect Cooling System that enables prolonged tool life and increased the processing speed for various conventional and advanced materials, when compared to conventional flood cooling.   We have demonstrated the feasibility of our system for turning and milling on numerous aerospace materials.  In addition, we are also focused on integrating our ICS into the real-world manufacturing environment.  Our presentation will describe our system, its potential integration with conventional machining operations, and the results of machining experiments for various materials.

Cold Spray Repair of Mg Gear Boxes
R. Kestler, NAVAIR, Cherry Point, NC

Navy helicopter magnesium gearbox housings experience a harsh corrosion environment leading to pitting damage of the magnesium substrates.  Most of the corrosion occurs on mounting surfaces, supports and lugs where dissimilar metal is in contact with the magnesium substrates.  NAVAIR and Fleet Readiness Center East are involved in efforts to evaluate the use of aluminum and/or aluminum alloy coatings to repair corrosion damaged magnesium substrates.  These efforts target an emerging technology called cold spray.  Cold spray is a supersonic particle deposition process by which powder particles are deposited by means of ballistic impingement upon a suitable substrate at supersonic velocities to form a coating or free-standing structure.  Fundamentals of the cold spray process, repair opportunities, project description and initial test results will be presented.    

Advanced Rotocraft Materials Technologies II

Joint Rotocraft RDAT&E Center: Research and Development
W. E. Frazier, M. Yu, S. Verma, D. Isleib, NAVAIR-Naval Air Systems Command, Patuxent River, MD

The Base Realignment and Closure (BRAC) law of 2005 directed the establishment of a Joint Rotorcraft RDAT&E Center at the Naval Air Systems Command (NAVAIR) Patuxent River, MD.  The purpose was to both consolidate resources and provide enhanced focus on rotorcraft research, development, acquisition, test and evaluation.  The establishment of this Center provides a unique opportunity for the Navy to shape its R&D infrastructure (people, labs, processes, and external interactions) to better support the war fighter with more capable, durable, and lower cost rotorcraft. 

This paper describes the 2013 vision state for the Rotorcraft Center of Excellence (RCOE) and the steps being taken to fully implement the Center.   Importantly, the unique operational requirements of the Navy’s rotorcraft which dictate the design, materials, and technologies used are expounded upon.  Critical technology needs are described and examples of salient rotorcraft technology solutions that are being developed and transitioned are provided.

Development of a New High-Performance Gas Carburizable Gear Steel
J. Sebastian, J. Wright, QuesTek Innovations, Evanston, IL

QuesTek Innovations, in conjunction with a major aerospace rotorcraft manufacturer, has utilized its computational Materials by Design® technology to develop a new high-performance gas carburizable gear steel. Initial prototype alloy compositions have been refined, and the final composition for the new steel has been produced by premium processing methods at full industrial ingot scale (10,000 lb.). The new gear steel, based on martensitic matrix and secondary hardening microstructural concepts, exhibits core and case properties equivalent or superior to current high-performance gas carburizable gear steels (including Pyrowear X53). The secondary hardening characteristics of the new steel impart superior temperature resistance relative to current steels. Surface processing (including gas carburization and shot peening processing) has been demonstrated in conjunction with QuesTek’s aerospace partner. Characteristics of the new alloy will be compared with those from other commercial high-performance gear steels (including QuesTek’s Ferrium C61).

High Pressure Combustion Driven Powder Compaction and Materials Aspects for Power Transmission Components
K. Nagarathnam, D. Trostle, D. Massey, UTRON Inc, Manassas, VA

An overview of the scientific and technological aspects in the materials development and manufacturing strategies of UTRON’s High Pressure Combustion Driven Powder Compaction (CDC) technology (Fig. 1) will be provided. Key results of the CDC processed ferrous alloys (e.g., Pyrowear 53) and nanocomposite alloys (Figs. 2 and 3) for potential power transmission rotorcraft component materials development and applications will be discussed. Examples of other materials developed by CDC at UTRON such as copper, stainless steel, refractory materials (W, Mo and TZM), niobium, NanoSiC, Nano BoronCarbide will be presented and the significant processing, materials performance and cost-effective manufacturing advantages will be highlighted. Some of the unique advantages of CDC include high densities,(Fig. 4)  near net or net-shaping, (Fig. 3) improved surface finish/quality, suitability for simple/complex geometries, synthesis of single as well as multilayered micro/nano materials, milliseconds of compaction process time, little or no post-machining, and process flexibility. The materials characterization strategies include geometry control, process optimization, sintering/heat treatment responses, structure/property characteristics such as geometrical, physical properties, select microstructures and mechanical properties will be presented. Under optimum conditions, the CDC ferrous alloy samples processed at much higher compaction pressures responded well for vacuum carburization with the result of wear resistant surface hardened fine microstructures (Fig. 5) and surface hardnesses as high as Rc 66-69 with deeper case depths (20 to 25 mils).  Anticipated applications of CDC compaction include power train components, high temperature propulsion components, refractory x-ray targets, laser optical mirrors, vacuum seals, accelerator/RF microwave components, high temperature nozzle liner parts/heat sinks, advanced propulsion system components for missile defense, advanced high density magnets and high performance engine parts.

Microstructure-Properties of Cast Alloy Ti-5Al-5Mo-5V-3Cr for Airframe Structures
E. Y. Chen1, L. W. Weihmuller2, D. R. Bice1, G. D. Hall2, W. A. Thomas2, (1)Transition45 Technologies, Inc., Orange, CA, (2)Bell Helicopter Textron, Hurst, TX

Alloy Ti-5Al-5Mo-5V-3Cr-0.5Fe (Ti-5553) is an emerging high-strength titanium alloy with improved static mechanical properties compared with the industry workhorse Ti-6Al-4V.  Studies to date have shown that this material also has comparable or better fatigue properties to steel and Ti-6Al-4V, respectively, thus could be a replacement candidate for these alloys to achieve weight savings and/or enhanced durability.  This potential weight saving can be especially advantageous for rotorcraft where forged steel components can be replaced by a titanium alloy.  This presentation reviews work conducted on characterizing the microstructure-properties of Ti-5553 in the cast form.  Mechanical properties covered here include tensile, toughness, and fatigue behavior for microstructures achieved under different thermo-mechanical processing conditions.  The results show outstanding strength and fatigue properties relative to both wrought and cast Ti-6Al-4V.  These results will be discussed in light of potential applicability to naval airframe structures that have requirements for such alloys for current and next generation aircraft systems.  This work was supported by the Naval Air Warfare Center.

Development of Slurry Resistant Materials by Laser Cladding
R. Kovacevic1, E. Yarrapareddy2, P. Smith3, (1)Southern Methodist University, Dallas, TX, (2)Laser Cladding Services. Ltd., Houston, TX, (3)US Army Research Laboratory (ARL), Aberdeen Proving Grounds, MD

SMU’s research team in cooperation with ARL has been developing an advanced manufacturing technology that uses directed energy in the form of photons, electrons, electric arc, and plasma arc to “grow” or “print” metallic components via a process known as direct metal deposition (DMD), near-net-shape, solid free-form or additive manufacturing.  The result of this work is the recently developed prototype of multi fabrication (MultiFab) system for rapid manufacturing and repair for which was issued an US Patent No. 7,020,539 on March 28th, 2006.  A number of additive operations based on laser powder cladding, Gas Metal Arc Welding, Gas Tungsten Arc Welding, micro Gas Tungsten Arc Welding and micro-plasma powder cladding, combined with a number of multi-axis subtractive operations (milling, drilling, turning) are performed using a single set-up on a single PC-based, CNC-controlled production platform.  The developed laser-based direct metal deposition system is used to synthesize a slurry resistant material.  

        There is a growing demand for high performance material systems characterized with superior properties in erosion, abrasion, and heat resistance.  Recently developed nano-based material systems have shown such superior properties.  However, very limited research and development work has been done on studying their behavior in applications that range from drilling tools for oil excavation to medical implants. 

        Our newest result (Fig. 1) shows that commercially available nickel-tungsten carbide 60 (Ni-Tung 60) reinforced by WC-nano sized particles in the concentration of up to 5% has improved the slurry erosion resistance by about 25% with respect to non-reinforced monolithic Ni-Tung 60.  The WC- nano sized particles together with WC-micro sized particles are uniformly distributed throughout the Ni-matrix resulting in an increase of the harder phase surface resistant to erosion and synthesized with the laser-based direct metal deposition process.

Tunable Energy Management Using Magnetorheological Fluids
O. Vazquez1, N. M. Wereley2, L. (. Ahure3, (1)F3 Engineering, Paterson, NJ, (2)University of Maryland, College Park, College Park, MD, (3)University of Maryland, College Park, MD

2008 AEROMAT Conference
Rotorcraft M&P program
Presentation Abstract

 Tunable Energy Management Using Magnetorheological Fluids

 Odilo Vazquez, CTO
F3 Engineering

 Amy Ahure, Norman M. Wereley
Dept. of Aerospace Engineering, University of Maryland College Park

 F3 Engineering develops application-specific systems using magnetorheological fluid (MRF) technology for mitigating the effects of shock and vibration.  The F3 systems are typically used to protect personnel and equipment in mission-critical situations and are able to manage the forces even under conditions when both shock and vibration occur simultaneously.  The system responds in “real-time” without input from an operator.  Typical response times are less than one millisecond.
The MRF, a type of “smart” fluid, is comprised of micrometer-sized ferrous particles suspended in a carrier fluid.   When subjected to a magnetic field, the particles orient in such a way as to change the rheological properties of the fluid.  The system has the capability of controlling the yield stress of the fluid by modulating the field intensity.  The resultant effect is that the force transmitted by the fluid can be controlled precisely by the electromagnetic field.

The F3 MRF “tunable” energy-management system includes custom modules:

F3 has successfully demonstrated the practicality of this technology in the development of an engine mount for the US Navy’s carrier-based E2C Hawkeye aircraft and the development of a steering damper for high-performance motorcycles.  Throughout the design and development stages, F3 continually monitors risk factors using the DoD matrix.
 

Advanced Rotocraft Materials Technologies III

Sikorsky Survivable Affordable Repairable Airframe Program (SARAP) Virtual Prototype and Validation (VPV) Update
T. Carstensen, Sikorsky Aircraft, Stratford, CT

The Survivable Affordable Repairable Airframe Program (SARAP) Virtual Prototype and Validation (VPV) Program is a multi year cooperative agreement between Sikorsky Aircraft Corporation and the U.S. Army Applied Aviation Technical Directorate (AATD) to validate technology advances in design processes, structural efficiency, crashworthiness, materials and manufacturing processes, and repairability of rotorcraft airframe structures. Specific objectives of the SARAP VPV program include a 25% weight reduction, a 40% recurring and 40% non-recurring cost reduction, while reducing overall development time, maintaining or improving crashworthiness, and field repairability of the structure as compared to baseline designs such as the UH-60.  To achieve these aggressive program goals a number of number new design, analysis, and materials, and process technologies have been evaluated. 

 The SARAP VPV program is divided into a number of major task efforts, which include:

 ·        Development of Technology Baselines (UH-60 cabin and H-53 center fuselage)
·        Technology Development/Refinement (Design processes, sensor based technologies, design concepts, materials and processes.)
·        Virtual Technology Designs (UH-60 cabin and H-53 center fuselage)
·        Design, Fabrication, and Testing a Technology Demonstration Article (UH-60 cabin section) 

 This presentation will include an update on the overall Sikorsky SARAP VPV program approach with specific emphasis on an overview of the major technologies evaluated, the design of a virtual prototype, the design and manufacture of the technology validation article, and program metric validation approach.

 

Development and Qualification of Composite Tail Rotor Drive Shaft for the UH-60M
J. Garhart, Sikorsky Aircraft, Seymour, CT

An overview of the development and qualification of a carbon fiber composite drive shaft system is presented as a summary of the design approach, material characterization and article test.  As part of the UH-60M upgrade program, weight reductions have been achieved through the implementation of composite materials for airframe and dynamic systems applications.  The introduction of an all composite tailcone precipitated the requirement for a compatible composite tail rotor drive shaft to provide a suitably matched coefficient of thermal expansion.  Improvements in manufacturing technology in recent years have enabled the expansion of composite laminates into the domain of dynamic components with critical load and precision balance requirements.  This effort utilized proven manufacturing methods to produce a composite structure with highly controlled properties to successfully replace the legacy metallic component.  Triaxial braid architecture was selected as the structural reinforcement for the design to address the components physical, mechanical and ballistic requirements.  Resin transfer molding was chosen as the manufacturing method using CYCOM 890 resin to the meet stringent dimensional tolerances of a dynamic component.  Component qualification testing was conducted to ensure that the dynamic response, mechanical properties and ballistic tolerance of the shaft met the existing system requirements.  This research was partially funded by Army ManTech under contract No. DAAH23-2-C-R002.  The U.S. Government is authorized to reproduce and distribute reprints for Government purposes notwithstanding any copyright notation herein.  The views and conclusions contained in this document are those of the authors and should not be interpreted as representing the official policies, either expressed or implied of the Army ManTech office or the U.S. Government.

Near Net Shape Formed NiTi-Based Shape Memory Alloy Actuators
R. W. Smith1, J. Mabe2, R. T. Ruggeri2, R. D. Noebe3, M. Taya4, M. Yu5, E. Rosenzweig6, (1)Materials Resources International, Lansdale, PA, (2)The Boeing Company, Seattle, WA, (3)NASA Glenn Research Center, Cleveland, OH, (4)University of Washington, Center for Intelligent Materials and Systems, Seatlle, WA, (5)NAVAIR-Naval Air Systems Command, Patuxent River, MD, (6)Naval Air System Command, PAX River, MD

The presentation will report on the viability of the Vacuum Plasma Sprayed (VPS) process as a near net shape forming process for producing NiTi (NiTinol) and higer transition temperature NiTiPd actuators. The shape memory properties of VPS deposited NiTi (Nitinol-55 type) powders will be reported and their shape memory behavior will be presented. Metallurgical structures and x-ray diffraction (XRD) phase analysis will make structure comparisons to conventionally cast and wrought Nitinol 55. Shape memory transition temperatures as measured by differential scanning calorimetry (DSC) and loaded cantilever beam testing will also be reported. Actuator performance actuator tube testing of VPS NiTi materials will be shown as comparable to cast and wrought Nitinol 55 actuator tubes.

Improved Dimensional Stability and Ductility of TiNiPd Shape Memory Alloys after Severe Plastic Deformation
I. Karaman1, K. C. Atli1, M. Haouaoui1, C. J. Yu2, (1)Texas A&M University, College Station, TX, (2)NAVAIR-Naval Air Systems Command, Patuxent River, MD

NiTi alloys are ideal for actuator applications in automotive, aeronautics and medicine due to their extraordinary properties such as superelasticity, shape memory, low weight, and high work output. Nevertheless, their transformation temperatures are well below 100°C, restricting their use to low temperature applications. Hence, there is an urgent need to develop high temperature shape memory alloys (HTSMA). TiNiPd alloys have attracted considerable interest as HTSMA since their martensitic transformation temperatures can be varied from room temperature up to 525°C. However, they suffer from embrittlement due to the second phase particles that contain predominantly titanium. In addition, even though the shape memory response of TiNiPd alloys is fairly stable at room temperature, it deteriorates with increasing temperature due to extensive plastic strain accumulation as a result of the decrease in critical shear stress for slip with temperature.

 In this study, we aim to increase the critical stress for slip (CSS) in NiTiPd alloys by refining the grain size to nanometer range via a severe plastic deformation technique called equal channel angular extrusion (ECAE). Two TiNiPd alloys were ECAE processed at temperatures as low as 400°C. The microstructural evolution of the alloys was monitored using Scanning and Transmission Electron Microscopy. Isothermal monotonic and isobaric thermal cyclic experiments were conducted to evaluate the effect of ECAE-induced microstructural changes on the functional properties. We have observed considerable improvement in thermal cyclic and dimensional stability after ECAE which can be attributed to the increase in CSS. Transmission electron microscopy observations revealed that this improvement is caused by ultrafine-scale grains on the order of few hundred nanometers. ECAE also enhances the ductility of the TiNiPd shape memory alloys by breaking up the Ti-rich second phase particles during processing. It has been determined that the fracture toughness of the TiNiPd alloys was increased after ECAE process.

Design of an Inchworm Actuator Based on Ferromagnetic Shape Memory Alloy Composite
Y. Liang1, M. Taya1, J. Q. Xiao2, G. Xiao3, (1)University of Washington, Center for Intelligent Materials and Systems, Seatlle, WA, (2)University of Delaware, Newark, DE, (3)Micro Magnetics, Inc., Fall River, MA

Ferromagnetic shape memory alloys (FSMAs) have been studied for possible applications of fast responsive and high power, yet light weight actuators controlled by magnetic field. There are three approaches that have been proposed in the FSMA research community, (1) martensite variant mechanism by applied (constant) magnetic field (variant rearrangement mechanism used by the others) (2) magnetic (H) field induced phase transformation and (3) hybrid mechanism controlled by applied magnetic field gradient. We have identified that the third approach, hybrid mechanism, can produce large force and reasonably large stroke with fast response because it can be driven by a compact electromagnet with high-applied magnetic field gradient, providing a large stress capability, and reasonably large strain. Therefore, it is adopted in the present design of the inchworm actuator. The hybrid mechanism is based on the stress-induced martensitic phase transformation produced by applied magnetic field gradient, thus enhancing the displacement, as the stiffness of shape memory alloy reduces due to the martensitic phase transformation. Despite the promising performance of Fe-Pd FSMA system by the hybrid mechanism, the price of Pd is very expensive. One of the alternative FSMA systems is a ferromagnetic shape memory alloy composite that consists of a ferromagnetic material and a superelastic grade shape memory alloy. The function of the former is to introduce a large magnetic force by the hybrid mechanism, while that of the latter is to sustain large stress and induce larger strain. We have designed and fabricated the inchworm actuator based on the FSMA composite and the hybrid mechanism. The inchworm actuator is made of two sets of electromagnet systems, FSMA composite membranes and clutch systems. The actuator can provide moderate output force and very large two-way displacement achieved by the inchworm mechanism which accumulates many small strokes. The inchworm mechanism is successfully demonstrated by the clutch system driven by the FSMA composite membrane. Our prototype inchworm actuator succesfully produces 30N force and 65mm/s stroke speed. It is noted that the stroke of this inchworm actuator based on FSMA composite can be easily increased from the current 500 mm as far as the center bar is increased and the inchworm motions are stably designed with clutch system.

Thermoplastic Rapid Prototyping for Flightworthy Rotocraft Components
K. A. Boszak, Bell Helicopter Textron Inc., Hurst, TX

Rapid prototyping offers many advantages that aid in rotorcraft component design and manufacturing.  One of the most-promising rapid prototyping techniques, selective laser sintering, has undergone advancements that have enabled rapid prototyping to evolve into a technology capable of part manufacturing.  This fabrication technique allows for parts to be fabricated from a CAD solid model and hence does not require a drawing, production interpretation, or a tool.  A finely powdered material is solidified layer by layer using a high power laser until the part is complete.  Advances in the thermal stability of laser sintering equipment have allowed for improved reliability and repeatability of production builds.  In addition, optimizations of materials and equipment parameters have improved the Z-direction properties and have thus improved the overall mechanical integrity of parts fabricated.  As a result, selective laser sintering has shown tremendous promise for use in a wide array of applications including functional prototypes, iterative design, tooling, and flightworthy production parts.

One major benefit to rapid prototyping is that it allows an actual part to be produced from a 3D model in as little as a few days.  This schedule reduction is critical for both design needs and for production.  Another benefit is the time/cost savings for tooling, which are substantial for limited production and relatively low volume unique products such as rotorcraft.  Additionally, rapid prototyping for manufacturing allows parts to be designed for function instead of being designed for manufacturability.  Complex geometry parts can be built making it is possible to reduce part count for an assembly.

This presentation provides an overview of selective laser sintering, discusses the benefits and limitations of this technology, examines what has been done to qualify the materials and processes for flightworthy applications, and defines the direction that this industry seems to be proceeding regarding future applications and materials.

Affordable Structures/Low-Cost Manufacturing

Roadmapping and Design Concepts

Space Exploration Systems: A Technology Pull for Structural and Multifunctional Materials
W. K. Belvin, NASA Langley Research Center, Hampton, VA

NASA is in the process of developing vehicles and systems for crewed missions to low Earth orbit (replacing the Space Shuttle System), Lunar transport of crew and cargo, and long-duration Lunar surface missions.  Preliminary design studies are being used to develop system concepts and requirements for each of the major exploration elements.  For example, the Crew Exploration Vehicle (now known as Orion) completed several design analysis cycles in 2006.  In 2007, the Lunar Lander (now known as Altair) began system level conceptual design of the ascent and descent stages.  For each of these design efforts, a Structures and Mechanisms Subsystem (SMS) team was responsible for investigating and selecting preliminary structural load paths, structural concepts, and material systems, while interacting with other vehicle subsystems to insure that system level requirements and constraints were satisfied.  Rapid physics-based modeling of vehicle loads and structural concepts enabled accurate prediction of the vehicle’s strength, stiffness, stability, and mass.  To optimize the vehicle performance, the SMS team evaluated advanced material systems and alternative structural concepts.  For example, potential Orion crew module mass savings were identified if a composite material system was used for the pressure vessel instead of Al-Li metallic.  Similarly, the Altair lander was found to be severely mass constrained.  Lightweight, environmentally durable materials were identified as enabling to the Lunar mission using the current architecture. This presentation will briefly review the current space exploration architecture and the major elements needed for initial Lunar missions.  Experience from the SMS team is used to identify key design drivers and constraints for these vehicles. The need for advanced structural and multifunctional material systems with high specific strength and stiffness will be highlighted.

Composite and Hybrid Structures for Aerospace Applications
J. Baur, Wright-Patterson AFB, Wright-Patterson AFB, OH

Traditionally, materials for aircraft and satellites structures were high-performance metals, ceramics, or polymer matrix composites (PMCs). Occasionally, these were combined at the structural level to form hybrid structures. However, spatially varying materials in order to place the right properties at the right location has the potential to avoid previous trade-offs in properties and create a new generation of structural hybrids materials. While the full promise of these materials has yet to be realized, many of the improved property trade-offs include combinations of the high specific stiffness of PMCs, electrical and thermal conductivity of metals, and high temperature and oxidative durability of ceramic materials. An example application that might benefit from such hybrid concepts is a structure that is exposed to an extreme environment of temperature, oxidation, or impinging energy on one side, but has milder conditions on the other. Due to the spatial variation in conditions, there are weight and durability benefits over simply using a single material selection based on the most stringent requirement. Hybrid solutions also become important in optimizing multiple structural functions in such applications as embedded antennae, apertures, and structurally integrated devices. Even more futuristic concepts such as shape change, electromagnetic tailoring, and active thermal management seek to integrate disparate classes of materials into spatially varied, multi-scaled and bio-inspired designs that enable adaptive functions. Fundamental understanding of each component and their interfacial properties is needed. In the case of adaptive hybrids, the structure will have both spatially and time-variant properties. To accomplish this vision of hybrids structures, an integrated experimental and modeling program which looks across multiple length scales and engages activities across industry and academia is required. In this presentation, we will review the Air Force’s progress towards that goal and provide a roadmap of future direction and plans for this relatively new AFRL/RX Branch.

Developments in New Materials and Manufacturing

Alcan - SpaceX Al-Li Solutions for the Falcon Rockets
M. Niedzinski1, C. Thompson2, J. Richichi2, J. Ayers2, F. Eberl3, S. Jambu4, R. Morganti5, (1)Alcan Aerospace, Chicago, IL, (2)SpaceX, Hawthorne, CA, (3)Alcan Rhenalu, Issoire Cedex, France, (4)PECHINEY Aviatube, Montreuil-Juigné, France, (5)Spincraft Corporation, North Billerica, MA

Advances in materials and assembling technologies for launch vehicles and space structures are key aspects to reach increased payload for affordable and reliable access to space. Good weldability for friction stir and fusion welding are necessities for entirely welded tank walls and domes of  rockets. High static properties in the welded joint are needed in order to reduce wall thickness for increased weight reduction of the space vehicle structure. Good formability is essential for fabrication of complex domes.

The use of high strength and low density Al-Li alloys such as 2198 sheet and 2195 plate allows assembly of tank walls and domes by using friction stir welding in circumferential joints. These new generation alloys successfully replaced legacy alloys such as 2219 and 2014. Complementarily to the sheet material, the tank inner structure can be stiffened by using 2196 extruded stringers. The very low density 2196 material allows reaching at least 5% density reduction by reaching static properties of today’s flying 7xxx alloys.

After presentation of the main properties and features of the 2198 sheets, 2195 plate and 2196 extrusions, various examples of their application in SpaceX-Falcon rockets will be presented. Likewise some of the novel fabrication and joining technology will be discussed.

Innovative Bushed Joint Technology for Cost Effective Metallic/Composite Assembly
L. Reid1, T. H. Johnson2, (1)Fatigue Technology,, Seattle, WA, (2)Fatigue Technology, Inc., Seattle, WA

Modular aircraft demand high-speed assembly and low cost manufacturing.  Joining of major subassemblies requires close tolerance alignment and minimal/no machining during final assembly of joint components.  Lug and clevis arrangements facilitate component/assembly, removal and repair in service and are typically bushed to provide a sacrificial wear surface and a means of allowing final machining for alignment.  In composite structures they also provide a bearing surface to protect the composite laminate.

High interference expanded ForceMate bushings are rapidly/consistently installed and overcome problems associated with traditional thermal or freeze fit bushings.  Installation is accomplished by pulling an expansion mandrel through the initially clearance fit bushing.  Besides the high interference fit, the expansion induces a beneficial residual compressive stress around the bushing, which greatly enhances the fatigue life, durability and damage tolerance of the bushing installation.  In critical lug attachments such as engine pylons and landing gear ForceMate bushings have eliminated or greatly extended the inspection intervals.

Installation in highly loaded fatigue critical joints such as wing attachment, recent innovations in metal, composites and composite/metal aircraft assembly joints provide the following:

a.                   Elimination of potential fatigue damaging burrs

b.                  Off-center ream allowance

c.                   Multiple bushing installations without disassembly of the lug or joint

d.                  Protection of holes in composite structure

e.                   Close tolerance assembly of metal to composite structure such as floor beam to frame attachment

f.                    A double-flanged nested bushing arrangement

g.                   Facilitate installation of pre lubricated lined bushings

h.                   Installation of spherical bearings into bushed lugs

This paper will describe the ForceMate method and benefits, present fatigue life and durability data, as well as qualification testing providing enhancement in push-out, torque resistance, and vibration.  Discussion of innovative applications on aircraft assemblies as well as assembly and in-service cost savings will be provided.

Showing the Potential of New Material Developments and Manufacturing Process' by Means of Structural Analysis
R. De Rijck1, M. Miermeister2, A. Norman1, W. Spanjer1, J. de Kanter1, M. Lansbergen1, (1)Corus Research Development & Technology, IJmuiden, Netherlands, (2)Aleris Aluminum Koblenz GmbH, Koblenz, Germany

In the highly competitive field of aerospace-materials development it is important to show the potential of material developments and manufacturing process' by means of structural analysis. The conceptual approach composites have taken shows the possibilities of composite developments in aircraft the metal‑alloy community has neglected. The development of structural analyses tools by CRD&T alongside the development of aluminum alloys by Aleris approaches this conceptual design philosophy.
Using the structural analyses tools, concepts are evaluated comparing different material solutions. Not just showing the potential of alloys developments, also taking into account possible production advantages. One of the examples is the conceptual design of a wingbox. Using global dimensions, the wingbox loading can be evaluated for different design concepts, e.g. monolithic, built-up or CFRP solutions. At this stage different materials can be assessed showing the advantages of the Aleris alloy developments. Alloy 7081 in both T7451 and T7651 shows enormous potential for wingbox applications. Higher stresses, lower weight or cost can then be the design driver. These concepts show high weight savings (15%) without a major increase in cost for 7081-T7451 as an integral lower wing solution. If a higher stressed lower wing skin is required, the 7081-T7451 alloy can offer great damage tolerance solutions as a spar alloy.
Similar conceptual steps can be taken for the fuselage, combining static and damage tolerant analysis in different concepts, e.g. riveted, bonded or welded structures. Taking into account at an early stage the production advantages solutions can offer in performance and/or cost. In competition with composites AlLi alloys are developed as a weight saving solution. The Aleris AlMgSc development provides similar results for fuselage applications with improved impact and fatigue performance with the additional advantage of cost savings by the application of innovative manufacturing methods. Several results will be shown to support these statements.

Additive Manufacturing for Superalloys – Producibility and Cost Evaluation
J. J. Moor, Pratt & Whitney, East Hartford, CT

The primary goal of this project, Additive Manufacturing for Superalloys – Producibility and Cost Evaluation, is to achieve cost and lead-time reductions of up to 50% for high-temperature static turbine engine components such as diffuser and turbine cases.  Such components are used in virtually all military and commercial engines.  The majority of these components are fabricated from either wrought or cast Inconel 718 or Waspaloy.  Each of these material forms present some common and unique issues that result in these parts being some of the most expensive found in the engine.   This program addresses the cost-driving issues through the development and implementation of additive manufacturing techniques that can be used to fabricate hardware in more cost-effective ways based on overall part and feature specific geometries.  This program was set up in a gated fashion which is split into five tasks:

 ¨        Task 1 – Concept Identification
¨        Task 2 – Feasibility Investigation
¨        Task 3 – Technical and Business Evaluation
¨        Task 4 – Testing and Validation
¨        Task 5 – Production Implementation Planning

 Currently the team is working on Task 4 which is evaluating the feasibility of additive manufacturing on representative case hardware.  The current task is targeted for completion by the end of the year. The final task (Task 5) is scheduled to run from February through May of 2008.

Recent Progress on Accounting for Residual Stress in Integrity Assessment of 3-D Structure
R. J. Bucci1, M. A. James1, D. L. Ball2, (1)Alcoa, Inc., Alcoa Center, PA, (2)Lockheed Martin Aeronautics Company, Fort Worth, TX

This talk will cover the aggressive pursuit of structural unitization and will present examples. Also, The consequence of residual stress effects in material characterization & design will be discussed in terms of:

Deficits of classic FCGA approach

Next generation FCGR testing & analysis

We will address the quantification of residual stresses and will present:

Proposed design FCGA improvements

We will conclude the presentation discussing a holistic modeling vision for residual stress from evolution in metal processing to impact on final part performance.

Emerging Materials and Processes

Emerging Materials and Processes I - Materials I

Development Of Nanocomposites For Blast Resistant, Hierarchical Structures
C. C. Ibeh1, M. Bubacz2, (1)Center For Nanocomposites & Multifunctional Materials [CNCMM], Pittsburg, KS, (2)Mercer University, Macon, GA

The Center for Nanocomposites and Multifunctional Materials [CNCMM] is currently implementing the “Multifunctional Materials For Naval Structures” project at Pittsburg State University (PSU), a multi-institutional research thrust and partnership between PSU, North Carolina A&T University and University of New Orleans, that is sponsored by the Office of Naval Research (ONR).  CNCMM’s research efforts focus on the design and development of energy absorbing and dissipating, hierarchical nanocomposite structures for blast resistant structures and ship hulls.  Designs center around nanocomposites and foam-filled honeycomb cores with 3-D/2-D facesheet laminates, and design criteria include structural integrity, toughness and flammability resistance.  Flame retardant vinyl ester resins are the choice polymeric matrices for cost-effectiveness; epoxy resins are used as benchmark for this study.  Nanoparticles used for this study include nanoclay, silicon carbide and carbon nanofibers.  Infusion of nanoparticles into polymer matrices is achieved via sonication.  Nanocomposites and foam-impregnation of 3-D fabrics and honeycomb cores is carried out via compression molding and vacuum assisted hand lay-up (VAHLUP).  Research efforts are carried out by student-faculty/staff teams that are sponsored by CNCMM as part of its workforce and economic development mission.  In-lab produced nanocomposites are characterized for mechanical, nano-structural and flammability resistance properties using a Universal Testing Machine, XRD/AFM and Cone Calorimetry respectively.  Developed nanocomposites exhibit synergies in specific mechanical and flammability resistance properties.  Cone calorimetry data show reduced peak heat release rate (PHRR), effective heat of combustion (EHC) and smoke density.

Effect of Addition of Ni and Ag on Cu-CNT Composite's Electrical Conductivity
S. Amruthaluri1, N. D. Munroe1, P. K. S. Gill2, W. Haider1, (1)Florida International University, Miami, FL, (2)Florida International University, miami, FL

Copper-Carbon nanotube (Cu-CNT) composites are of great interest due to their wide range of applications in electrical appliances. In recent years the researchers have shown lot of interest in this composite. Powder metallurgy technique was used to prepare Cu-CNT composite with addition of Silver (Ag) and Nickel (Ni). Different compositions were prepared for comparative analysis. Enhancement in electrical conductivity of this composite was observed by using four probe method. Scanning Electron Microscopy (SEM) and X-ray mapping showed homogenous mixing of CNTs in the composite. This composite overcomes the limitations of interfacial bonding in Cu-CNT matrix and homogenous distribution of CNTs.  Our investigation demonstrated that addition of Ag and Ni resinates changes the morphology of the composite by increasing the interfacial bonding between Cu and CNT.

Fibre Reinforced FeCo Alloys for the More Electric Engine
S. Godfrey1, M. Lunt2, (1)QinetiQ, Farnborough, United Kingdom, (2)DSTL, Salisbury, United Kingdom

The more electric engine concept is a world wide initiative looking to change the way electrical power is produced within a gas turbine. This design change will lead to a reduction in platform weight, a reduction in machine complexity and improved performance. One of the key components to implementing this design change is a high temperature electrical motor / generator mounted co-axially inside the engine core. This so called integrated starter generator (ISG) will operate at high temperatures and stresses, which places demands on the magnetic materials used to construct the motor. In terms of magnetic performance, FeCo alloys appear to be prime materials for this application. They offer high magnetic saturation, high curie temperatures and low magnetic losses. The main problem with these materials is that they lack the mechanical strength necessary for use in high temperature rotating applications. This paper summarises work to produce a high strength metal matrix composite (MMC) FeCo system. Technology based on reinforcing titanium alloys with SiC fibres has been developed and adapted. The FeCo matrix is considerably more reactive than titanium systems and therefore barrier layer coatings on the fibre have been developed to control the fibre-matrix reactions. The composite material has excellent mechanical properties, in particular creep and low cycle fatigue at temperatures up-to 500°C.

Microstructural Analysis of Cu-Cr-MWCNT Composite
W. Haider1, P. K. S. Gill2, N. D. Munroe1, S. Amruthaluri1, (1)Florida International University, Miami, FL, (2)Florida International University, miami, FL

Chromium-MWCNT composite is anticipated to find vast applications in the aerospace industry due to their enhanced electrical conductivity and mechanical properties. In this investigation Cu-Cr-MWCNT composites were prepared via a powder metallurgical technique by varying the composition of MWCNT in order to determine the optimum composition for the desired electrical and mechanical properties. The microstructure of the composites was examined by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Raman Spectroscopy and Transmission Electron Microscopy (TEM).

Results indicated the formation of varying amounts of chromium carbide on the surface of MWCNTs. SEM analysis revealed an increase in diameter of the CNT’s, due to the formation of carbide on the surface, even though some of the outer walls of the MWCNTs were removed during fabrication. The chemical composition and structural changes during manufacturing of these composites were assessed with the help of Raman spectroscopy.

Minimizing the Adhesion of Ice Using Silicone Based Coatings
S. Sivas, B. Burkitt, R. Thomaier, NuSil Technology, Carpinteria, CA

Ice buildup on aerodynamic surfaces and aircraft engines is the most serious weather hazard effecting aircraft performance and safety.  Several current strategies to eliminate or reduce ice buildup such as chemical or thermal deicing cause tremendous loss in flight delays and cancellations. Under extreme circumstances these solutions may not be probable due to time constraints or location and may compromise or limit flight mission capabilities. A more practical and economical choice for aircraft manufactures is to use a material or apply a coating that reduces ice adhesion to the surface. In order to evaluate the effectiveness of these types of materials, the Department of the Army, Engineer Research and Development Center, Cold Regions Research and Engineering Laboratory (CRREL) in Hanover, NH, U.S., has designed a test to measure the adhesion strength of ice to surfaces. Under the direction of Pratt & Whitney several different commercially available ice-phobic coatings and materials were tested and compared, including the silicone based ice-phobic coating R-2180. The results showed that several of these materials perform better than the industry standard ice-phobic material, Teflon®, while R-2180 was the most favorable of all the coatings tested. In addition R-2180 continued to perform better than Teflon® after simulated exposure to extreme environmental conditions, including physical wear, thermal cycling, humidity cycling, and salt spray.  Combined with specular gloss readings and contact angle measurements used to evaluate the smoothness of the silicone based coating, ice adhesion testing reveals that although ice-phobic materials do not eliminate ice formation under static conditions, the smooth surface creates a complex interaction with the ice dramatically reducing the energy required to remove ice buildup.

Nonlinear Structural Evaluation of Electron Beam Freeform Fabrication of Stiffened Panels
A. Brickler1, E. W. Nelson2, R. Kapania3, E. K. Hoffman4, (1)University of Maryland, Hampton, VA, (2)Virginia Tech, Hampton, VA, (3)Virginia Polytechnic Institute and State University, Blacksburg, VA, (4)NASA Langley Research Center, Hampton, VA

The goal of this study is to validate advanced fabrication techniques for aircraft components. The test specimens are aluminum alloy blade-stiffened panels which represent a component of skin-stiffener compression panels used in aircraft fuselage and wings. The four different fabrication methods tested and compared are a stiffener riveted onto the skin, an integral stiffener machined from plate, a stiffener friction stir welded onto the skin, and a stiffener built by electron beam freeform fabrication (EBF3). To validate the fabrication techniques, first the buckling characteristics are determined with compression tests and analysis. Then the results for the panels made with the new technique of EBF3 are compared with the results for the panels made with the more proven manufacturing methods. All panels failed in global buckling. The results show that the integrally stiffened panels on average carried a 19% higher compression load than the EBF3. The friction stir welded panels on average carried a 14% higher compression load and the riveted panels on average carried a 10% higher compression load than the EBF3 panels. Three test panels for EBF3 were manufactured using the EBF3 process to apply stiffeners. The biggest problem that affected the EBF3 panels was the induced residual stress during the manufacturing process due to a thermal gradient in the base plate. This also resulted in some distortion of the plates. Different procedures were used for each panel to help remove some of the residual stresses. Test results show that the EBF3 process has potential as a manufacturing technique for aerospace structures, but that more work needs to be done to understand and reduce the residual stresses in the skin.

Emerging Materials and Processes II - Processes

A Novel Method to Spray WC-Co Using Portable Low Pressure Cold Spray Technology
J. Villafuerte, Centerline Windsor Ltd, Windsor, ON, Canada

Title:  "A Novel Method to Spray WC-Co Using Portable Low Pressure Cold Spray Technology

 Author: Julio Villafuerte, Ph.D., P.Eng.,
Corporate product development manager for CenterLine
(Windsor) Ltd., Windsor, Ontario, Canada, Julio.villafuerte@cntrline.com

 Cold spray is a new solid-state spraying process capable of producing thick metallic coatings or freestanding deposits on a diversity of surfaces. The process takes place at low temperatures, thus avoiding thermal effects such as oxidation, tensile residual stresses, and metallurgical transformations associated with conventional thermal spray processes.  However, due to the nature of the solid-state bonding, the use of traditional cold spray methods has been limited to metals and other materials displaying a certain level of ductility.  A large number of coating applications call for a combination of corrosion, wear, and thermal resistance, requiring materials that cannot typically be sprayed using cold spray.  High Velocity Oxyfuel (HVOF) spraying of WC-Co is one of a number of methods to provide thermal barrier, wear, and corrosion proof coatings.  The use of HVOF in spraying WC-Co has been particularly widespread to replace hard chrome plating in light of recent OSHA regulations limiting the use of processes that release Hexavalent chromium (Cr+6), a well-known carcinogen.  In this paper, we present a different method to cold spray WC-Co cermets using a portable low-pressure system.  The coatings show attractive physical and mechanical properties, without the aggravations associated with elevated process temperatures such as decarburization, oxidation, metallurgical transformations, and residual stresses.  This method can also be applied to cold spray other materials such as Ti-based alloys, Ni-based alloys, steels, Tungsten, Tantalum, ceramics (TiC, VC, WC, HfC, ZrC, NbC, Cr3C2, TaC, Al2O3, Cr2O3, TiO2, ZrO2, TiN, AlN, BN, Si3N4), intermetallics (Ni3Al, Ti3Al), and other cermets.

Effects of Surface Preparation on the Performance of Cold Spray Coatings
B. T. Golesich1, T. Eden2, D. L. Ballard3, J. E. Barnes4, M. Sharma5, K. M. Anderson6, (1)Kuchera Defense Systems, Windber, PA, (2)The Pennsylvania State University, University Park, PA, (3)Air Force Research Laboratory, Wright-Patterson AFB, OH, (4)Lockheed Martin Aeronautics, Fort Worth, TX, (5)Bucknell University, Lewisburg, PA, (6)Kuchera Engineering, Windber, PA

Cold Spray technology is an emerging and alternative coating method to thermal spray coating applications that is gaining acceptance as a method of applying a corrosion resistant coating for aerospace aluminum alloys.  In the Cold Spray process, ductile or composite ductile/hard particles are accelerated to supersonic velocity by expanding a low-molecular weight gas through a converging-diverging nozzle. Upon impact with a substrate, the particles deform and create a mechanical bond.  Unlike traditional Thermal Spray processes where the particles are molten or semi-molten, lower temperatures are used and the particles remain in a solid state during the deposition process.  Another benefit of the Cold Spray process compared to Thermal Spray is the reduced oxide in the coating.  For some applications, to achieve acceptable adhesion strength and coating build-up, proper surface preparation is required. The purpose of this preparation is to remove the surface oxide layer inherent to the substrate, increase the surface roughness for improved mechanical bonding, and remove any debris or oils that could affect the coating performance.  For this study, the focus was to determine the effect that different surface preparation techniques have on coating quality and adhesion for a commercially pure aluminum coating on AA2024-T3 substrates.  The primary techniques involved dry grit blasting with SiC, Al2O3, and glass bead mediums.  Different nozzle trajectories were examined in an attempt to minimize the amount of imbedded grit to the substrate.  Chemical de-oxidation was also evaluated as a non-aggressive preparation technique. Unprepared substrates were used as the baseline for comparison.  Once the substrates were prepared and coated with the Cold Spray process, the coating microstructure and the substrate/coating interface were examined using optical microscopy. Adhesion testing was also conducted following the ASTM International Pull and Bend test procedures.  Results of this study will be presented.

Fabrication of Highly Conductive Cu-Cr Alloy Reinforced with Multiwalled Carbon Nanotubes
P. K. S. Gill1, N. D. H. Munroe2, (1)Florida International University, miami, FL, (2)Florida International University, Miami, FL

There is a great need for contact materials for use in Vacuum Circuit Breakers (VCB) that possess good electrical and thermal conductivity, as well as superior mechanical strength. The most common contact material for medium voltage and high current VCB applications has been the copper (Cu) and chromium (Cr) alloy, which was developed in the 1970’s. Although Cu-Cr alloys are of great interest due to their good electrical and thermal conductivity in conjunction with high strength and ductility, the usage of up to 50% of Cr (a strategic metal) in certain alloys is cost prohibitive. Subsequently, any reduction in the amount of Cr required without a compromise in the desired properties of the alloy is desirable. 

Previous researchers have focused their efforts on developing Cu-Cr alloys with fine and uniform microstructure to enhance the physical properties.  This investigation focused on the development of a Cu-Cr-MWCNT composite material that possesses enhanced properties as compared to the currently used materials. A remarkable increase in the electrical conductivity and strength of the composite was achieved with 5-15 % addition of the ternary element.

Ion Fusion Formation: An Alternative Solid Freeform Fabrication Process
R. J. Adams, Honeywell, Tempe, AZ

Honeywell has developed Ion Fusion Formation (IFF), a new Direct Metal Deposition (DMD) type solid freeform fabrication (SFF). One of its notable distinctions is deposition without an airtight chamber.  Progress to date has been made including equipment upgrades, improved automation, improved shielding and the ability to deposit aluminum. We will describe those advances. This is a near-net-shape hardware manufacturing process that uses a very hot ionized gas to deposit metal in small discreet amounts and ultimately build a complete part. Components can be used as-deposited or post-deposition processed to gain some improvement in properties and then final machined.  The process has low initial capital, maintenance and operating cost and is user friendly.

  Success of deposition without an airtight chamber in such reactive metals as titanium & aluminum has been a significant achievement. This opens the possibility of reducing cost for all depositions. Furthermore it paves the way for building large structures using DMD. Chemical & mechanical properties for aluminum, low alloy and 347 stainless steel, titanium, refractory metal, alloys and other materials will be presented.  In addition, we will review the requirements for shielding and its effect on properties as well progress in component manufacture will be discussed.

 SFF was developed as part of the trend toward use of net-shape and near-net-shape methods using no molds, mandrels or patterns such as powder metallurgy, plasma spraying and chemical vapor deposition processes. Using SFF, the part is built in three-dimensional space using a computer and electronic model to direct location of discreet deposits until a full part is built.

 Other forms of SFF use expensive lasers for their heat source. IFF uses inexpensive electrical energy to generate power for fusion. Thus the energy can be infinitely varied so a larger range of component size can be fabricated with the same equipment.

Rapid Solidification Techniques for Obtaining Metallic Glasses
S. P. Pawar, N. S. Patki, P. P. Kulkarni, College Of Engineering Pune, pune, India

This paper reports an attempt to produce metallic glasses of Al alloys by using Chill block casting and Solid mould casting. Al alloys Al- Si, Al-Si-Cu and Al-Si-Cu-Zn were prepared so as to improve chances of formation of metallic glasses. The characterization of all samples was done by image analyzer, microhardness tester and x ray diffractometer.

Keywords: - chill block casting, solid mould casting.

Emerging Materials and Processes III - Laser Processesing

Laser Micromanufacturing of Polymer Nanocomposites
S. Chen, L. H. Han, W. Zhang, University of Texas at Austin, Austin, TX

We report direct laser ablation of high-density polyethylene (HDPE) filled with carbon nanofibers using a pulsed Nd:YAG laser. Both 532 nm and 355 nm wavelengths with a spot size of 40 mm were used for the study. The laser fluence was varied from 0.8 μJ/cm2 to 3.8 μJ/cm2. Material pop-up occurred near the threshold energy, while open holes were achieved with higher laser energy. The etching depth increased linearly with the number of pulses. Although polyethylene was transparent to the laser beam, the carbon nanofibers added to the polymer matrix absorbed the laser energy and converted it into heat. Numerical heat conduction simulation shown the HDPE matrix was partially melted or evaporated, due to pyrolytic decomposition.

 Also we would like to report on a laser-assisted photothermal imprinting method for directly patterning carbon nanofiber-reinforced polyethylene nanocomposite. A single laser pulse from a solid state Nd:YAG laser (10 ns pulse, 532 nm and 355 nm wavelengths) is used to melt/soften a thin skin layer of the polymer nanocomposite. Meanwhile, a fused quartz mold with micro-sized surface relief structures is pressed against the surface of the composite. Successful pattern transfer is realized upon releasing the quartz mold. Although polyethylene is transparent to the laser beam, the carbon nanofibers in the high density polyethylene (HDPE) matrix absorb the laser energy and convert it into heat. Numerical heat conduction simulation shows the HDPE matrix is partially melted or softened, allowing for easier imprinting of the relief pattern of the quartz mold.

Experimental Investigation on Sub-Micron Scale Laser Shock Peening of Metallic Surfaces
S. Chen1, H. H. Kwon1, N. Mitchell1, Y. Guo2, (1)University of Texas at Austin, Austin, TX, (2)The University of Alabama, Tuscaloosa, AL

Laser shock peening is a technology that a laser beam is used to create a shockwave, which then in turn “dents” the target material, creating a compressive residual stress in the surface of various metallic components.  There are several advantages associated with laser shock peening.  The primary advantage is that when a series of dents are made in the material in a regular pattern, which may act as lubricant reservoir for improved sliding/rolling performance. In addition, the fatigue life of the material can also be greatly improved. A sample that has been treated with laser shock peening will generally have a superior fatigue life that is on the order of several times longer than those of non-treated surfaces. In addition, laser shock peening can improve the corrosion resistance of a specimen, as well as several other properties.  Here we report our experimental investigation of sub-micron scale laser shock peening of Aluminum (Al) and Ti-6Al-4V (Ti) surfaces. A Nd:YAG laser (355 nm wavelength, 10 ns pulse width) was used. The metal surfaces were coated with a layer of alumina foil as a sacrificial layer. The sample was then immersed in water. The laser beam was focused on the alumina foil surface to generate the shock wave. Micro and sub-micron dents were generated in Al and Ti samples surfaces. The dent size dependence on the laser energy/intensity was also investigated. Both scanning electron microscopy and atomic force microscopy were used to characterize the surface topography.

Laser Deposition of Functionally Graded Materials
R. Freeman, R. J. Scudamore, G. Ng, TWI (Yorkshire) Ltd., Rotherham, United Kingdom

Direct Laser Deposition (DLD), an additive manufacturing technique where powder is delivered into a molten pool created by a laser, was used to create deposits that were graded in terms of material chemistry. Functionally Graded Materials (FGM) were generated in a layered manner to demonstrate the practical feasibility of the technique, and determine the mechanical properties across the graded areas. The work was carried out using a Trumpf DMD505 laser deposition system and specialist deposition nozzles. The DMD505 comprises a fully integrated five-axis, CNC controlled gantry, a powder feed system, and a 2.0kW CO2 laser. The trials comprised of two tasks. Initially, tool steel and mild steel were graded and evaluated. The second, more detailed task, graded from titanium 6-4 alloy to titanium 6-2-4-2 alloy.

Deposition parameters were required for all combinations of materials. An emphasis was placed on the optimisation of metallurgical quality, before the mechanical testing was carried out. The grading of the titanium alloys was achieved to a level of metallurgical quality, in terms of solidification defects and porosity. Hardness, tensile strength and ductility were evaluated at differing deposit chemistries, with properties approaching that of wrought material, and no unpredictable drop-off in mechanical behaviour. Demonstration deposits were created as rectangular blocks, and cylindrical tubes.

Development of Hybrid Laser/TIG Welding Process for Gap-free Galvanized Steel DP980 at Overlap-joint Configuration
D. Lin1, M. S. Yang1, M. W. Huang1, M. F. Kong1, P. D. R. Kovacevic1, R. Ruokolainen2, D. X. (. Gayden2, (1)Southern Methodist University, Dallas, TX, (2)General Motors Corporation, Warren, MI

Zinc, particularly at the interface of two pieces of galvanized steels in the overlap-joint welding, creates a problem since its boiling point of 907 ¢ªC is much lower than the melting point of the steel (around 1500 ¢ªC). High power laser welding has advantages in welding steels over traditional arc welding since it can work in a high speed. However, since laser produces extremely high heat input over a short period of time, metallic zinc vapor trapped between two overlapped sheets can quickly increase its pressure. The zinc vapor will be evacuated through the molten pool generated by the laser beam producing blowholes, spatters, and porosities in the weld. In addition, the strength of an as-welded joint is relatively low due to the reduced cross-sectional area. To solve the problems mentioned above, the Center for Laser-aided Manufacturing at Southern Methodist University has developed a low cost technology based on a commercially available high power fiber laser combined with a GTAW system. In this hybrid process, the electric arc generates a molten pool at the upper piece while the laser beam further enlarges and deepens the molten pool and penetrates through the interface opening the vent for the zinc vapor and providing sound joints. The strong forces in the molten pool caused by the electric arc further enhance the evacuation of the zinc vapor. Monitoring of the welding processes via a machine vision system and the final inspection of the welded specimens has demonstrated the elimination of blowholes and high pressure spatters during the welding process. A metallographic analysis has not shown the presence of the porosity across the weld bead. In addition, mechanical testing has shown that the as-welded joint in the gap-free overlap configuration is strong and the fractures occur at the heat-affected zone.

Friction Stir Processing of Laser Deposited T-6-4
R. Francis1, J. W. Newkirk2, F. Liou3, (1)University of Missouri - Rolla, Rolla, MO, (2)U. of Missouri-Rolla, Rolla, MO, (3)Missouri University of Science & Technology, Rolla, MO

Laser additive manufacturing (LAM) produces complicated near net shapes for aerospace components.  Deposition produces a microstructure which is characteristic of the process and processing parameters used.  Friction stir processing (FSP) offers a method of altering the microstructure after the deposition and can be integrated into the manufacturing process.  The results obtained by using FSP to alter the microstructure of laser deposited Ti-6-4 will be presented.  Highly refined microstructures can be achieved and the process can be employed during the build process to create microstructure independent of deposition parameters.  Processing parameters have been optimized for build geometries and the use of this technique in building components will be discussed.

Effect of Laser Surface Melting on Corrosion Performance of Aerospace Aluminum Alloys
Z. Huq1, D. Larson1, B. Mitton1, J. Rindt2, (1)University of North Dakota, Grand Forks, ND, (2)Alion Science & technology, Grand Forks, ND

Laser surface melting (LSM) has attracted growing interest in recent years for its ability to improve the corrosion performance of aluminum alloys.  LSM is a versatile and promising technique that can be used to modify the surface properties of a material without affecting its bulk properties.  The rapid heating and cooling cycles in LSM have been reported to dissolve the intermetallic particles within the melted layer, homogenizing the chemical composition of the layer.  The corrosion of high strength aluminum alloys is dominated by the presence of micro-sized intermetallic particles.  Dissolution of these particles and formation of a solid solution should therefore substantially improve the corrosion resistance of the surfaces.  The aim of this study is to investigate the effect of high power fiber LSM using various shielding gases on the corrosion performance of friction stir welded (FSW) high strength aerospace aluminum alloys.  The results will be compared with non-welded base materials.  Surface morphology, microstructures, phase transformation and compositional changes will be reported.  Corrosion data based on potentiodynamic polarization, open circuit potential, and electrochemical impedance tests performed on LSM surfaces immersed in a 0.5 M NaCl solution will be presented following this investigation. 

Emerging Materials and Processes IV - Materials II

Synthesis and Properties of CNT Textiles and Yarns
D. Lashmore, B. White, M. Schauer, R. Braden, Nanocomp Technologies, Concord, NH

The emphasis by Nanocomp on CVD synthesis of high strength carbon nanotubes has led to a unique process for continuous production of nanotube yarns, and to a new type of very strong non-woven CNT sheet. These materials may be single wall or dual wall. In this presentation an overview of the electronic, mechanical properties and some applications of these carbon nanotube wires and sheets will be presented. Sheet material is now being fabricated 3 foot by 10 foot panels, the largest CNT textiles ever made! Yarns over 1000 m have also been produced! These products potentially enable a variety of applications which make use of their very high specific strength and electronic properties. For example yarns are over 1 N/Tex (2 GPa) and textiles over 0.5 N/Tex (1GPa) have been demonstrated. Prepregged composites of the textiles with strengths of about 2 GPa have been demonstrated. A unique process for post nanotube alignment not only dramatically increases strength but also reduces resistivity and increases the Seebeck Coefficient. Experiments on doping will be described that enable the stabilization of the p type yarns at high temperature in vacuum. Applications include: very light weight electrical conductors to replace copper wire in some applications, composites, sandwich structures, hybrid batteries, fire resistant coatings, and thermoelectric devices.

A Very High Strength PH Stainless Steel For 280ksi, MLX19
A. Tronche, AUBERT & DUVAL, Gennevilliers, France

 AUBERT & DUVAL alloy, MLX19, is a very high strength PH stainless steel recently introduced by the RetD department . The alloy continues a series of high strength, high fracture toughness, and corrosion resistant PH steels from AUBERT&DUVAL. This series of alloys, already widely used in the Aerospace industry, provided solutions ranging from 150 to 250ksi, extended now to 280ksi. Thereby, replacement of cadmium or chromium plated low carbon steels like 300M may be considered. Additionally, the alloy offers Aerospace manufacturers certain fabrication benefits.

 MLX19 is non Carbon, non Cobalt containing steel. The applied heat treatment is a standard PH steel treatment. The alloy therefore presents the advantage of simple heat treatment with low distortions during ageing, weldability and high corrosion resistance. The grade is also well adapted to manufacturing of die forged products.

 The metallurgy along with the characteristics of the grade will be discussed, and will be compared to those of other high strength PH grades including MLX17.

Cast Fe-30Mn-9Al-1Si-0.9C-0.5Mo Alloys with High Specific Strengths
R. A. Howell, D. C. Van Aken, V. L. Richards, Missouri University of Science and Technology, Rolla, MO

FeMnAlC alloys with chemistries in the range of 18-28wt%Mn, 9-12wt%Al, and 0.7-1.2wt%C are age hardenable austenitic steels. The high aluminum content gives the steel corrosion resistance, reduces the density (10-15% ) to a range of 6.5 to 7.2 g/cm3, and produces age hardening in combination with carbon. Wrought materials are typically solution treated above 1000°C, quenched and aged at 550°C for 16 hours to produce precipitation of ?-carbide in the austenite phase. FeMnAlC alloys possess tensile strengths from 627 to 1200 MPa, and an elongation to failure as great as 35% in the peak-aged condition. The combination of strength and low density makes the FeMnAlC alloys attractive as a low cost alternative to titanium alloys. Furthermore, FeMnAlC alloys have casting characteristics similar to cast irons, e.g. high fluidity and low melting temperatures. In this paper, the quench sensitivity and age hardening behavior of a cast Fe-30Mn-9Al-1Si-0.9C-0.5Mo alloy is reported. Quench sensitivity is an important consideration in the heat treatment of these alloys, since distortion and adverse residual stresses increase with quenching rate. At slower rates of cooling the age hardening response can be adversely affected by precipitation of brittle intermetallic phases along austenite grain boundaries. In this study, cast Jominy end-quench bars were used to examine cooling rate effects upon the age hardening potential. Four Jominy bars were solution treated at 1050°C and quenched using a standard end-quench apparatus. End quenching produced a steady increase in hardness with increasing distance from the quenched end. The Jominy bars were subsequently aged at 500°C for 3, 6, 10, and 30 hours and compared to the same cast material that was water quenched and aged. The peak-aged hardness was obtained at shorter aging times. A minimum cooling rate was determined based upon microstructure and aging response.

AlSiC Reinforced with Glass Fiber and Bonded with Epoxy
R. Sagar, IIT Delhi, Delhi, India

The composite is manufactured and tests have been carried out to charecterize its properties like strength, hardness etc It is possible to produce very small diameter and very long holes with this material. These holes have to be drilled in blades of high speed gas turbines. The studies have been made in this paper on the surface finish and roundness of the hole produced in an alloy of Al.

Environmentally Compliant Materials and Processes

Session 1: Material

Environmentally Compliant Materials for Aerospace and Defense
K. O. Legg, Rowan Technology Group, Libertyville, LA

Be-free, High-Strength, Copper Alloy for Aerospace Bushings
J. A. Wright, A. Misra, QuesTek Innovations LLC, Evanston, IL

Non-Aqueous Low-VOC Solvent Replacement for P-D-680 Cleaner
E. Arafat, NAVAIR-Naval Air Systems Command, Patuxent River, MD

P-D-680 (A-A-59601) is a petroleum-based solvent, which contains hazardous air pollutants (HAPs) and volatile organic compounds (VOCs), and causes health and environmental concerns.  Its successor, MIL-PRF-680, is also a petroleum-based solvent which contains the same amount of VOC as P-D-680 but does not contain HAPs. Solvent emissions are regulated regionally and locally, with the Air Pollution Control Districts in California implementing the most stringent requirements.  The San Joaquin Valley Air Pollution Control District (SJVAPCD) has recently imposed restrictions limiting the use of solvents with VOC content to no greater than 25 grams per liter for immersion cleaning processes unless the solvent is used in an airtight cleaning system.
A need exists for a specification to classify and qualify products that are low-VOC and HAP-free to meet these new environmental regulations. This specification covers non-aqueous cleaning solvents that are free of hazardous air pollutants and contain a low amount (no more than 25 grams per liter) of volatile organic compounds for cleaning air, sea, and ground vehicle components and support equipment.  The requirements for the new specification include the following properties: non-ozone depleting substances (non-ODS), HAP-free, low-VOC (25 g/L), effective cleaning efficiency, non-toxic, compatible with metals and non-metal substrates, and safe to use.  The new specification will not replace MIL-PRF-680 totally but will target specific cleaning applications. The new specification consists of two types; Type I is intended for cleaning light soils such as oils and hydraulic fluids, and Type II is intended for cleaning heavy soils such as greases and carbon residues.

Effect of Powder Coating on the Mechanical Properties of Aluminum Substrate
O. S. Es-Said1, C. Maldonado1, D. Diaz1, D. Piatkowski2, (1)Loyola Marymount University, Los Angeles, CA, (2)NAVAIR, Lakehurst, NJ

The effects of curing temperature, based on new, low temperature powder coating methods and traditional high temperature powder coating methods were studied. Heat sensitive aluminum alloys (2024-T3, 6061-T6, and 7075-T6) were subjected to two different heat treatment cycles, which were based on temperatures of 121° and 204° C(250 and 400°F). Findings indicate that although both cure temperatures achieved powder coatings adhesion and thickness appropriate for industrial uses, the high temperature cure treatment negatively affected the mechanical properties.

 Key Words: solvent-borne paints; Low Temperature Cure Powder (LTCP); degradation of mechanical properties, age hardenable aluminum alloys

Qualifying Ultrahigh-Strength, Corrosion Resistant Landing Gear Steel for Flight
B. Tufts1, C. Kuehmann1, P. Trester2, (1)QuesTek Innovations LLC, Evanston, IL, (2)General Atomics, San Diego, CA

QuesTek Innovations’ Ferrium® S53 alloy is being qualified for use in US Air Force landing gear systems. Ferrium S53 is a martensitic, carbide-strengthened, secondary-hardened corrosion resistant steel developed to serve as a drop-in replacement for 300M steel. The details of the Aerospace Materials Specification (AMS) and MMPDS dataset, including design minimums, will be presented. Component qualification and rig testing will highlight the progress being made toward implementation of S53. Forging, machining, and heat-treating specifics along with shot peening, painting, and finishing recommendations will be presented. Although S53 was developed as a drop-in replacement for 300M in landing gear systems, many additional applications are anticipated for this 290ksi UTS corrosion resistant steel.

Session 2: Processing

The Characterictics of Coatings Applied by the Detonation Spray Process
A. Chi, R. Michael, B. Podstupka, Demeton, West Babylon, NY

Environmentally Friendly Corrosion Resistance Protective Coating of High Strength Custom 465 Steel
P. M. Singh1, H. Garmestani1, B. Nguyen2, T. R. McNelley3, (1)Georgia Institute of Technology, Atlanta, GA, (2)Moog, Torrance, CA, (3)Naval Postgraduate School, Monterey, CA

Custom 465 (S46500) is an age-hardenable martensitic stainless steel designed for applications requiring combinations of high strength and toughness. However, custom 465 in the solution annealed and cold treated condition is relatively low in strength and strain-hardening rate due to the low carbon concentration in the martensite. Aging of fully martensitic precipitation hardening in S46500 stainless steel results in strengthening due to the formation of precipitate like γ-phase (Ni3Ti). Cold working prior to aging enhances the precipitation and resulting aging response. For example, the yield strength is increased from about 240 ksi for unreformed material to approximately 295 ksi in material given a 70% cold reduction prior to aging at 482°C (H900). Deformation-induced defect structures may affect precipitation kinetics and precipitate morphology. This behavior of steel was exploited to develop a surface layer with high strength and high hardness on the annealed Custom 465 samples by surface straining the samples by shot peening treatment prior to final aging. This allows for the surface hardness to be increased without significantly reducing the bulk toughness. Corrosion properties of surface treated samples were compared with the non-treated annealed Custom 465 samples. Improvements in the surface hardness with shot peened and aged samples will be discussed.

Elimination of Chromated Wet Sealing of Fasteners using PreCoated Fasteners for Naval Aircraft
F. Lancaster, E. S. Arafat, NAVAIR, Patuxent River, MD

QwikSeal™ Self-Sealing Fastener Technology
G. Schmidt, D. D. Deppe, SMRC, Austin, TX

Wet installation of aircraft fasteners is a time-consuming, labor-intensive process involving the handling and disposal of environmentally hazardous sealant materials. With funding provided by the US Navy, Systems and Materials Research Corporation (SMRC) in partnership with PRC-DeSoto/PPG Aerospace is developing QwikSeal™, a self-sealing fastener technology designed to change the wet installation paradigm.  QwikSeal will first be introduced using a derivative of PR-2001, an AMS3277-compliant two-part polythioether aerospace sealant manufactured by PRC-DeSoto.  In the QwikSeal process the sealant is chemically modified to enable both resin and catalyst components to be pre-mixed and machine applied to the fastener. A proprietary nanocomposite frangible size coat covers the sealant acting both as structural support for the sealant and as a moisture barrier to prevent premature cure. Fastener installation stresses fracture the size coat, allowing the uncured sealant to flow through the hole as in a conventional wet installation. With the barrier coat gone, ambient moisture de-blocks the reaction and allows the sealant to cure normally.  The QwikSeal process requires no changes to fasteners, holes, or tooling, and eliminates virtually all of the artisan’s handling of sealant products associated with fastener installation.  Since the sealant volume applied is metered, only a small squeeze-out bead around the fastener’s head and tail remains to be wiped away, minimizing post-installation cleanup. QwikSeal has the potential to reduce manufacturing costs, speed production, improve quality and consistency, and reduce the hazmat footprint associated with wet installation of aircraft fasteners.

Feasibility Study of Paint Removal from Aircraft Skin by Direct Diode Laser Beam
D. Lin, M. F. Zamora, P. D. R. Kovacevic, Southern Methodist University, Dallas, TX

The focus of this investigation is the feasibility study of paint removal from a typical aircraft skin structure consisting of a thin substrate of aluminum alloy, 2024 T3 or 7075 T6, a thin primer layer, and a thin layer of topcoat paint. In certain cases, the topcoat of paint must be removed for aircraft paint repair. To remove the damaged topcoat of paint, the Center for Laser-aided Manufacturing (CLAM) at Southern Methodist University has developed an innovative technology that successfully removes the topcoat paint without damaging the underlying primer layer and the aluminum alloy substrate.
The developed paint-removal technology is based on a hybrid approach which integrates a short pulsed laser beam from the direct diode laser with a cold air stream from a cooling system. Preliminary results have shown that: (1) a direct diode laser with continuous or pulsed waves will burn the primer, or even substrate, and so fail to effectively remove the topcoat paint, and (2) a pulsed laser beam in conjunction with a cold air stream can efficiently de-bond the topcoat paint from the primer layer transforming the topcoat into loose, reticulated particles with segment sizes around 100 µm. Temperature measurements on the backside of the specimen, EDX analysis after paint removal and the study of various laser parameters have been performed to optimize this process.

Environmentally Compliant Aluminum Ceramic Coating
B. Bodger, DemVal, Inc., Ronkonkoma, NY

Thermal Spray Material Alternatives to Chrome VI Coatings
G. Engleman, MesoCoat, Inc, Euclid, OH

Chrome plating provides a very effective surface treatment for wear and corrosion reduction. In use for more than 70 years, it has proven to be a relatively inexpensive, effective solution. Electrolytic Hard Chrome (EHC) is applied using the reduction of hexavalent chrome in a solution of chromic acid. The EHC plating process is a low efficiency process which results in vigorous gas evolution at the electrode. This results in airborne mist which contains hexavalent chrome, a known carcinogen.  Several alternative technologies exist to coat a substrate with metal without using electrolytic solutions or plating baths. These technologies do not eliminate the use of metal coatings, but they do eliminate the use of non-metal toxic components such as cyanide from the plating process. They can also reduce the amount of metal-contaminated wastewater and sludge that is generated from plating. These alternative technologies include thermal spray coating, vapor deposition, and chemical vapor deposition, and can be used to apply alternate materials.  MesoCoat, Inc. has developed a combined top-down/bottom-up approach to this problem, utilizing a novel process for producing nano-featured feedstock materials as an alternative to the technologies described above.  This approach both reduces the amount of waste produced and the amount of post plating processing required resulting in a hard, corrosion resistant coating.

High Temperature Materials

Nickel Superalloys

New Low Density Single Crystal Superalloys for Turbine Blades
M. V. Nathal, R. A. MacKay, T. P. Gabb, J. L. Smialek, NASA Glenn Research Center, Cleveland, OH

Second-generation single crystal alloys are typically used in the production of turbine blades for subsonic aircraft engines.  These alloys have good high temperature creep resistance and demonstrate a range of oxidation resistance and alloy densities.  More advanced, third and fourth-generation single crystal turbine blade alloys have excellent high temperature creep but have very high alloy densities because of the nature and amount of refractory metals used in these alloys. These latter alloys typically have more limited applications as a result.  We have taken the approach of designing new single crystal alloys with high temperature creep and oxidation resistances that meet or exceed the performance of second-generation single crystal alloys and do so at a reduced alloy density. Lower blade alloy density can provide significant reductions in total engine weight, because the size of the rotating disk, shaft, and other supporting structures can be concurrently reduced.  Thus, lower density and stronger turbine blade alloys provide improved engine performance, reduced fuel burn, and reduced emissions for subsonic aircraft.  Results from creep rupture testing, cyclic oxidation testing, microstructural stability tests, and density measurements will be presented for the low density superalloy single crystals and compared with published data from several production turbine blade alloys. To gain an understanding of the fundamental effects of alloying elements on mechanical and environmental behavior, a number of microstructural features were examined, including g’ precipitate size and volume fraction, microstructural stability, phase chemistries, and oxide scale formation.  The goal of this work is to improve the ability to predict alloy behavior in order to tailor these alloys for specific turbine engine applications.

The Effect of Microstructure on the Intermediate Temperature Primary Creep in Single Crystal, Ni-base Superalloys
G. E. Fuchs, B. C. Wilson, University of Florida, Gainesville, FL

            Some second, third and fourth generation single crystal Ni-base superalloys (i.e., Re-containing alloys) have demonstrated a propensity for excessive primary creep at intermediate temperatures.  During testing between 650°C and 850°C, the Re-containing alloys can exhibit up to 28-30% creep in the first few hours of a creep test.  Secondary creep with a very low creep rate immediately follows and rupture lifetimes for these alloys can be quite long:  up to an order of magnitude longer than first generation alloys in similar test conditions.  Although rupture times are long, the time to 1% creep can be much shorter than that observed in first generation alloys.  This behavior has been attributed to the presence of secondary g’ precipitates in the g matrix channels, as well as on the Re content of the alloys.  This investigation examined creep behavior for a common first generation alloy, PWA 1480, a common second generation alloy, PWA 1484, as well as an modified first generation alloy, PWA 1480 with 3 weight percent rhenium added.  Results show that while PWA 1484 exhibits high primary creep, the PWA 1480 with Re did not, suggesting that Re is not the sole cause of high primary creep.  Additionally, two different aging heat treatments were given to each alloy to either precipitate or prevent the formation of, fine (nm scale) secondary g’ in the g channels.  Results of these tests revealed that the presence of the fine secondary γ’ had a significant impact on the extent of primary creep; however, the presence of the fine secondary γ’ was not the only factor controlling the primary creep.  The role of the fine scale microstructure and the alloy composition on primary creep deformation will be discussed.

Advanced Characterization of Superalloys to Evaluate Tertiary Gamma Prime
J. Tiley, Air Force Research Laboratory, Wright-Patterson, AFB, OH

Research involved determining the chemical composition gradients and the microstructure features for a commercial nickel superalloy.  Samples were subjected to multiple heat treatments and aging conditions and then characterized using a multitude of advanced techniques.  The chemical compositions were determined using local electrode atom probe tomography (LEAP) with support from bulk chemistry values measured using a Cameca SX100 microprobe.  The gradients were determined by sampling perpendicular to the precipitate surfaces within each of the samples with average values obtained using the same volume of material within the precipitate and matrix.  The microstructure features were determined using energy filtered transmission electron microscopy with an FEI Tecnai 200Kv TEM.  The data was used to determine the size distributions and the aspect ratios of the tertiary and secondary gamma prime as functions of the aging times and cooling rates.  Results are provided and discussed.

Effect of Annealing Procedures on Alloy 625 Mechanical and Microestructural Properties
O. Covarrubias, O. Elizarraras, Frisa Aerospace SA de CV, Santa Catarina, Mexico

The effect of annealing procedures on Alloy 625 is evaluated when forged rings were exposed to different heat treatment conditions.  Samples of these rings were analyzed by mechanical testing and microstructural evaluation, including optical microscopy and SEM techniques to define relationships between reported properties and microestructural characteristics.Several seamless rings were forged and rolled under controlled parameters.  These rings were then segmented to evaluate initial alloy properties and microstructural characteristics.  Other segments from each ring were annealed under selected parameters to determine the effect of time and temperature on alloy characteristics.  After annealing heat-treatment, segments were tested to evaluate microstructural, hardness and tensile properties.

After mechanical testing, two behaviors for Alloy 625 are observed: 1) the higher the annealing temperature, the lower the mechanical properties obtained, and 2) at one selected temperature above 900ºC, as soaking time is increased, mechanical properties as hardness and tensile decrease.

From the point of view of microstructure, Alloy 625 grain size tends to coarse when annealing temperature is increased above 950ºC for more than 100 minutes, and as mentioned, mechanical characteristics are negatively affected.  When this alloy is exposed to a selected annealing temperature below 950ºC, grain size do not coarse, but mechanical properties are decreased.

This behavior can be explained by development of fine precipitates into grains during heating and cooling operations performed on forging and rolling procedures.  After annealing heat treatment at temperatures above 900 it was observed these precipitates present coalescense, decreasing mechanical properties without affect grain size.

Cyclic Oxidation of Thermal Barrier Coatings - In Situ Analysis Under Controlled Temperature Gradient
P. Lours1, J. Sniezewski1, Y. LeMaoult1, F. Crabos2, (1)Ecole des Mines Albi, Albi, France, (2)Turboméca - groupe Safran, Bordes, France

Multimaterials systems such as thermal barrier coatings used at high temperature in gas turbines are subject to severe thermomechanical loading. During service, complex thermomechanical stress is generated, resulting from thermal variations that establish through the thickness of the multimaterials system. The occurrence of such thermal gradients specifically provokes spallation, enhancing the overall damage of material surface.
Consequently, it is of utmost concern to investigate the cyclic oxidation and spallation of materials under imposed/controlled temperature gradient. In order to reproduce the conditions of materials utilization a novel, specifically dedicated cyclic-oxidation-equipment is designed and implemented. Based on a coupled experimental/numerical approach, the design mainly focuses on the development of specific specimen-holders able to impose a controlled and measurable thermal-gradient through the specimen thickness using appropriate geometry, dimension, insulation, materials and fluids circulation. The possibility of controlling the gradient through the specimens brings a very interesting advance in the way to characterize TBC by reproducing at the laboratory scale the real in-service condition of high temperature turboengine materials.
In addition, the oxidation/spallation testing equipment includes the possibility to monitor in situ, using various optical means such as high-resolution CCD, high-speed and infrared cameras, the evolution of the material surface while thermally cycled. This versatile real-time approach allows the identification and analysis of the spallation mechanisms at different microstructural and time scales.
Preliminary results showing the impact of a thermal gradient on the propensity of thick APS-YSZ (300µm-1500µm) to spall upon thermal cycling are presented. The presence of a gradient has major influence on the kinetics and extent of spallation and the morphology and typical critical size of individual spalls. For given thermal gradients, the influence of the material microstructure, namely the size and crystal orientation of grains and the morphology of grain boundaries, as well as the time-scale of spallation event, are discussed.

Improving Understanding of Failure Mechanisms of Thermal Barrier Coatings
A. Atkinson1, D. S. Balint1, L. Chirivi2, A. Luz1, J. R. Nicholls2, K. M. Nikbin1, N. J. Vecchione1, X. Wang1, R. Wu1, (1)Imperial College, London, United Kingdom, (2)Cranfield University, Cranfield, United Kingdom

Thermal barrier coatings (TBCs) are crucial for increasing the turbine inlet temperature (and hence efficiency) of gas turbine engines.  This paper describes a UK collaborative project (funded by EPSRC and MoD) aimed at improving understanding of the thermal cycling failure mechanisms of electron beam physical vapour deposited (EBPVD) yttria stabilised zirconia (YSZ) TBCs on CMSX4 superalloys. 

The project involves the production of TBCs with different bond coats and with controlled surface morphologies, measurement of residual stress in the alumina thermally grown oxide (TGO) using luminescence, and measurement of YSZ mechanical properties and inter-layer adhesion by indentation.  Generation of stress in the coating on thermal cycling, and its relief by plastic deformation and fracture, was studied by finite element modelling (FEM).  The bond coats studied include two beta-structured Pt-Al types (differing in their aluminising temperature, LT and HT)) and a gamma-gamma prime structure produced by Pt diffusion without aluminising. 

In this contribution we describe some of the key findings of the project.  The TBCs with the LTPt-Al bond coat fail by a rumpling mechanism that generates isolated cracks at the interface between the TGO and the YSZ.  This reduces adhesion at this interface and the TBC delaminates when it can no longer resist the release of stored elastic energy of the YSZ, which stiffens with time due to sintering.  By contrast, the TBCs with Pt diffusion bond coats do not rumple, and the adhesion of interfaces in the coating does not significantly degrade.  These TBCs fail at the bond coat/TBC interface driven by release of stored elastic energy in both the TGO and YSZ.  The TBCs with HTPt-Al bond coats show mixtures of both failure mechanisms.  It is shown that the different failure mechanisms are caused by the different high temperature mechanical properties of the bond coats.

TBCs with Cost-Effective Nanostructured Bond Coats
G. E. Kim1, M. Brochu2, A. L. Moran3, T. Addona4, (1)Perpetual Technologies, Inc., Ile des Soeurs, QC, Canada, (2)McGill University, Montréal, QC, Canada, (3)United States Naval Academy, Annapolis, MD, (4)n-WERKZ, Ile des Soeurs, QC, Canada

A commercially viable means of processing nanostructured MCrAlY powder has been developed, applied, and tested for thermal barrier coating (TBC) application.  The new approach does not use liquid nitrogen, which has previously been the primary means of processing similar nanostructured metal powders and which is cost-prohibitive for many commercial applications.  In addition, the new approach offers the advantage of reduced processing time as compared to cryomilling.  MCrAlY coating samples with and without YPSZ top coats were produced using conventional thermal spray processes, i.e., HVOF and APS.  Preliminary results from static oxidation and thermal cycling tests show clear advantages over their counterpart coatings.  Compared to thermal spray coatings using conventional NiCrAlY bond coats, the nanostructured bond coat samples showed delayed formation of mixed oxide thermally grown oxide (TGO) and the TBC samples resulted in a 50% improvement in thermal cycles to failure.  Failure analysis of the thermal cycled samples validate this.

Innovative Materials and Processes for High-Temperature Applications

The Mechanisms of Nucleation and Growth of Massively Transformed ã in TiAl Alloys
M. H. Loretto1, H. Jiang2, H. Saage2, D. Hu2, X. Wu2, (1)University of Birmingham, Birmingham, United Kingdom, (2)IRC in Materials Processing, University of Birmingham, Birmingham, United Kingdom

The factors that control the nucleation and growth of massive gamma in TiAl-based alloys are reviewed with the aim of understanding the role that alloy composition has on the kinetics of the massive transformation. It is accepted that the growth of massive gamma, which involves individual atomic jumps across the interface between the alpha and the massive gamma, takes place far more rapidly than the growth of the other transformation products, lamellae, feathery and Widmenstatten because these require long distance diffusion. The situation concerning the factors which control the rate of nucleation is less clear and recent work aimed at understanding nucleation will be presented.

 

Properties of Mo- and Nb-Based Silicide Materials
S. Drawin1, M. Heilmaier2, P. Jéhanno3, D. Hu4, P. Belaygue5, P. Tsakiropoulos6, M. Vilasi7, J. Y. Guédou8, P. Novak9, N. Jones10, S. Sabbadini11, (1)ONERA, Chatillon, France, (2)University of Magdeburg, Magdeburg, Germany, (3)Plansee SE, Reutte, Austria, (4)The University of Birmingham, Birmingham, United Kingdom, (5)Turbomeca, Bordes, France, (6)University of Sheffield, Sheffield, United Kingdom, (7)Université Nancy 1, Vandoeuvre, France, (8)SNECMA, Moissy Cramayel, France, (9)Walter Engines a.s., Praha, Czech Republic, (10)Rolls-Royce plc, Derby, United Kingdom, (11)Avio S.p.A, Rivalta Torino, Italy

Increasing the temperature capability of turbine airfoil materials has been identified as a major requirement to develop efficient and clean aircrafts. The development of new alloys offering increases of metal surface temperatures by at least 150°C over the presently used Ni-base single-crystal superalloys capability is of strategic importance.

The ULTMAT (Ultra High Temperature Materials for Turbines) project has started in January 2004 in the frame of the European FP6, and will end in June 2008. Expected achievement of the project is a thorough evaluation of the capability of refractory metal (Nb and Mo) silicide based multiphase materials to withstand future enhanced temperature turbine service conditions (up to 1300°C), relying on mechanical, microstructural and environmental investigations in close relation with industrial scale material processing and component fabrication technologies.

The paper will present the main results currently obtained. Base materials for the alloy development are the metal/intermetallic ductile/brittle systems, more precisely the two-phase Nb-Nb5Si3 system and the three-phase Mo-Mo3Si-Mo5SiB2 system. Improvements in creep resistance and oxidation resistance at high temperature (in the range 1000-1300°C) have been obtained. Processing routes have been developed (ingot metallurgy and powder metallurgy) that have allowed the manufacture of complex shaped parts (turbine blades).

Alloy Development and Processing NbSi alloys to Produce Net Shape Components
M. H. Loretto1, D. Hu2, M. Wickins2, Q. Li2, X. Wu2, (1)University of Birmingham, Birmingham, United Kingdom, (2)IRC in Materials Processing, University of Birmingham, Birmingham, United Kingdom

Processing of niobium silicides to produce potential components for use in gas turbines is difficult and most work has used casting, commonly using directional solidification, followed by machining of these difficult-to-machine alloys. In the ULTMAT project, effort was focused on investigating the suitability of conventional ceramic moulds for investment casting of NbSi alloys. Net shape demonstrator blades with different sizes have been successfully cast using the GE MASC alloy and yttria face-coat ceramic moulds.  A parallel programme in the IRC was devoted to improve the oxidation resistance through alloying. Some alloys with increased Al concentrations have been studied and they show improvement at both high and low temperatures and at the same time the creep resistance was retained or improved compared to MASC alloy.

 

 

Advances in Nickel Superalloy Processing by Electron Beam Free Form Fabrication
B. H. Walker, R. M. Walker, Keystone Synergistic Enterprises, Inc., Port St. Lucie, FL

Keystone Synergistic Enterprises, Inc. and their business partner Acceleron, Inc. have recently completed an Air Force sponsored Phase II SBIR program demonstrating advances in processing of IN 718 using wire feed, electron beam free form fabrication (EBFFF) methods. Extensive process characterization was utilized to establish a direct correlation of process parameters with material microstructure, mechanical properties and quality. Both monolithic and dual alloy, complex gas turbine engine cases were produced with near-parent-metal mechanical properties and quality meeting aerospace requirements. Empirically validated economic process modeling verified components can be affordably produced by EBFFF using either direct or additive manufacturing methods. Keystone will present detailed results from this program and their efforts to date to bring this important technology to production readiness and offer EBFFF manufacturing services to industry.

Microstructural Characterisation of Laser Deposited Alloy 718
D. J. Marks1, L. Smith2, D. Clark3, (1)TWI, Rotherham, United Kingdom, (2)TWI, Cambridge, United Kingdom, (3)University of Birmingham, Birmingham, United Kingdom

Direct metal laser deposition (DMLD) offers many advantages as both an additive manufacturing and repair technique. The extent to which process parameters can be controlled during DMLD allows optimisation of conditions during manufacture and repair. However, the relationship between deposition parameters and microstructure needs to be defined, and then modelled, for material optimisation to be achieved.

Samples of Alloy 718 were deposited using a series of different laser power, frequency and feed-rate, to explore the relationship between process parameter and microstructure. Samples were deposited as a series of six passes, built up into a triangular cross section. By varying the pass spacing, the aspect ratio of the triangle was altered, allowing variations in cooling rate to be explored. Comparison was also made between as-deposited and heat treated samples.

The use of a field emission gun scanning electron microscope (FEG-SEM) equipped with electron backscattered detection (EBSD) allowed detailed microstructural characterisation. This revealed finely spaced dendrite arms within the deposits, indicating a high cooling rate during solidification. Chemical mapping of niobium highlighted the extent of segregation to interdendritic regions, which contain significant quantities of secondary phases and particles. Given the close dentrite spacing, it was considered that beneficial second phases, such as γ′′ should be comparatively well distributed throughout the deposits. Average grain size measurements revealed no significant trend between the locations within each deposit, or between as-deposited and heat treated samples. Crystallographic analysis indicated some evidence of texture development within the deposits.

Following an ageing heat treatment, as expected, there was little diffusion of the niobium, even when there are such small distances between the interdendritic regions and dendrite cores. This result suggests that any nucleation and growth of secondary phases during heat treatment (with the exception of γ′) would be confined to the niobium-rich interdendritic regions.

Carbon Nanotube Reinforced Nickel Matrix Composites
J. Hwang, R. Banerjee, A. Neira, University of North Texas, Denton, TX

<>Composites based on multi-walled carbon nanotubes (MWCNT) dispersed in a nickel matrix have been processed using the laser-engineered net shape (LENS) processing technique. The advantage of using LENS is that that while using a powder feedstock, the composites are processed via a liquid metal route involving rapid solidification. However, there exists a rather limited understanding of the interactions between liquid metal and nanotubes since most of the currently used processing technologies for nanotube based composites are not based on melt processing. The present study focuses on the survivability of nanotubes during melt processing using LENS in a liquid nickel matrix. Furthermore, the stability of MWCNT versus graphite powders in liquid nickel have been compared by processing both types of composites under identical conditions. These composites have been characterized in detail using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and, micro-Raman spectroscopy in order to determined the state of the nanotubes post processing. The microhardness and the wear resistance of the MWCNT reinforced composites have also been studied and these results will also be presented.

Thermal Protection Systems

Development of Titanium Based Thermal Protection Systems
Y. Kosaka, Timet, Henderson, NV

The program started in 2007 under the Metals Affordability Initiative. The goal of the program is to evaluate and demonstrate capability of titanium based thermal protection systems. In the program, more than a half dozen of titanium alloy sheets (0.040~0.060 inch gage) and thin foils (approx. 0.003~0.004 inch gage) are produced for various evaluations including elevated temperature mechanical properties and oxidation resistance. This presentation will update and discuss the recent progress of the program.

Progress Towards the Development of a Creep-Resistant Beta-Titanium Alloy Based on Timetal-21S
B. Peterson1, P. C. Collins2, H. L. Fraser3, (1)The Ohio State University, Columbus, OH, (2)Quad City Manufacturing Lab, Rock Island, IL, (3)Center for Accelerated Maturation of Materials, Columbus, OH

The composition of the alloy Timetal 21S has been selected as a baseline for the development of a new high temperature beta titanium alloy. A combinatorial approach employing directed laser deposition of elemental powders has been used to produce a number of test coupons that represent a controlled variation of compositions. The creep properties have been assessed using an Instron ETMT instrument operating in a constant load mode, and represented by their minimum steady-state creep rates. The microstructures have been characterized and quantified using a variety of techniques, and included in databases used to develop neural-network models for predicting minimum creep rates. In addition to the base elements (Ti, Mo, Nb, Al, and Si), neutral elements (Zr and Sn), beta-stabilizers (W), and dispersoid formers (B, C, Ge) are being explored. Based on these results, a new group of alloys for application in high temperature thermal protection systems are being developed.

Development of Superalloys Metallic Thermal Protection Systems
D. S. Shih1, E. T. McDevitt2, B. Baker3, (1)The Boeing Company, St. Louis, MO, (2)Allegheny Technologies Incorporated (ATI), Monroe, NC, (3)Special Metals Corporation, Huntington, WV

This presentation will update and discuss the recent development progress in the Metals Affordability Initiative project, "Superalloys-based Thermal Protection Systems."  In this program, thin foil (0.002-0.007-inch thickness gauge) of the Allvac 718Plus, Inconel 617, and Haynes 282 alloys will be produced.  Mechanical properties at room and elevated temperatures will be evaluated and an analysis methodology will be developed for the use of advanced hypersonic.

Development of Pt-modified g-Ni+g'-Ni3Al-based alloys for high-temperature applications
A. J. Heidloff1, T. Izumi1, B. Gleeson2, (1)Iowa State University, Ames, IA, (2)University of Pittsburgh, Pittsburgh, PA

Novel heat-treatable γ-Ni+γ'-Ni3Al-based alloys having excellent resistance to both high-temperature oxidation and creep are being developed in a systematic manner using multiple alloying additions, including Pt and Ir, i.e., platinum group metals (PGMs).  Alloys possessing such combined high temperature properties could find use in current and future niche aero applications involving extreme conditions. The microstructures, phase equilibria and thermal stabilities of the alloys studied were fully characterized. This included determination of the γ and γ' volume fractions and lattice parameters over the temperature range 700-1300°C using controlled-atmosphere synchrotron radiation. The results were correlated with the alloy microstructures.  Alloys subjected to intermediate-temperature creep were investigated using TEM and the resulting dislocation network spacings were used to determine γ/γ' lattice misfits, which were compared to the unstressed measurements obtained from the synchrotron results.  Oxidation behavior was studied at 1000°C under both thermal cycling and isothermal conditions.  PGM additions were found to reduce the detrimental effects of “strengthening” alloying additions on oxidation and to promote exclusive formation of a continuous Al2O3 scale.  Investigation of short-term oxidation behavior was also conducted to determine compositional and microstructural factors affecting the oxide-scale evolution. 

Hot Working of Platinum Group Metal (PGM)-Modified Ni-Base Superalloys
D. L. Ballard, S. L. Semiatin, P. L. Martin, Air Force Research Laboratory, Wright-Patterson AFB, OH

Platinum- and iridium-modified gamma-gamma prime superalloys are being evaluated for high-temperature use due to their superior oxidation resistance compared to conventional nickel-base superalloys. These materials also retain excellent strength at temperatures in excess of 1100°C due to their higher gamma prime solvi. Because of their cost and density, however, specific applications must be chosen carefully. One product form of particular interest comprises thin gage sheet and foil for thermal-protection-system applications. Initial research to evaluate the conversion of subscale ingots of PGM alloys to wrought form and subsequent conventional pack rolling to obtain sheet will be reviewed for three experimental alloys.

Gamma Prime Morphology and Creep Properties of Nickel Based Superalloys with Platinum Group Metal Additions
J. Van Sluytman, A. Suzuki, T. M. Pollock, University of Michigan, Ann Arbor, MI

Ni-based superalloys modified with platinum group metal (PGM) additions of Pt and/or Ir with selective amounts of Al, Cr, Re, Ta, and Hf have been investigated.  TEM evaluations reveal two-phase gamma-gamma prime microstructures over a wide range of composition with Pt and/or Ir additions up to 5at%.  Precipitate morphologies range from cuboidal to irregularly shaped, indicative of a wide range of lattice misfit. All PGM modified alloys possess positive misfit with magnitudes ranging from 0.3-1.0%.  Beyond the PGM additions, Cr, Re, and Ta have the greatest influence on precipitate morphology.   Compression creep tests were carried out in the stress range of 50-90 MPa at 1000°C.  Creep tests indicate that alloys containing (in at.%) 2.5% Pt or a combination of 2.5%Pt-2.5%Ir have higher resistance to creep deformation compared to alloys with 5%Pt or alloys containing only Ir.

Light Alloys

Light Alloy Technologies I

Latest Generation of Al-Li alloys Developed by Alcan Aerospace
P. Lequeu1, F. Eberl2, S. Jambu3, T. Warner4, A. Danielou4, B. Bes5, (1)Alcan Pechiney Rhenalu, Issoire, France, (2)Alcan Rhenalu, Issoire Cedex, France, (3)PECHINEY Aviatube, Montreuil-Juigné, France, (4)Alcan, Voreppe, France, (5)Alcan CRV, Voreppe, Cedex, France

Aluminium-lithium alloys of the so-called third generation were introduced mostly as plates in the early 1990’s. The drawbacks of the previous Al-Li alloy generation, like low ST properties and poor thermal stability, were eliminated thanks to the adoption of lower Li contents. Alloys such as 2195 or 2297 found their first industrial application in space and fighter aircraft application.
Recently, increases in fuel price and the subsequent need to reduce aircraft weight have led the commercial airframe manufacturers consider anew the use of such low density alloys in various structural parts currently produced in standard 2xxx and 7xxx qualities. Since 3rd generation Al-Li alloys were driven by military and space applications, they often exhibit damage tolerance properties which are not fully compatible with their use on commercial aircraft. This is the reason why Alcan Aerospace has worked over the last few years to develop appropriate Al-Li chemistries and their associated thermo-mechanical processing, based on commercial aircraft typical requirements.
The paper will illustrate some of the fundamentals behind the choice of chemistries, as well as the property balance generated at an industrial scale on a selection of those alloys. It will be shown that Al-Li properties can match and often exceed those of the corresponding baseline alloys, with the additional benefits of lower density, higher modulus and better corrosion resistance.
Examples will include alloys like 2050 for medium to thick plates, 2196 for heavy & small gauge extruded sections, as well as 2198 for sheet. Data on new high strength and / or high damage tolerance Al-Li alloys will also be shown for the full range of typical wing and fuselage applications.

Weight Savings for New Commercial Aircraft Through Application of 2098 Al-Li Sheets
F. Eberl1, K. P. Smith2, F. Bron3, (1)Alcan Rhenalu, Issoire Cedex, France, (2)Alcan Rolled Products, Ravenswood, WV, (3)Alcan, Voreppe, France

Although more and more composite materials are being used, advanced metallic structures are still bringing significant weight savings to aircraft.  The purpose of this paper is to present typical benefit obtained by using 2098 aluminum lithium sheets within the airframe structure.

 

Alcan experience on aluminum lithium is becoming stronger and currently a large range of products (stiffeners, plate and sheets) are qualified and proposed to customers, including 2098 alloy, previously qualified by one military aircraft manufacturer.  The next challenge was to develop 2098 sheets for a new set of requirements.  Because the new application is driven by static strength, details will be presented on static properties and the process to achieve them.

 

Significant weight gains can be reached with aluminum solutions thanks to their flexibility in design and manufacturing. The implementation of 2098 aluminum lithium will be reviewed with special emphasis on design criteria for further weight gain as well as good manufacturability in order to keep assembling costs low.

2050 Al-Cu-Li Last Generation Light Alloy Forgings Developed by Aubert&Duval in Cooperation with Airbus and Alcan
M. Piellard, Aubert & Duval Issoire, Issoire, France

The so-called third generation of Al-Li alloys exhibits very good performances demonstrated on plates by Alcan and Airbus. To offer our customers the most advanced forging solutions, Aubert&Duval, Airbus and Alcan investigated the feasibility and characteristics of 2050 T852 forged products.

It was shown that, in addition to a low density, this alloy offers interesting static, fatigue and stress corrosion resistance properties compared to the 7xxx series alloys. The study demonstrated that the cold deformation, usually used for stress relieving, is a key parameter for ensuring the optimum properties of 2050 forged products.

Results on forged blocks and industrial parts will be shown. Those results also include fatigue tests on anodized components.

Commercially Viable Nanostructured Aluminum for Coatings and Structural Applications
G. E. Kim1, A. L. Moran2, B. Jodoin3, T. Addona4, (1)Perpetual Technologies, Inc., Ile des Soeurs, QC, Canada, (2)United States Naval Academy, Annapolis, MD, (3)University of Ottawa, Ottawa, ON, Canada, (4)n-WERKZ, Ile des Soeurs, QC, Canada

A new means of producing nanostructured aluminum alloy (i.e., AA5083) powder at a lower cost has been developed by n-WERKZ Inc. The new powder processing method does not use high cost liquid nitrogen, which was relied upon by prior methods to attain nanostructured metal powder. Cold sprayed deposits of the powder showed the ability to deposit dense, well-adhered nanostructured AA5083 coatings without any signs of grain growth. With the knowledge that bulk materials of the same composition show lower propensity for localized corrosion with finer grain size, a corrosion study will be carried out to determine if the same holds true in coating form. If so, this may be a viable means of repairing localized damage in protective coatings and/or structures, as well as its application for superior corrosion/wear protection. Sample powder of the nanostructured AA5083 powder was used to produce bulk parts that were machined and tested under tension. The preliminary tensile test results revealed average yield and ultimate strengths of 400 and 490 MPa, respectively. The most surprising result was the average elongation of 15%, not typically seen on materials processed in similar manner, especially without liquid nitrogen which, amongst other things, helps mitigate oxidation during processing. Knowing that the issue of elongation has been addressed for the nanostructured AA5083, focus will shift towards exploring the further enhancement of its strength.

MagForming Project
G. I. Rosen, AMTS Technology Center, Kiryat Bialik, Israel

The EU project MagForming is being funded by the 6th framework program priority 4 aeronautics and space. The purpose of this project is to advance the state of the art in the technology of plastic processing of wrought magnesium alloys for aeronautical applications by developing tools and manufacturing processes for industrial applications. The measure for attaining the objective is by attempting to fabricate several technology demonstrators, at least one for each of the considered forming technologies. These are:  forging, pad-forming, deep drawing, super plastic forming, roll-bending and creep forming. The partners form a consortium consisting of ten companies and two universities from Europe and Israel. These partners are specialized in the development of new magnesium alloys, materials characterization, FEM analysis, development and construction of tools and dies, forming and application.

Light Alloy Technologies II

Alcan Aerospace's Vision of Future Aircraft Structure
T. Warner1, P. Lassince2, C. Bersuder2, K. P. Smith3, C. Boland3, (1)Alcan, Voreppe, France, (2)ALCAN Rhenalu, Issoire, France, (3)Alcan Rolled Products, Ravenswood, WV

The proportion of metallic structures in the large commercial airframes currently in development is significantly lower than in comparable previous generation aircraft.  Our analysis of the underlying reasons indicates that the airframers’ decisions are based on both quantifiable arguments (technical and economic) and less quantifiable parameters.   Technically, it is argued that CFRP panels have a significant weight advantage particularly in damage tolerance- or stiffness-dominated parts.  Equally, it is generally recognized that metallic solutions are currently lower cost.  Less quantifiable arguments include: the future potential of CFRP structures, the concomitant technological gap with newcomers to the large commercial airframe business that could be created by developing such solutions, and the advantage of CFRP’s relative novelty in obtaining government support for development activities.

 This analysis has led Alcan to respond around four principal axes.  Firstly, in response to the weight challenge we have developed very competitive metallic solutions using optimum existing technologies (alloys, assembly techniques) in innovative ways.  This approach has resulted in solutions exceeding 20% weight reduction vs today’s aerostructures, at lower cost, and applicable to a wide variety of airframes.  Secondly, in many cases combinations of materials represent optimum weight-cost solutions; to enable this, technologies for hybrid joining need to be optimized.  Thirdly, to address the perception of lower future potential of metallic structures, we are both increasing our effort on breakthrough metallic technologies and developing a more aggressive communication on metallic structures’ advantages, for example emphasizing the full recyclability of aluminium.   Finally, we are instigating a more balanced co-development strategy, by partially redeploying our resources from the development of generic solutions for large airframes to more targeted projects addressing a greater variety of specific customer developments.

 Examples of achievements and on-going development in the above four areas will be presented.

The Effect of Heat Exposure on Novel and Conventional Aluminium Alloys for Airframe Use
A. Shekhter, Defence Science and Technology Organisation, Fishermans Bend, Australia

The effect of thermal exposure on the conventional aluminium alloy 7050-T7451 and the novel alloy 7085-T651 was investigated. Engine exhaust leaks or fires could expose these airframe alloys to abnormally high temperatures, which in some cases can exceed the final ageing temperatures of these alloys. This can severely reduce the remaining life of components made from these alloys by significantly damaging their mechanical properties. The degree of thermal damage induced in aluminium alloys is time-temperature dependent; the reduction of mechanical properties increases with higher exposure temperatures and longer exposure times. This reduction is apparent both at elevated temperatures and at room temperature after exposure.

Given the above, an investigation was conducted to assess the effects of heat exposure on the static and fatigue properties of 7050-T7451 and 7085-T651. Hardness and conductivity tests of the baseline and heat-exposed materials were supported by tensile and fatigue life tests. Optical microscopy and fractographic examination were also performed. The hardness, tensile and fatigue tests indicated the mechanical strength and fatigue life were degraded by thermal exposure for both alloys. Optical microscopy of the heat-exposed material showed no apparent microstructural changes, suggesting that any such changes were below the resolution limit of the optical microscope (approximately 0.4 µm). The observed degradation of mechanical properties is of concern as it could reduce operational life and increase maintenance costs.

Advanced Aluminium Products for Aircraft Structural Components
S. Spangel, A. Buerger, Aleris Aluminum Koblenz GmbH, Koblenz, Germany

The aircraft industry is constantly looking for improved materials which offer benefits in terms of performance, weight and cost savings. The application of aluminium in future aircrafts being in competition with fiber reinforced composites requires that the performance capability of modern aluminium alloys is fully utilized. Within the past years Aleris Aluminum has developed several sheet and plate alloys with improved strength and toughness behaviour compared to conventional 7xxx and 2xxx series alloys. This presentation covers the recent sheet and plate developments for aircraft applications by Aleris Aluminum including alloys currently being internationally registered as well as newly developed alloys. The focus will be on alloy AA7081 which is available as plate in a wide thickness range between 1 and 8 inches and various tempers while offering superior strength combined with a high fracture toughness compared to conventional 7xxx series alloys. Applications for alloy 7081 may include wing components or fuselage frames. The demand for lighter structures and advanced manufacturing technologies has accelerated the development of AlMgSc alloys. With a density in the range of today’s Al-Lithium alloys, their excellent fatigue and damage tolerance properties, good corrosion resistance and very good weldability AlMgSc alloys offer huge benefits in terms of weight and cost savings. Currently AlMgSc alloys are being considered for applications in future aircraft structures. The application of advanced manufacturing technologies such as Laser Beam and Friction Stir welding in combination with a subsequent creep forming process simplifies further integration of structural components and offers additional weight and cost reduction potential. The overall process chain will be improved. The fabrication of current Aleris AlMgSc alloys and an outlook on new developments by Aleris on AlMgSc type alloys will be discussed. Furthermore, latest results on the new Aleris HDT 2xxx alloy (KO8144) for sheet applications will be presented.  

Linking Microstructure and Strength in Friction Stir Welded Thick Wing Stringer Sections
A. Sullivan, J. D. Robson, The University of Manchester, Manchester, United Kingdom

Joining relatively thick stringer sections using the Friction Stir Welding technique is beneficial due to the potential strength gain and weight saving over fusion welding techniques.  Optimised welding parameters have been used to produce 20mm Friction Stir Welds which have subsequently undergone microstructural analysis using SEM, TEM and SAXS techniques.  Friction Stir Welding has been carried out within the AA7449 ageing sequence, the alloy initially being in a temper for age forming prior to welding and subsequently (post weld) overaged to a T7 in service condition.  Each of the processing steps including the parent material, post welding and after post weld heat treatment have undergone microstructural characterisation.  This provides a detailed description of the effect of the processing on the microstructure and relates this to the strength of the joint.  Quantification has been carried out in terms of the welding zones, nugget, TMAZ, HAZ and also the parent (unaffected) material.  Hardness maps have been produced for each of the weld conditions and are linked with maps of particle radius relating strength to the microstructure throughout the weld.  A simple hardness model has been developed and linked to an existing thermal model, which together provide a reasonable prediction of hardness across the weld zone.  In contrast to most sheet applications the thermal histories present in thick plate Friction Stir Welds have been found to promote extensive strengthening phase precipitation in the nugget region but conversely reducing post weld natural ageing.  Subsequent heat treatment to the T7 condition reduces the strength of nugget zone and parent material but has little effect on the HAZ minimum and location.

Kaiser Investments and Development of Select® Products for Aerospace
R. Nash1, P. Ainsworth1, R. Parkinson2, (1)Kaiser Aluminum, Spokane, WA, (2)Kaiser Aluminum, Foothill Ranch, CA

Kaiser Aluminum is investing $231 Million to increase both the capabilities and capacity to produce SELECT® plate and extrusions.  Nearly $139 Million of this investment has been dedicated to the Trentwood rolling mill for the installation of new heat treat furnaces, a large stretcher, an advanced ultrasonic inspection system, and an automated transportation system. These new facilities have expanded the Kaiser plate thickness capability up to 10ins [100 – 254mm].  A group of new products for a variety of aerospace companies have been developed and qualified using a new rapid development methodology.

Validation of Innovative Concepts Through Mid-Size Demonstrators at Alcan Aerospace
J. C. Ehrstrom, F. Lemaitre, Alcan, Voreppe, France

Developing new materials in parallel with introduction of innovative concepts is recognized as the route to rapid improvement of aircraft structures weight efficiency. In addition to the work in Integrated Project Teams publicized previously, ALCAN set the objective to demonstrate the potential of some design features generically. These ideas will be further developed within the specific constraints of each Original Equipment Manufacturer.

 The concept of crenellations was proposed by ALCAN five years ago with the presentation of simulation results. Tests on mid-size demonstrators (typically 1-m wide stiffened panels) have shown that over-thicknesses in the skin retard the crack largely so that a 15 to 25% weight reduction potential is achieved. The crenellations were shown to work under variable amplitude loading, for bottom wing and upper wing alloys, as well as on welded fuselage sections. Tests were conducted internally on a 1000 KN, a 2500 KN machine, and in external labs including the GKSS.

 The experience gained from several series of tests allowed derivation of analytical rules to help optimize the design of crenellations.

 The concept of local over-thicknesses can also be interesting in compression as is demonstrated with sub-stiffened panels (stiffened panels having small intermediate pad-ups of different geometries stabilizing the skin). Tests on sub-stiffened panels were made at ALCAN and in collaboration with the Queen’s University Belfast.

 Bonding, in particular of top-hat stringers was known as an efficient concept and merits reconsideration. Tests on panels with bonded stringers show a 15% benefit in compression and large benefit in fatigue crack growth over riveted or integral designs. In addition, bonding of aluminum-lithium alloys does not bring any specific issue.

 A five years program of demonstrators testing shows that combining new alloys and new concepts can improve the weight of aluminum aircraft structures by about 25% versus the conventional 2000 technology.

Model Development and Implementation/Validation

Material and Process Model Development

TC-PRISMA, a New Tool for Simulation of Precipitation Reactions in Alloys
A. Engström1, H. Strandlund1, X. Lu1, Q. Chen1, P. Mason2, (1)Thermo-Calc Software AB, Stockholm, Sweden, (2)Thermo-Calc Software Inc, McMurray, PA

A new software tool, TC-PRISMA, for simulation of precipitation reactions in multicomponent alloys has been developed. Based on accurate models for nucleation, growth and coarsening, simulations of heat treatment may be performed under realistic conditions and a large number of different quantities may be calculated.

 The nucleation models implemented into this new software accounts for heterogeneous nucleation and several different types of nucleation sites are considered. The models used for calculation of particle growth rate take the effect of finite interface mobility into account and growth under ortho- as well para-equilibrium may be considered.  To ensure high predictive capabilities thermodynamic, kinetic and property databases assessed by the CALPHAD method are used for calculating diffusivities and surface energies.

 In this presentation it will be shown how TC-PRISMA can be applied for calculating average quantities, particle size distributions and transformation diagrams in steels during industrial heat treatment.

Modeling and Simulation of Oxidation Using DICTRA
S. Hallstrom, L. Hoglund, J. Agren, KTH, Stockholm, Sweden

A long missing feature in the diffusion simulation software DICTRA has been the diffusion in complex phases with many sub-lattices, for example complex oxides. Recently, this capability was implemented, and in this talk we present some results of the current achievements.

DICTRA can now treat diffusion in basically any oxide, provided that there is diffusion data available and that the necessary mobilities have been assessed. The first system to be addressed was the important Fe-O system. It contains three different oxides, from the simple wustite to the complex magnetite, which has the spinel structure. The current  approach was successful, and the work was continued with the Cr-O system and the technically important Fe-Cr-O.

We will show the diffusion models and the results of the assessment, as well as successful simulations of oxidation where layers of oxides grow on top of an Fe or Fe-Cr substrate.

A Finite Element Model for TBC Damage Detection and Lifetime Prediction
A. Luz, D. Balint, K. Nikbin, Imperial College London, Lisbon, Portugal

Thermal Barrier Coatings (TBC) have been used for almost three decades for heat insulation in high-temperature components to increase efficiency. Reliable diagnostic techniques that are practical to implement are needed to identify the location and severity of degradation in TBCs to protect against premature TBC failure. Luminescence spectroscopy has been utilized in detecting early damage, as it exhibits monotonic changes in the spectral characteristics with damage. Nevertheless there is still no agreement on what are the best spectral parameters that indicate damage. A new Finite Element model is presented, which is used to make realistic predictions of TBC lifetime, from as-manufactured to critically damaged. The aim of the modelling is to accurately incorporate all observed behaviour for a specific coating while retaining computational feasibility. To simulate damage accumulation and delamination the finite element model has been used to run several thermal cycles during which nucleation, propagation and coalescence of cracks is incorporated. A variety of cracking scenarios have been studied. The stress field of the oxide layer determined by the finite element model is subsequently converted into luminescence spectrum. Each stress level is represented by a Gaussian-Lorentzian shape function and by adding all the different stresses within the probed volume, the whole spectrum is obtained. The predicted luminescence spectrum for several cracks is used to identify characteristic spectral features that can be employed to accurately predict TBC lifetime.

Microstructure Material Models to Design Higher Reliability for Electronic Components
R. V. Pulikollu1, K. Line1, M. Kayyar2, (1)VEXTEC, Brentwood, TN, (2)VEXTEC Corporation, Brentwood, TN

Electronic interconnects and solder joints traditionally have been designed using rules of thumb developed from experience.  Therefore, the mechanical design of solder joints has not been able to take advantage of optimization because of limitations in analysis methods and in testing.    

 

New OEM support arrangements such as performance based logistics and power-by-the-hour are creating financial incentives for electronics suppliers to develop systems with higher reliability.   VEXTEC analysis methodology and microstructure durability analysis capabilities allow the reliable life of electronics to be virtually optimized before design and testing begin. Our studies have shown that through analysis we can determine the changes in the shape of Ball Grid Array (BGA) solder to increase durability life by as much as three times.  This will translate into electronic packages with substantially higher life and reduced system maintenance costs for the OEM and system operator. 

 VEXTEC offers this capability as a service to electronic manufacturing OEMS.

Simplified 2D Transient Modeling of Splat Formation: Application to Zirconia
K. Fataoui, spcts University of Limoges CNRS UMR6638, limoges, France

Since the nineties many works have been devoted to splat formation modeling taking into account the molten droplet impact on to a flat surface, its flattening and solidification occurring during flattening. They were mainly developed by the team of Professor J. Mostaghimi in department of mechanical engineering of the University of Toronto (Canada) and resulted in commercial code Simulent Drop ® The model of Toronto allows calculating particle flattening splashing as well the real contact between splat and smooth substrate. The aim of this work is to test if 2D simplified model allows determining the real contact splat substrate and compare the results with experiments and the results of 3-D model.

This simplified modeling is based on the Navier-Stokes equations, with added term to account for surface tension, including a constant contact angle to describe the transport of mass and momentum. The fluid flow was assumed to be Newtonian, lamina rand incompressible. The normal stress was asserted as the only stress applying to free surface. The equations were discretized by finite elements techniques in 2-D Eulerian structured grid.

The free surface deformation was tracked by level function  used to smooth the density and viscosity jump across the interface between inner droplet ( ) and surrounding atmosphere ( ).

Density, surface tension, viscosity of impacting liquid particle were assumed to be temperature dependent. Fluid flow boundary conditions were no slip and no-penetration at solid surface.

The particle conditions at impact (temperature and velocities for a given diameter) were calculated thanks to the Jets&poudres model [1] with usual zirconia particles plasma spray conditions.

References

[1]   http://Jets.poudres.free.fr

Since the nineties many works have been devoted to splat formation modeling taking into account the molten droplet impact on to a flat surface, its flattening and solidification occurring during flattening. They were mainly developed by the team of Professor J. Mostaghimi in department of mechanical engineering of the University of Toronto (Canada) and resulted in commercial code Simulent Drop ® The model of Toronto allows calculating particle flattening splashing as well the real contact between splat and smooth substrate. The aim of this work is to test if 2D simplified model allows determining the real contact splat substrate and compare the results with experiments and the results of 3-D model.

This simplified modeling is based on the Navier-Stokes equations, with added term to account for surface tension, including a constant contact angle to describe the transport of mass and momentum. The fluid flow was assumed to be Newtonian, lamina rand incompressible. The normal stress was asserted as the only stress applying to free surface. The equations were discretized by finite elements techniques in 2-D Eulerian structured grid.

The free surface deformation was tracked by level function Φ  used to smooth the density and viscosity jump across the interface between inner droplet ( Φ=0) and surrounding atmosphere (Φ=1 ).

Density, surface tension, viscosity of impacting liquid particle were assumed to be temperature dependent. Fluid flow boundary conditions were no slip and no-penetration at solid surface.

The particle conditions at impact (temperature and velocities for a given diameter) were calculated thanks to the Jets&poudres model [1] with usual zirconia particles plasma spray conditions.

References

[1]   http://Jets.poudres.free.fr

Since the nineties many works have been devoted to splat formation modeling taking into account the molten droplet impact on to a flat surface, its flattening and solidification occurring during flattening. They were mainly developed by the team of Professor J. Mostaghimi in department of mechanical engineering of the University of Toronto (Canada) and resulted in commercial code Simulent Drop ® The model of Toronto allows calculating particle flattening splashing as well the real contact between splat and smooth substrate. The aim of this work is to test if 2D simplified model allows determining the real contact splat substrate and compare the results with experiments and the results of 3-D model.

This simplified modeling is based on the Navier-Stokes equations, with added term to account for surface tension, including a constant contact angle to describe the transport of mass and momentum. The fluid flow was assumed to be Newtonian, lamina rand incompressible. The normal stress was asserted as the only stress applying to free surface. The equations were discretized by finite elements techniques in 2-D Eulerian structured grid.

The free surface deformation was tracked by level function  used to smooth the density and viscosity jump across the interface between inner droplet ( ) and surrounding atmosphere ( ).

Density, surface tension, viscosity of impacting liquid particle were assumed to be temperature dependent. Fluid flow boundary conditions were no slip and no-penetration at solid surface.

The particle conditions at impact (temperature and velocities for a given diameter) were calculated thanks to the Jets&poudres model [1] with usual zirconia particles plasma spray conditions.

References

[1]   http://Jets.poudres.free.fr

“Parametric Study of Machining Effect on Residual Stress and Surface Roughness of Nickel Base Super Alloy UDIMET – 720”

Application of Material and Process Modeling - 1

The Application of Bayesian Neural Network Modeling for the Prediction of Tensile and Fracture Toughness Properties in Alpha/Beta Titanium Alloys
S. K. Koduri1, V. Dixit1, P. C. Collins2, H. L. Fraser3, (1)The Ohio State University, Columbus, OH, (2)Quad City Manufacturing Lab, Rock Island, IL, (3)Center for Accelerated Maturation of Materials, Columbus, OH

The development of computational tools that permit microstructurally-based predictions for tensile and fracture toughness properties of commercially important titanium alloys is a valuable step towards the accelerated maturation of materials. This talk will discuss the development of Neural Network Models based on Bayesian statistics to predict the yield strength, ultimate tensile strength and toughness of Ti-6Al-4V at room temperature. The development of such rules-based models requires the population of extensive databases which contain both compositional and microstructural information. These databases have been used to train and test Neural Network models to predict the tensile and toughness properties. In addition, these models have been successfully used to identify the influence of individual microstructural features on the mechanical properties, consequently guiding the efforts towards development of more robust phenomenological models. The influence of the individual microstructural features on tensile and toughness will be discussed.

Utilization of Modeling Tools for Extrusion Process Optimization
D. Li1, E. Crist2, N. Minakawa2, O. Yu2, (1)RTI International Metals, Inc., Niles, OH, (2)RMI Titanium Company, Niles, OH

Computer modeling programs have been used to optimize the extrusion processes.  First, an induction heating modeling program has been developed to predict the temperature profile of billets during induction heating and soaking processes.  With the help of this program, induction heating equipment is capable of achieving desired temperature profile and reducing variation between pieces with different diameters.  Finite element modeling software (DEFORM) is used to study the metal flow during extrusion to achieve balanced flow at the outlet.  It is also used to evaluate different die designs with considerable savings of time and expense because the amount of trial-and-error testing is reduced.

Use of 3-D Simulation to Control Melt Pool Size and its Temperature in Complex Deposits with Laser Additive Manufacturing
A. B. Chaudhary, M. Keller, Applied Optimization, Inc., Dayton, OH

<>Control of melt pool size and its temperature is important to attaining consistent solidification conditions in laser additive manufacturing. The laser power and speed that will result in such consistency is unknown a priori because the temperature field evolves continuously during the deposition and the geometry of the deposit can vary from one location to another. This paper describes a hands-off automated simulation of laser additive manufacturing. It is developed to solve for the laser power and velocity conditions that control melt pool size and its temperature to user-specified values under complex deposit conditions. The solution outputs the evolving temperature and stress fields as the deposit progresses. It also computes the thermal gradient and velocity of the solidification front for the purpose of correlation with resulting microstructure.  Sample solutions will be presented.

Finite Element Weld Modeling for Aerospace Applications
Y. P. Yang1, I. Harris1, G. Ritter1, B. Bishop2, (1)Edison Welding Institute, Columbus, OH, (2)Edison Welding Institute, columbus, OH

Welding and cladding have been considered to use in aerospace industry, especially friction stir welding (FSW), laser beam welding (LBW), laser weldbonding (LWB), and laser additive manufacturing (LAM).  Finite element weld modeling has been playing an important role in developing these processes, such as selecting welding parameters for new geometries and materials, optimizing welding sequences for distortion mitigations, and so on.  This paper attempts to review the recent weld modeling applications for aerospace industry, particularly LBW and LWB, in Edison Welding Institute (EWI). 
Laser welding was used in assembling a thin-panel structure for aerospace applications. The structure consists of a thin plate with many L-shape stiffeners.  LBW was used to join the stiffeners to the thin plate.  Welding-induced buckling distortion was a major concern.  To control the buckling distortion, a three-roller system was designed with the help of finite element weld modeling. Finite element model was used to optimize the relative distances between the laser and the rollers.  This improved LBW process has been successfully used to weld the structure by eliminating buckling distortion and producing low weld residual stresses.  
Laser weldbonding is a process combining use of a welding method and adhesive bonding in the same joining process. It has been demonstrated to weld an aluminum aerospace structure.  Weldbonding offers the potential of greater structural rigidity at lower weight, lower metal gauge, and lower cost over traditional riveting. Finite element modeling was performed to compare the stress characteristics in a laser weldbonded structure and a riveted structure.  The analysis results show more preferred stress distributions in the laser weldbonded structure than the riveted structure.  Experimental results also show the weldbonded structure has higher load carrying capability.
In addition, this paper also briefly introduces the modeling of FSW in joining titanium structures, and LAM in repairing engine blades.

Modeling and Experimental Analysis of Micron Surface Dents and Mechanical Behavior During Laser Shock Peening Ti-6Al-4V
M. P. Sealy1, Y. Guo1, S. Chen2, (1)The University of Alabama, Tuscaloosa, AL, (2)University of Texas at Austin, Austin, TX

Laser Shock Peening (LSP) is a mechanical process where pressure waves caused by expanding plasma plastically deform the surface of a material. Typically, LSP is applied to metals as a form of surface treatment. As a result, the mechanical properties on the surface are enhanced to improve the performance of fatigue, wear, and foreign object damage (FOD).

Titanium Ti-6Al-4V is a widely used engineering material in aerospace, automotive, and biomedical industries. Surface integrity induced by LSP of Ti-6Al-4V components is critical for product performance. However, the surface deformation and mechanical behavior in peening a Ti-6Al-4V surface has not been well understood. The research aims to understand the laser/ Ti-6Al-4V interaction, surface dent, and the related mechanical phenomena.

A 3D finite element model has been developed to simulate micro scale laser shock peening of Ti-6Al-4V. The 3-dimensional Spatial and Temporal Shock Pressure Load was modeled using a developed load user subroutine. The dynamic mechanical behavior at high strain rates has been modeled using an internal state variable (ISV) plasticity model via a material user subroutine VUMAT which was coded into finite element software ABAQUS. Surface dent profile was simulated and favorably agrees with the measured geometry in terms of dimension and shape. Two simulation schemes at constant peak peening pressure and constant peening time were performed. Surface material behavior including stresses, strains, and strain rates along the peening or depth direction and along the radial direction were examined. A few interesting difference in mechanical phenomena between the surface and subsurface have been identified.

Keywords: laser shock peening, surface dent, titanium, dynamic mechanical behavior, finite element analysis

Property Analysis of a High Performance Cu-Ni-Sn Spinodal Alloy
W. R. Cribb1, F. C. Grensing2, (1)Brush Wellman Inc., Cleveland, OH, (2)Brush Wellman Inc., Elmore, OH

Spinodally hardened Copper-Nickel-Tin alloys have been under development for over 40 years.  With considerable development effort, the ToughMet® class of Copper-Nickel-Tin alloys have become materials of commerce.  One wrought temper, ToughMet® 3 AT110 (UNS C72900), has become the material of choice in high performance wear-critical applications.  In preparation for AMS and MMPDS design allowables listing, substantial testing data was generated, including basic tensile and compression mechanical properties, pin bearing performance and shear strength over a wide rod and tube diameter size range.
Property performance will be described in detail and an initial overview of basic work hardening and fracture characteristics will be presented, including key inputs to modeling and design.

Application of Material and Process Modeling - 2

Modelling of Processing and Materials Phenomena in Nickel-Based Superalloys
R. C. Reed1, J. C. Gebelin1, N. Warnken1, P. Brown2, (1)University of Birmingham, Birmingham, United Kingdom, (2)Rolls-Royce plc, Derby, United Kingdom

At the University of Birmingham, we have established recently a new facility for the computer modelling of processing and related materials phenomena, whose remit emphasises applications for aeroengines. This is known as the 'Partnership for Research in the Simulation of Manufacturing and Materials', or PRISM2. The aim of this partnership is to bring together organisations with an interest in process simulation, i.e. universities, companies, software developers and hardware providers, in order to develop computer-based methods and software tools that facilitate component manufacture and optimisation, and the integration of these topics into the design and through-lifecycle analysis of these parts for aeroengine applications. Processes under consideration include casting, sheet forming, welding and heat treatment. In this paper PRISM2 will be introduced and some details of the work being carried out will be presented.

Computational Materials Science Techniques to Identify Ni-base Superalloys for IGT Applications
S. A. Tapia, G. E. Fuchs, University of Florida, Gainesville, FL

The successful use of single-crystal alloys in IGT applications is contingent upon overcoming processing problems such as defect formation, and maintaining microstructural stability once in service.  The present work uses a design approach aimed toward the development of a set of alloys for industrial gas turbine application. In the hopes of better understanding elemental variation effects on the aforementioned material properties, a baseline alloy composition named the baseline ‘Model’ alloy (based on CMSX-4 and PWA 1483) was used as the foundation from which two iterations of ‘elemental variation effect’ evaluations were conducted (‘Phase I’ and ‘Phase II’).  The thermodynamic equilibrium module in the JMatPro Program was utilize to evaluated ‘Phase I’ and ‘Phase II’ theoretical property trends and determine chemistry modifications to the baseline ‘Model’ alloy.  Five variant alloy compositions were tailored using JMatPro modeling techniques and were laboratory tested for validation purposes.  To address the effects of additions previously shown to influence hot corrosion and material stability, final compositions incorporated characteristic variations of Al/Ti ratio (with Ta variation), Cr (with Al and Ta variations), and Re content for comparison.  This study evaluates the computational capabilities of the JMatPro thermodynamic equilibrium module to predict material properties related to defect formation and microstructural stability.  Through computational techniques this work also contributes to a better understanding of elemental variation effects on microstructural stability, phase transformation temperatures, and material segregation behavior to facilitate the development of better alloys for future single crystal IGT use.

Phase-field Simulation of Microstructure Formation During Solidification and Homogenisation Processing of Single Crystal Superalloys
N. Warnken, R. C. Reed, University of Birmingham, Birmingham, United Kingdom

Precipitation Simulation of Nickel-Base Superalloys
F. Zhang1, K. -. S. Wu1, W. -. S. Cao1, S. -. L. Chen1, Y. A. Chang2, D. U. Furrer3, (1)CompuTherm, LLC, Madison, WI, (2)University of Wisconsin, Madison, WI, (3)Roll-Royce Corporation, Indianapolis, IN

The understanding and control of the precipitation of secondary phases during heat treatments is critical for the properties of age-hardening superalloys. A modeling tool has been developed at CompuTherm to simulate the complicated precipitations and microstructure evolutions during arbitrary thermal histories.
The modeling tool, which is part of the Pandat™ software, integrates both thermodynamic calculation and kinetic simulation. Thermodynamic calculation provides driving force of precipitation while thermodynamic and mobility databases are also needed for providing model parameters. The package is designed for generalized applications while in this presentation the investigation is focused on nickel alloys 718 and U720. In this presentation, we will present the general features of this modeling tool and some calculation results for the two nickel alloys. The output results include the amount and size change of each precipitate phase with time, particle size distribution, TTT curves and so on. One unique feature of this modeling tool that offers tremendous help for alloy design is a global optimization module for search of the best or worst scenario given alloy chemistry range and heat treatment conditions. This feature will be discussed in this presentation as well.

Numerical Modelling of the d-Phase Precipitation Kinetics in the Superalloy Allvac 718PlusTM
M. Stockinger1, C. Stotter2, C. Sommitsch2, E. Kozeschnik3, (1)Böhler Schmiedetechnik GmbH & Co KG, Kapfenberg, Austria, (2)Christian Doppler Laboratory of Materials Modelling and Simulation, University of Leoben, Leoben, Austria, (3)Christian Doppler Laboratory for Early Stages of Precipitation, Graz University of Technology, Graz, Austria

Aerospace gas turbine discs operate in an environment of relatively high stresses caused by centrifugal forces and elevated temperatures. These severe conditions require materials with excellent high temperature properties. Recently, the new alloy Allvac 718PlusTM was developed to further increase the service temperature by at least 55°C while retaining a comparable processability to alloy 718. The properties of gas turbine disks are sensitive to the microstructure, e.g. grain size and precipitations, which depend on the processing history. The interest in microstructure modelling has gained considerable momentum over the past two decades. However, most of the published models are of Avrami type, which have no predictive capabilities with regard to second-phase precipitation. In order to obtain an adequate final microstructure and hence optimized mechanical properties it is necessary to predict the precipitation history as a function of temperature. The results of the simulations are fed into a physical-based microstructure model.

In this paper, we present experimental results on the δ-phase precipitation kinetics in Allvac 718PlusTM. Based on this data, computer simulations were performed using the precipitation kinetics module of the software package MatCalc. Experimental data and simulation results, i.e. time-temperature–precipitation (TTP) diagrams, were compared in order to calibrate the precipitate-matrix interfacial energy. Annealing experiments were performed and the fraction of δ-phase precipitates was determined by means of quantitative optical microscopy. Additionally, differential scanning calorimetry (DSC) investigations were carried out to determine the solution temperature of the δ-phase. The results of the calculations obtained using a temperature-dependent interfacial energy were in good agreement with the experiments.

Modelling of Crack-Tip Deformation and Crack Growth in a Nickel-Based Superalloy at High Temperature
L. Zhao, J. Tong, University of Portsmouth, Portsmouth, United Kingdom

Modelling of crack tip deformation and crack growth in a nickel-based superalloy at elevated temperature has been carried out for a compact tension (CT) specimen using the finite element method. A unified viscoplastic model with non-linear kinematic and isotropic hardening rules has been adopted to describe the material constitutive behaviour. The material model was implemented in the finite element software ABAQUS via a user-defined material subroutine (UMAT). Finite element analyses for stationary cracks showed distinctive strain ratchetting behaviour near the crack tip at selected load ratios, leading to progressive accumulation of tensile strain normal to the crack growth plane. Results also showed that low frequencies and superimposed hold periods at peak loads significantly enhanced strain accumulation at crack tip.

Finite element simulation of crack growth was carried out under a constant ΔK-controlled loading condition. Similar to stationary crack analysis, crack tip deformation for a growing crack also shows the distinctive feature of strain accumulation. Lower frequency and longer dwell period enhance strain ratchetting and strain accumulation. This is consistent with the observed dependency of crack growth rate on frequency and dwell period from the experimental results, i.e., faster crack growth rate at lower frequency and longer dwell period. A crack growth criterion based on strain-accumulation is proposed where a crack is assumed to grow when the accumulated strain ahead of the crack tip reaches a critical value over a characteristic distance. The criterion has been utilised in the prediction of crack growth rates in a CT specimen at selected loading ranges, frequencies and dwell periods, and the predictions were compared with the experimental results. During crack growth simulation, crack closure behaviour was also examined using the standard compliance offset method for both plane strain and plane stress cases, and confirmed the lack of crack closure for plane strain condition.

Role of Microstructure and Environment on Dwell Fatigue Crack Growth in a Nickel-Based p/m Superalloy
S. Kirchhoff, K. Maciejewski, H. Ghonem, University of Rhode Island, Kingston, RI

The influence of microstructure and environment on interganular crack growth in a P/M nickel base superalloy subjected to loading cycles with hold time has been examined. Research studies have shown that the sizes and spatial distributions of the γ’ precipitates have a measurable influence on the yield strength of Nickel based superalloys. This is due to the fact that these small precipitates make the lattice planes highly resistant to slip band formation at high temperature. The role of the strengthening phases of the microstructure on crack tip damage resistance is not well understood. Furthermore, dwell loading in air environment is known to promote crack tip damage acceleration due to the diffusion of air species, particularly oxygen. The role of microstructure on crack growth rate has been examined through variations in temperature, duration and cooling rates of the heat treatment stages; solutioning, stabilization and aging.  Influence of long term exposure at 650°C, a typical service temperature, has also been examined. The changes in the size and volume fraction of the secondary γ’ as well as the formation and development of carbides associated with the modified microstructures were determined through SEM observations. A series of crack growth experiments with different hold times ranging from 100 seconds up to 2 hours has been carried out at 650oC and 700 oC in both air and vacuum environment.  The microstructure of the test specimens included the as received conditions as well as microstructures which have seen modified heat treatment cycles.  Results of these tests were compared and used to identify the roles pertaining to microstructure variations and environment on dwell crack growth damage mechanisms.

Material and Process Modeling Support for Problem Solving and Optimization

A Coupled Creep-Plasticity Model for Relaxation of Shot-Peened Residual Stresses in a Nickel-Base Superalloy
D. J. Buchanan1, R. John2, R. A. Brockman1, (1)University of Dayton Research Institute, Dayton, OH, (2)US Air Force Research Laboratory, Wright-Patterson AFB, OH

Shot peening is a commonly used surface treatment process that imparts compressive residual stresses into the surface of metal components.  Compressive residual stresses retard initiation and growth of fatigue cracks.  During the component loading history, the shot-peened residual stresses may change during cyclic loading, or during elevated temperature static loading, such as thermal exposure and creep.  In these instances, taking full credit for compressive residual stresses would result in a nonconservative life prediction.  As a result, designers are reluctant to incorporate any compressive residual stresses into fatigue life predictions of turbine engine components, subject to elevated temperatures and inelastic loading conditions.

This research describes a methodical approach for characterizing and modeling residual stress relaxation under elevated temperature loading, near and above the monotonic yield strength of IN100.  The model incorporates the dominant creep deformation mechanism, coupling between the creep and plasticity models, and effects of prior plastic strain.  The initial room temperature residual stress and plastic strain profiles provide the initial conditions for relaxation predictions using the coupled creep-plasticity model.  Model predictions correlate well with experimental results on shot-peened dogbone specimens subject to cyclic and creep loading conditions at elevated temperature.  The predictions accurately capture both the shape and magnitude of the retained residual stress profile.

Modeling of Transport Phenomena and Numerical Simulation of Lack of Fusion during Laser Deposition
J. W. Newkirk1, H. N. Chou2, Z. Fan1, F. Liou1, K. Slattery2, M. E. Kinsella3, (1)Missouri University of Science & Technology, Rolla, MO, (2)Boeing Phantom Works, St. Louis, MO, (3)AFRL/RXLMP, Wright-Patterson AFB, OH

Direct laser deposition is a solid freeform fabrication process that has the capability of direct fabrication of metal parts. The part is fabricated in a layer-by-layer manner in a shape that is dictated by the CAD solid model. A primary objective of laser deposition is to achieve porosity free deposited layers with good metallurgical bonding and minimal dilution. Of the common defects in laser deposition, lack-of-fusion (LOF) is the most damaging since it may act as a crack under certain loading conditions. This work presents prediction of LOF using a comprehensive heat transfer/fluid dynamics coupled model. This model is used to simulate the coupled, interactive transport phenomena between laser, powder, and the substrate during the laser deposition process. The simulation involves laser material interaction, free surface evolution, droplet formation, transfer and impingement onto the substrate, and melt-pool dynamics. Transient temperature and velocity distributions of the falling particles and melt pool as well as melt pool geometry are calculated in a single model, using the continuum formulation and the volume of fluid technique. Experimental validation of model predictions is also presented.

Evolution of Approaches to HIP Modeling
V. Samarov, V. Goloveshkin, D. Seliverstov, LNT PM Inc., Garden Grove, CA

The general task of HIP modeling is in designing the initial shape of the HIP tooling providing the final “net” or “near net shape” part after HIP consolidation of powder. It is well known that there are no precise mechanical models of material behavior for stress and temperature conditions far beyond the yield level typical for HIP. Therefore in most of the cases the initial adequacy of the constitutive equations does not enable to provide the necessary precision of modeling. The real process of adequate mathematical modeling for this complex technological process comprises one or two iterations when after the first modeling and its experimental verification , the necessary corrections are installed into the model. The core of modeling is the description of the mutual deformation of the compressible (powder) and non-compressible (HIP tooling) materials. The paper presents the evolution of the models providing adequate description of the HIP deformation  for parts of   different geometrical complexity and physical non-uniformity mainly used for the aerospace applications.

Finite Element Modeling of Drilling Processes with Solid and Indexable Tooling in Metals and Stack-ups
T. Marusich1, S. Usui1, D. A. Stephenson1, L. N. Zamorano1, A. J. Shih2, (1)Third Wave Systems, Minneapolis, MN, (2)University of Michigan, Ann Arbor, MI

Aerospace manufacturing relies heavily on drilling processes. Aerospace drilling operations focus on holes for rivets loaded in shear in aluminum, titanium and composite stack-ups. Optimal chip flow and tool life are often in competition with burr formation, general hole quality and cycle time. Physics-based modeling of drilling processes can provide insight and information not readily available or easily obtained from experiments, and in a much faster time frame.

 A three-dimensional finite element-based model of drilling is presented which includes fully adaptive unstructured meshing, tight thermo-mechanically coupling, deformable tool-chip-workpiece contact, interfacial heat transfer across the tool-chip boundary, and constitutive models appropriate for process conditions and finite deformation analyses.  Explicit modeling of entrance, steady-state and exit modeling of aluminum and titanium materials, as well as metal stack-ups is performed. Drilling through stack-up layers is also shown. The modeling includes both solid twist and indexable drills. Metal cutting tests are performed and comparison with predicted data is provided.

Finite Element Simulation of Factors Influencing Surface Integrity in Metal Cutting Processes
C. E. Fischer, Scientific Forming Technologies Corporation, Columbus, OH

Disturbance of part surface integrity by a metal cutting process can substantially decrease the fatigue life of a component, and introduce other difficulties in subsequent metal removal operations.  Fatigue behavior is influenced by residual stress distribution near the surface, and by surface microstructure changes, commonly known as “white layer” formation.  

Finite element simulation of the metal cutting process offers an opportunity to gain a better understanding of the role of cutting parameters on surface integrity.  Cutting speed, rake angle, tool edge preparation, tool wear, and coolant all play key roles in residual stress and surface microstructure changes.  With simulation, limits can be established which optimize cutting performance and avoid abusive regimes of cutting parameters or tool wear.

While there are still opportunities for improved understanding of residual stress, this is an area which has received substantial attention in the literature.  Several elastic-plastic finite element codes offer residual stress calculations, so there have been numerous papers published regarding residual stress simulation and measurement.

The capability to incorporate microstructure evolution into a finite element simulation of metal cutting is unique.  Software featuring microstructure integrated process simulation is demonstrated.  Microstructure models interact with deformation, stress, and thermal models to provide prediction of grain size and phase transformations.  Case studies demonstrating model capabilities will be presented.

Finite Element Modeling of Part Distortion
T. Marusich, S. Lankalapalli, L. Zamorano, J. Backus, S. Heyroth, K. Marusich, Third Wave Systems, Minneapolis, MN

Machining of large monolithic structures is becoming a standard in today’s aerospace world.  Driven by cost, as well as performance, it is becoming necessary to machine these parts better, faster, lighter and cheaper than ever before.  When machining these large monolithic structures, deformation becomes a large problem.  The typical solution to this problem is machine with lower than optimum material removal rates and do additional fixture rotations which adds unnecessary time and cost to the manufacturing process.  A Finite Element Model has been developed specifically to predict and control these distortions.  The model takes into consideration the machining induced residual stresses as well as the bulk stresses in the material from the manufacturer.  It is the combination of these two residual stress components coupled with the geometry of the part and type of material that allows us to accurately predict, manage and control the shape and magnitude of deformation in large thin walled structures.  The model can be used to determine the ideal cutting conditions for the process as well as determine the best location within the stock plate to machine the part from.  Multiple machining tests have been done in order to validate the accuracy of the model.  Being able to predict distortion will change how parts are machined.  Distortion prediction can be deeply integrated into the manufacturing process as far back as initial part design.

Plenary Program

Plenary Session

Revolutionizing Aircraft Assembly – Overview of the Eclipse 500
B. K. Christner, Eclipse Aviation Corporation, Albuquerque, NM

Application of Materials Technology in the Design of Future Turbine Engines
M. Gritton, Rolls-Royce Corporation, Indianapolis, IN

Composite Propeller Blades: Design, Manufacture and Development
T. Wybrow, Dowty Propellers, Gloucester, United Kingdom

Dowty Propellers have established themselves as world leaders in composite aircraft propeller design and manufacturer. From early developments made on hovercraft more than thirty years ago, the composite technology and the company have developed over the years into a world leading position. Currently Dowty propeller systems can be found on a variety of both civil and military aircraft (turbo-props in the region of 4000-12,000 SHP) and hovercraft typically used as military landing craft.

 

Some of the key benefits of turbo-props over the more mainstream turbo-fans will be discussed, including; reduced fuel consumption, reduced exhaust emissions and lower operational costs. Furthermore, for military purposes in particular, the thrust available allows take off and landing on a much shorter runway/airstrip than a turbo-fan aircraft would be able to achieve.

 

The key design considerations for composite propeller blades will be explored. These include high strength to weight ratio, high fatigue resistance and damage tolerance. A composite blade also offers the significant advantage of being largely repairable where a metal blade may have to be replaced. As a primary structure of the aircraft, no fatigue or other structural failure is permissible. Composite blades are subject to stringent certification to evaluate the structural integrity, the detail of which will be outlined. Dowty Propellers are responsible for this certification and testing of the propeller, much of which is done in-house.

 

The composite blade manufacture involves a number of different materials and techniques. The processes explored include dry-fibre preforming of carbon and glass fibre, polyurethane foam injection, over-braiding and resin transfer moulding (RTM).

 

New areas for growth will be outlined, including un-ducted fans, as well as a discussion on potential new markets. Furthermore, developments in materials and processing will be explored with a view to future automated composite propeller manufacture.

Superplasticity and Superplastic Forming

Superplasticity Theory, Modeling and New Materials

Low-Temperature Superplastic Flow of Ultrafine Ti-6Al-4V
G. A. Sargent1, D. Li2, S. L. Semiatin3, (1)University of Dayton, Dayton, OH, (2)RTI International Metals, Inc., Niles, OH, (3)Air Force Research Laboratory, Wright-Patterson AFB, OH

The superplastic-flow behavior at low temperatures (650 – 800°C) and a range of strain rates (10-4 to 10-2 s-1) of Ti-6Al-4V with an ultrafine two-phase (alpha/beta) microstructure has been established. Program materials comprised billet product manufactured by warm isothermal (‘abc’) forging, tested in compression, and sheet fabricated by warm rolling, tested in tension. Extensive metallography on undeformed and deformed samples water quenched from the various test temperatures was conducted using backscattered-electron imaging in an SEM to characterize microstructure stability. Despite the low deformation temperatures, both lots of material showed similar (measurable) dynamic coarsening, whose kinetics mirrored the flow-hardening observed during compression and tension tests. The plastic-flow phenomenology was interpreted in the context of the classical Bird-Mukherjee-Dorn relation. Over the entire test-temperature range, the stress and grain-size exponents of the strain rate were ~1.4-2 and ~2, respectively, for strain rates of 10-4 and 10-3 s-1. The constitutive analysis suggested that multiple (dislocation glide-climb and diffusional) mechanisms control deformation, thus complicating the interpretation of the apparent activation energy derived from the plastic-flow data.

+ Currently Consultant with UES at the Air Force Research Laboratory, AFRL/MLLM, Wright-Patterson Air Force Base, OH 45433.

The Effects of Super Plastic Forming on the Mechanical Properties and Hydrogen Content of Titanium Ti 6AL-4V
M. Al Bawaneh, J. Brewer, R. Hedrick, Ducommun AeroStructures Incorporated, Parsons, KS

Super plastic forming (SPF) experiments on Ti-6AL-4V are being carried out at elevated temperatures ranging from 1600 oF to 1700 oF under different process parameters. The key process input parameters of the experiments under investigation are starting material thickness, forming time and pressure. The effects of these parameters on grain size, hydrogen content, alpha case, ultimate tensile strength, yield strength and elongation are the focus of this study.

Superplastic Response of Continuously-Cast AZ31B Magnesium Sheet Alloys
J. M. Boileau, P. A. Friedman, D. Q. Houston, S. G. Luckey, Ford Motor Company, Dearborn, MI

Magnesium sheet is typically produced for commercial applications with the traditional DC-ingot casting method.  As a result of the hexagonal close-packed crystallographic structure in magnesium, multiple rolling passes and annealing steps are required to reduce the thickness of the ingots.  Thus, high fabrication costs characterize the creation of magnesium sheet suitable for common forming operations.  Recently, continuous casting (CC) technology, where molten metal is solidified directly into sheet form, has been applied to magnesium alloys; this method has shown the potential to significantly reduce the cost of fabricating magnesium sheet alloys.   In order to understand the viability of the CC process, a study was conducted to investigate the superplastic potential of alloys produced by this method.  This study focused on AZ31B Mg that was continuously-cast on twin-roll casters from three different suppliers.  These three materials were compared with a production DC-cast AZ31B alloy in terms of microstructure, elevated-temperature tensile properties, and superplastic forming response.  The data from this study found that microstructural features such as grain size and segregation can significantly affect the forming response.  Additionally, the CC alloys can have equivalent or superior SPF response compared to DC-cast alloys, as demonstrated in both elevated temperature tensile tests and superplastic forming trials using a rectangular pan die.

Finite Element Modeling, Simulation, Tools and Capabilities at Superform
H. Raman1, S. Riley2, (1)Superform USA, Riverside, CA, (2)Superform Aluminium, Worcester, United Kingdom

Over the past thirty years Superform has been a pioneer in the SPF arena, having developed a keen understanding of the process and a range of unique forming techniques to meet varying market needs. Superform’s high profile list of customers includes Boeing, Airbus, Aston Martin, Ford and Rolls Royce. One of the more recent additions to Superform’s technical know-how is Finite Element Modeling and Simulation. Finite Element Modeling is a powerful numerical technique which when applied to SPF provides a host of benefits including accurate prediction of strain levels in a part, presence of wrinkles and predicting pressure cycles optimized for time and part thickness. This talk will outline a brief history of Finite Element Modeling applied to SPF and then go into some of the modeling tools and techniques that Superform has applied and continues to do so to successfully make complicated parts. The advantages of employing modeling in the design stages are then presented with real world examples.

Finite Element Analysis of SPF and QPF of AA5083 Sheets
F. Jarrar1, F. K. Abu-Farha2, L. Hector3, M. K. Khraisheh4, P. Krajewski3, (1)University of Jordan, Amman, Jordan, (2)University of Kentucky, Lexington, KY, (3)General Motors R&D Center, Warren, MI, (4)Masdar Institute of Science and Technology, Abu Dhabi, United Arab Emirates

In this work, finite element analysis of superplastic forming (SPF) and quick-plastic forming (QPF) of AA5083 is presented. A microstructure-based constitutive model capable of describing the deformation of the material at different strain rates is used in the simulation. Different forming scenarios (e.g. constant pressure, constant strain rate and variable strain rate) are discussed.

Transformation Superplastic Forming of Cast Titanium Alloys
E. Y. Chen1, Q. Li2, D. R. Bice1, D. C. Dunand3, (1)Transition45 Technologies, Inc., Orange, CA, (2)University of Nevada, Reno, Reno, NV, (3)Northwestern University, Evanston, IL

One approach to expand the application of titanium alloys is to reduce their processing cost by near-net-shape castings.  In near-net shape cast parts, an additional forming step is however sometimes still needed to achieve the final shape with the required tolerances and wall thickness.  Superplastic forming is an attractive option, due to the low stresses needed for deformation and to the relatively low tooling costs.  However, in the as-cast state, titanium and most titanium alloys have a grain structure too coarse to allow deformation by grain-boundary sliding through microstructural superplasticity.  Thus, for most titanium alloys - and in particular for the commercially-dominant Ti-6Al-4V alloy - complicated and costly thermo-mechanical treatments are needed to produce the fine grains with equiaxed shape necessary for microstructural superplasticity by grain-boundary sliding, resulting in high tensile strains (>100%) and low strain-rate sensitivity.  An alternative approach to achieve high tensile strains uses transformation superplasticity which has no grain-size requirement as it relies on the biasing by an applied external stress of internal stresses produced by cyclical phase transformation.  This presentation explores the application of transformation superplastic forming to superplastic form coarse-grain cast titanium.  This work was supported by the National Science Foundation.

Industrial Manufacturing Using Superplastic Forming

SPF: Simply Designing and Forming Complex Parts Successfully
A. J. Barnes1, R. Stracey2, (1)Superform USA, Riverside, CA, (2)Superform Aluminium, Worcester, United Kingdom

Much of the early mystique associated with superplastic forming(SPF) has been replaced by sound economic judgement and by sophisticated computer based part and tool design and process simulation techniques.

This presentation examines the best approach to part design aimed at achieving functional performance and optimized forming conditions utilizing FE analysis and techno-economic evaluation. Modern downstream post-forming trimming methods and assembly techniques are also reviewed.

Innovative Titanium Sheet Metal Engine Aft Fairing Heat Shields for Boeing Commercial Airplanes
L. D. Hefti, The Boeing Company, Seattle, WA

In the past, engine aft fairing heat shields have typically been titanium castings.  With the 737 Next Generation, these components were converted to titanium 6Al-4V sheet metal details fabricated in either a “U” shape using hot sizing or a “V” shape using Superplastic Forming (SPF).  This conversion saved approximately 20% in both cost and weight.  When the 787 was being designed, the engineers were looking to develop a sheet metal version of their heat shields hoping to achieve similar savings.  However, the 787 design was considerably different from the 737 due to “plume suppressors” which no longer allowed the details to be simple “U” or “V” shaped.  Also, the operating environment was more severe with the sonic db level being higher and the temperature being hotter.  The 787 design contains SPF details as well as the first Boeing Commercial Airplane application of Superplastic Forming and Diffusion Bonding (SPF/DB).  The SPF/DB stop-off technology being used contains several innovative process developments that are covered by patent applications.  Some of the heat shield components are fabricated using the world’s first applications of fine grain 6Al-4V titanium, also covered by patent applications, that was developed to SPF at 1450 °F instead of 1650 °F which is used for standard grain material.  Due to the temperature requirements, 6Al-2Sn-4Zr-2Mo titanium had to be used for the lower skin and the internal components that touch the skin.  The 787 heat shield assemblies are estimated to save approximately 15% in both cost and weight.   The 747-8 program has designed heat shields that are very similar to the 787 except the sonic environment does not require the side skins be as stiff so SPF/DB components are not being used.  The 777 is investigating converting to the 787 design that would include SPF/DB hardware.

Some New Developments of Superplastic Forming in the Framework of the euro-spf Group
J. J. Blandin1, W. Beck2, R. Curtis3, G. Bernhart4, (1)Institut National Polytechnique de Grenoble, Saint Martin d Heres, France, (2)FormTech GmbH, Weyhe, Germany, (3)Kings College London, London, United Kingdom, (4)Ecole de Mines d'Albi Carmaux, Albi, France

SuperPlastic Forming (SPF) is used in several industrial sectors in Europe since more than fifty years, the main activity being concentrated in aeronautics. Nevertheless, in the recent past, new applications have arising not only in aeronautics since in this field this technology has several competitors. In this presentation, examples of such recent applications of SPF will be presented. Information will be also given on the Euro-SPF group of which the main goal is to federate the community of European industries and universities involved in SPF.

Superplasticity in Continuous Cast AA5083 Al Prepared Via Friction Stir Processing
M. A. Garcia-Bernal1, R. S. Mishra2, R. Verma3, D. Hernandez-Silva1, (1)Instituto Politécnico Nacional-ESIQIE, D.F., Mexico, (2)University of Missouri – Rolla, Rolla, MO, (3)General Motors, Warren, MI

In this work, the effect of friction stir processing on the superplastic properties of continuous cast AA5083 Al sheets have been investigated, optimizing the Mn content. Three continuous cast AA5083 alloys with different Mn (0.5, 0.75 and 1.0wt.%) concentrations were friction stir processed using several parameters and pins. Ultra-fined microstructures with averages grain sizes of 0.8-2.5μm were obtained. Tensile test revealed that the maximum tensile elongation of 810% was achieved at 530 ºC and 3 x 10-2 s-1 in the alloy with the lowest Mn content. The stability of the microstructure at elevated temperature was the most important issue to overcome.

A Historical Perspective of Developing the Superplastic Forming Process for Aerospace Applications at the Boeing Company
D. G. Sanders, L. D. Hefti, The Boeing Company, Seattle, WA

Superplastic Forming (SPF) was developed concurrently in several different divisions in what has now been consolidated into the Boeing Company.  The evolution from pure scientific research through to the current state-of-the-art in automation and mass production are explored.

 The North American Rockwell organization, along with their subsidiary, the Rockwell Science Center, performed pioneering work in the development of SPF of titanium and later made historical innovations in Diffusion Bonding (DB), which they combined together to create the Superplastic Forming and Diffusion Bonding process (SPF/DB).  This organization was granted close to 100 U.S. patents during the 1970’s through the end of the 1980’s.  The application of these methods was targeted primarily on the B1B airplane.   

 The McDonnell Douglas organization found alternative ways to combine welding technologies with SPF and DB in order to fabricate complex sandwich structure using less press time than was required for the Rockwell methods.  The 2-sheet SPF/DB and 4-sheet SPF/DB integrally stiffened panels were used extensively on the F-15E aircraft and several other aero-structures.  The major developments for these manufacturing processes occurred during the 1970’s through 1990’s. 

 The Boeing Puget Sound organization developed a primitive SPF process during the late 1960’s and early 1970’s, but then abandoned the process for nearly 20 years.  In 1988, a new R&D initiative was undertaken geared towards mass production of both aluminum and titanium parts.  A manufacturing center for SPF and SPF/DB was subsequently setup for both military and commercial applications.  Many medium to large sized assemblies that had been previously been fabricated in multiple pieces were converted to monolithic structures for cost and weight savings. 

Superplastic Forming Special Topics

Indirect Verses Direct Heating of Sheet Materials: Superplastic Forming and Diffusion Bonding Using Lasers
A. F. Jocelyn, University of the West of England, Bristol, Bristol, United Kingdom

Abstract

Many from within manufacturing industry consider Superplastic Forming (SPF) to be ‘high tech’ but it is often criticised as too complicated, expensive, slow and, in general, an unstable process. Perhaps, the fundamental cause of this negative perception of SPF, and also of diffusion bonding (DB), is the fact that the current process of SPF/DB relies on indirect sources of heating to produce the conditions necessary for the material to be formed. In the main, heat is usually derived from the electrically heated platens of hydraulic presses, to a lesser extent from within furnaces, and sometimes from heaters imbedded in ceramic moulds. Recent evaluations of these isothermal methods suggest they are slow, thermally inefficient and even inappropriate for the process.

In contrast, direct heating of only the material to be formed by modern, electrically efficient, lasers could transform SPF/DB into the first choice of designers in aerospace, automotive, marine, medical, architecture and leisure industries. Furthermore, ‘variable temperature’ direct heating which, in theory, is possible with a laser beam(s) may provide a means to control material thickness distribution, a goal of enormous importance as fuel efficient, lightweight structures for transportation systems are universally sought. This paper compares, and contrasts, the two systems and suggests how a change to laser heating might be achieved.

Combined Mechanical Deep Drawing and Pneumatic Bulge Forming of Superplastic Materials
F. K. Abu-Farha1, M. A. Nazzal2, M. K. Khraisheh3, (1)University of Kentucky, Lexington, KY, (2)German Jordanian University, Amman, Jordan, (3)Masdar Institute of Science and Technology, Abu Dhabi, United Arab Emirates

The superplastic forming technique (SPF) is a unique sheet metal forming process that stretches the limits of formability in lightweight alloys beyond conventional, promising greater potentials for applications in the transportation industry.  The technique, primarily practiced by pneumatic bulge forming, offers great advantages over conventional forming operations.  The ability to shape hard-to-form alloys into highly intricate shapes remains one of the most attractive.  Yet, this is generally achieved at low forming rates, causing a major limitation in SPF’s industrial use on a larger scale.  In order to overcome this drawback, superplastic forming can be merged or hybridized with several other manufacturing processes, for enhanced forming efficiency and improved productivity merits.
This work presents one of such hybrid concepts, in which the pneumatic bulge forming practice of superplastic forming is combined with the conventional mechanical deep drawing operation.  Sheets are partially formed by a fast deep drawing step, followed by a finishing pneumatic bulge forming step that takes care of the intricate details of the shapes to be formed.  Forming according to this concept is first FE-simulated, before being carried out at elevated temperatures, using AZ31 magnesium alloy sheets.  Both the FE and experimental results demonstrate how forming time can be considerably reduced, while sustaining the formability merits associated with the superplastic forming process

Progressive Distortion Behaviour of Large SPF Tool Under Thermo-Mechanical Fatigue and Fatigue-Creep Interactions
A. A. Deshpande, S. B. Leen, T. H. Hyde, University of Nottingham, Nottingham, United Kingdom

SPF tool distortion due to the thermal cycling and cyclic creep can lead to the forming of faulty SPF parts. In addition, thermo-mechanical fatigue and creep can cause cracking, which eventually lead to un-repairable damage to the tool. The aim of the present research work is to develop a generic methodology for predicting the distortion behaviour of large aerospace SPF tools, made from 40% nickel, 20% chromium alloys. Initially FE modelling of the SPF process is performed under realistic forming conditions to understand distortion behaviour of a large representative SPF tool. Progressive distortion of the tool due to creep relaxation during forming cycle (dwell period) is predicted. Thermo-mechanical fatigue-creep interaction tests and high temperature creep tests are designed and carried out based on FE predicted results. FE predictions and experimental results are compared and analysed. Factors affecting tool distortion such as heating and cooling cycles, heating and cooling rates and the batch size are studied to optimize the SPF process.

Necking Instabilities in the Superplastic Deformation of Coarse Grained AA5182 Aluminium Alloys
A. V. Kazantzis1, Z. Chen1, J. T. M. De Hosson2, (1)University of Groningen and the Netherlands Institute for Metals Reseach, Groningen, Netherlands, (2)The University of Groningen, Netherlands Institute for Metals Reseach, Groningen, Netherlands

Two coarse-grained Al alloys AA5182 with as-received grain sizes 19 and 34 μm have been evaluated with respect to their superplastic properties.  They exhibited moderate elongation to failure reaching maxima, in excess of 300%, at temperatures between 425 and 450oC and at strain rates 10-2 s-1.

Extreme grain refinement by recovery, reconstruction and recrystallization produced microstructures consisting of grains as small as 2 μm at the tip region, suggesting that the precipitates are quite effective in pinning the subgrain boundaries, which in turn are readily converted into low and high angle grain boundaries.

This grain refinement, however, occurred also randomly in other locations in the specimens, wherever large strain was localized, resulting in multiple necking in specimens exhibiting maximum elongations prior to failure.This behavior renders coarse grained AA5182 Al-alloys quite unstable, as superplastic materials and, despite their low fabrication cost, their precipitate size needs to be regulated further, so that their superplastic elongation to retain the uniformity that is required in practical applications in the automotive and aerospace industry.

On the Activation Energy for Super Plastic Flow
J. D. Muñoz-Andrade, UNIVERSIDAD AUTONOMA METROPOLITANA UNIDAD AZCAPOTZALCO, Mexico, Mexico

By applying the quantum mechanics and relativistic mathematical model of Muñoz-Andrade the activation energy for super plastic flow in spatially extended polycrystalline systems is obtained. Over this framework, in the present study the activation energy for super plastic flow in spatially extended polycrystalline systems dependence on strain rate and phase velocity de Broglie are obtained, in addition, the nature determination of the wavelength of the cellular dislocations l^ wave associated with super plastic flow. It is concluded that the super plastic flow associated with cooperative grain boundary sliding and self accommodation process is assisted in nature behavior by cellular dislocation dynamics. Furthermore, the most important results of this work are analyzed in the environment of the cosmic micromechanics connection during super plastic flow in spatially extended polycrystalline systems.

Material Models for Simulation of Superplastic Mg Alloy Sheet Forming
E. Taleff, University of Texas, Austin, TX

Magnesium (Mg) alloys are currently the focus of a worldwide effort aimed at increasing their use in automotive components because of their low densities and high strength-to-weight ratios.  Because forming at elevated temperatures, e.g. 400 to 500 °C, provides excellent ductility in several wrought Mg alloys, hot forming is of great interest for producing these components.  Unfortunately, the availability of accurate material models for plasticity in wrought Mg alloys at elevated temperatures is severely limited.  The present study investigates a material constitutive model for high-temperature plasticity in a fine-grained Mg AZ31 sheet material, developed using data from uniaxial tension, and evaluates the accuracy and applicability of this constitutive model to finite-element-method simulations of forming under biaxial tension conditions.  Bulge forming experiments, which produce a nearly balanced-biaxial stress state, were conducted at 450 °C using four constant gas pressures.  Simulation results are compared with experimental results.  It is discovered that wrought Mg AZ31 behaves differently than wrought Al alloys previously investigated, e.g. fine-grained AA5083 sheet.  Recommendations on the use of experimental data for constitutive model construction and on applying constitutive models to forming simulations are made.

Symposium on Materials / Structural State Awareness and Prognosis

Materials/Structural State Awareness I

Basic Studies for Materials State Awareness
E. A. Medina1, K. V. Jata2, S. A. Martin3, (1)Radiance Technologies, Inc., Dayton, OH, (2)Air Force Research Laboratory, Wright-Patterson AFB, OH, (3)NDE Computational Consultants, Dublin, OH

In integrated vehicle health monitoring and materials damage assessment it is not clearly known how sensitive the damage detection capability will be to changes in material characteristics which may be due, for example, to heat exposure. Additional effects on the damage detection capability can also arise due to other external factors; however, they will not be examined here. This study investigates the influence of heat treatment on damage detection capability through a comparison of wave propagation and vibration characteristics of thermally soaked specimens with those of baseline measurements. A set of Titanium and Aluminum specimens was utilized in these experiments. For each specimen, ultrasonic velocity, and dynamic vibration characteristics were measured before and after each thermal exposure.

Precious-Metal Sensors for HM in Harsh Environments
C. Gouldstone, J. Brogan, J. Gutleber, R. Gambino, R. Greenlaw, B. Keyes, MesoScribe Technologies, Inc., Stony Brook, NY

Nickel-based sensor utility is limited when exposed to high temperatures for long periods, due to oxidation effects which affect durability and repeatability.  This work addresses these shortcomings using precious metal-based devices, including thermocouples and strain gages, which potentially offer higher longevity and more consistent response over sensor lifetime.  Devices are deposited by Mesoplasma Direct Write, a high-precision derivative of thermal spray, capable of embedding multilayer thick-film devices onto surfaces and within coatings.  In-situ temperature and strain measurement capability in engines and other harsh environments supports HM by reducing uncertainty, and consequently extending service intervals and increasing asset availability.

Development of a Residual Stress Depth Profile Measurement Instrument
D. S. Erdahl1, D. A. Stubbs2, W. C. Hoppe2, J. R. Sebastian2, J. D. Hoeffel2, R. B. Olding2, (1)University of Dayton, Dayton, OH, (2)University of Dayton Research Institute, Dayton, OH

The U.S. Air Force has a strong strategic and economic interest in extending the safe life of the gas turbine engines in its inventory. Many research programs have investigated the relationship between near surface residual stresses, introduced during manufacturing by processes such as shot peening, and the fatigue life of engine component alloys. At the present, there is interest in extending engine life by taking credit for residual stresses that extend fatigue life; however, this requires accurate, nondestructive measurement of the residual stresses.

In recent years, research programs have established that residual stresses in some nickel-based engine alloys can be accurately and repeatably calculated from electrical conductivity measurements acquired using eddy current (EC) nondestructive testing (NDT) methods. This work has also shown that, under laboratory conditions, conductivity measurements as a function of eddy current frequency can be used to calculate residual stress as a function of depth in the material.

In November 2005 the U.S.A.F. awarded a competitively-bid contract to the University of Dayton to demonstrate the feasibility of incorporating the EC NDT residual stress measurement technique into an instrument designed for eventual depot deployment. The program goals focused on creating an EC instrument/system that can reliably and repeatably measure electrical conductivities which allow calculation of residual stress as a function of depth in nickel alloys. Key performance requirements include:

- electrical conductivity measurements accurate to within 0.1 percent relative to the nominal alloy conductivity

- measurement times of less than 5 minutes

- EC frequencies from 100 kHz to 50 MHz

- instrument design anticipates eventual usage in a depot environment as part of an automated inspection system

This presentation will describe the program goals, instrument design, and experimental results. The potential for moving the technology to the depot floor will also be discussed.

X-ray nanoCT: 3D Analysis of Aerospace Materials with Submicrometer Resolution
K. Brockdorf, phoenix|x-ray Systems + Services Inc., St. Petersburg, FL

During the last decade, Computed Tomography (CT) has progressed to higher resolution and faster reconstruction of the 3D-volume. Most recently it even allows a three-dimensional look into the inside of materials with submicron resolution. By means of nanofocus® tube technology, nanoCT®-systems are pushing forward into application fields that were exclusive to expensive synchrotron techniques. High-resolution X-ray CT allows the 3D visualization and failure analysis of the internal microstructure of aerospace materials like light metal alloys, CFKs and other composites – even where 2D X-ray microscopy would give only the integral information of the overlaying internal features.
The new nanotom is a compact laboratory system that allows the analysis of samples up to 120 mm in diameter and weighing up to 1 kg with exceptional voxel-resolution down to <500 nm (<0.5 microns). It is the first 180 kV nanofocus computed tomography system tailored specifically to the highest-resolution applications in fields like material science, micro electronics, geology and biology. Therefore it is particularly suitable for nanoCT®-examinations e.g. of synthetic and composite materials, metals and metal foams, ceramics etc.
The CT volume data set can be displayed in various ways; it can be sectioned and sliced in all directions, rotated and viewed from any desired angle. Highly applicable to a variety of fields, nanoCT can be a viable substitute for destructive mechanical slicing and cutting. Any internal difference in material, density or porosity within a sample can be visualized and data such as distances can be measured. Some of the many applications of nanoCT® include the analysis of fiber textures, air inclusions or cracks in composite materials with voxel resolutions of less than one micrometer.
The presentation will outline the hard- and software requirements for high resolution CT. It will showcase several quality control applications involving different aerospace materials that were inspected with nanoCT®.

Laser-Ultrasonic and Laser-Tapping Techniques for Probing Aerospace Composite Structures
A. Blouin, C. Néron, D. Levesque, B. Campagne, J. P. Monchalin, National Research Council Canada, Boucherville, QC, Canada

Laser-ultrasonics is by now a well known and mature nondestructive technique for inspecting polymer matrix composites used in aerospace. This technique uses a pulse echo interrogation mode, in which ultrasound is first generated by a pulsed laser and then detected by a second laser coupled to an optical interferometer. The technique is particularly powerful for inspecting parts of complex shape. While very successful to find delaminations in laminates, difficulties are found for reliably detecting disbonds in honeycomb and foam core structures, particularly when the detachment occurs at the back skin. For this purpose, and other inspection tasks for which laser-ultrasonics usually fails (such as probing highly porous and attenuating materials like metallic foams), a novel technique called Laser-tapping or Laser-acoustics is proposed. Laser-tapping is based on the thermoelastic excitation by a pulsed laser of the top layer which bulges and is driven into vibration if it is detached from the material underneath. This bulging and vibration is then detected by a second laser coupled to a photorefractive interferometer. Laser-tapping uses essentially the same hardware as laser-ultrasonics but probes in a lower ultrasonic frequency range. Laser-ultrasonics and laser-tapping can then be advantageously used concurrently. In particular, since laser-tapping detects both skin delaminations and skin disbonds and cannot distinguish between them, the distinction can be provided by the time-of-flight between the laser ultrasonic echoes. The combined inspection system provides all the features of laser-ultrasonics, i.e. non contact, no surface preparation and ease of probing complex parts. The inspection system can also be made very flexible by using optical fiber coupling. Examples of applications of the combined system will be presented for a variety of honeycombs structures with defects, including delaminations in the skin and skin disbonds, at the front side and back side.

Detection of Defects in Aerospace Low Pressure Compressor Blades Using Ultrasonic Techniques
E. M. Rasselkorde1, P. Wallace2, (1)TWI Validation Centre (Wales), Port Talbot, United Kingdom, (2)TWI Ltd, Margam, Port Talbot, United Kingdom

       Complex geometry components made from titanium material such as aerospace gas turbine Fan engines is often classified as “safety critical” component, and subject to very high stresses and vibration. It required the highest structural integrity. NDT techniques such as Ultrasonic and eddy current have been developed to inspect these components. This paper presents an ultrasonic testing inspection for the fan blades components, modeling using CIVA and Continuum Ultrasonic Modeler has been performed in order to predict the ultrasound propagation and defects responses for different type of scans. A comparison between the experimental and modelling results was shown good accuracy of the modeling in predicting the ultrasonic inspection performance. 

Detection of Defects in Aerospace Low Pressure Compressor Blades using Eddy Current Arrays
E. M. Rasselkorde1, M. Papaelias2, (1)TWI Validation Centre (Wales), Port Talbot, United Kingdom, (2)The University of Birmingham, Birmingham, United Kingdom

Aerospace gas turbine Turbo Fan engines operate under harsh environmental conditions involving high temperatures, friction, eroding and corroding elements. Low Pressure Compressor blades (Fan Blades) are also subject to very high stresses and vibration, especially during aircraft take-off and landing, which can lead to crack initiation and subsequent propagation. Unless existing cracks are identified before reaching critical dimensions, turbine blades will fail causing a chain of events that could eventually render the host turbine engine inoperable. This paper discusses the development of novel eddy current arrays customised for the inspection of turbine blades using a commercially available eddy current acquisition unit.

Materials/Structural State Awareness II

Early Fatigue Detection in Aerospace Alloys with MWM-Array Eddy Current Sensors
N. J. Goldfine1, V. Zilberstein2, D. Grundy1, J. Cammett1, (1)Jentek Sensors, Inc., Waltham, MA, (2)JENTEK Sensors, Inc., Waltham, MA

This presentation discusses the results of MWM-Array monitoring during fatigue tests of aluminum 7075-T651 and Ti-6Al-4V coupons.  The goal is detection of early-stage cracks in aluminum and titanium alloys.  Results are presented for two different coupon geometries.  The aluminum coupons are flat plates with electro-polished and as-machined holes.  The titanium coupons have exposed, curved surfaces that are shot peened.  MWM‑Arrays are used in both scanning and surface-mounted configurations.  Acetate replicas provide the actual crack lengths at multiple intervals throughout the fatigue tests of the titanium coupons.
The MWM-Array, in both scanning and surface-mounted modes, offers a convenient and effective way to monitor such coupon tests to study early-stage fatigue behavior.  One observation from these tests, that is generally well known, was that at early stages, multiple small cracks (<0.005 in. long at the surface) formed and then coalesced into larger cracks.  This is true for both shot-peened Ti-6Al-4V and polished or as-machined aluminum 7075.  This behavior is observed, for example, in actual engine components, where multiple shallow cracks initiate and grow in regions with fretting damage.  For aluminum 7075, multiple small cracks generally initiate at inclusions before coalescing into longer cracks.  Although, a single large crack eventually dominates the NDT signature, this appears to occur when the crack is relatively long; for example, when a dominant crack in titanium alloy components is greater than 0.015 in. (length at the surface).  This is a concern for both prognostics (life prediction) and for qualification of Nondestructive Testing (NDT) methods. 

In-Process Quality Assurance for Welding: Applications to Aerospace Manufacturing
V. R. Dave, D. A. Hartman, M. J. Cola, Beyond6 Sigma, Santa Fe, NM

In-Process Quality Assurance is an emerging field of enquiry in manufacturing technology that started in the 1980s and has seen recent growth in several areas of welding for aerospace applications.   This talk reviews the underlying technology for In-Process Quality Assurance as well as recent applications to aerospace and other critical parts manufacture.  The historical evolution of the concept will also be traced as it has been applied to the aerospace industry in particular.

 

The basis for In-Process Quality Assurance is the direct interrogation of process physics and dynamics as opposed to exclusive reliance on machine tool monitoring or post-process inspection.   In-Process Quality Assurance is complimentary to these other technologies and provides valuable process information not available through other means.   Applications to real-time closed loop control will also be discussed.   In this modality of operation, In-Process Quality Assurance is used to largely preclude the occurrence of defects altogether.

 

Specific application areas to be discussed include: gas metal arc weld (GMAW) repair of titanium IBRs, rotary friction welding, linear friction welding of titanium, and other welding applications to non-aerospace industries.  Case studies will be shown that specifically address how the technology is applied, how it may be integrated into an overall quality system, and what quality questions it can address as well as limitations to applicability.

Analytical model of the interaction of Lamb waves with fastener sites
K. V. Jata1, S. S. Chellapilla2, J. C. Aldrin3, (1)Air Force Research Laboratory, Wright-Patterson AFB, OH, (2)Radiance Technologies, Inc., Huntsville, AL, (3)Computational Tools, Gurnee, IL

Critical issues remain to be addressed concerning the reliability of in-situ ultrasonic sensors in the structural health monitoring (SHM) domain, where ultrasonic guided waves have been proposed for the frequent monitoring of aircraft joints for fatigue cracks around fastener sites.  In particular, the interface conditions between the fastener shaft and hole are found to vary with time, and often independently of the damage state of the joint.  Changes in the magnitude of scattered ultrasonic signals from fastener sites can result from dynamic structural loading, thermal cycling, aging of sealant present in some structures, and scheduled maintenance actions.  Under certain conditions, the scattered signals from a fastener location can be difficult to distinguish from fatigue crack signals.  Prior work from ultrasonic measurements of fastener sites in aging aircraft has highlighted the variation in fastener-hole fit conditions and the challenge of separating crack signals around the fastener site from re-radiated signals from the fastener hole. To better understand the scattering of ultrasonic guided waves from fastener sites in aircraft structures, analytical models are presented and used for studying the interaction of ultrasonic waves with a cylindrical hole and an elastic insert which are coupled by a stiffness interface.  Parametric studies are presented which investigate the effect of variations in the fastener contact conditions on the reflection of incident Lamb waves and the generation of secondary waves around the fastener hole.

Magnetostrictive Sensor for Health Monitoring in Aircraft Structures
G. M. Light, C. Thwing, A. R. Puchot, Southwest Research Institute, San Antonio, TX

 The DoD aircraft fleets consisting of the C-5, C-17, B-52, A-10, F-16, F-15, and others are aging and in many cases either exceeding their intended life or rapidly approaching  their intended life with no new aircraft purchases on the horizon.  One way to keep the aircraft flying is to use structural health monitoring (SHM) technologies.  SwRI has developed the magnetostrictive sensor (MsS) technology that has been successfully used to monitor piping, but has applications to plate geometries such as aircraft structure.  The MsS probe has a low profile (approximately 0.005 inch thick) and is bonded to the surface of the structure.  The MsS probe generates a guided wave that travels long distances from the probe into the plate or aircraft structure to provide a means of long range inspection and condition monitoring.  SwRI has conducted a wide range of laboratory tests to demonstrate the feasibility of MsS to detect defects under fasteners, quality of bond of patches, and defect growth under patches.  Recently, SwRI utilized the MsS technology on a C-141 test panel.  The MsS was bonded to various surfaces and then the surfaces were subjected to 20,000 ksi loads to study potential issues associated with sensor debonding and slight changes that might occur in the fastener holes.  Notches were introduced into several fastener holes and used the MsS to monitor changes in the defects.   The purpose of this paper is to describe the MsS technology and the results of the various laboratory experiments showing the potential for MsS aircraft structural health monitoring.  The DoD aircraft fleets consisting of the C-5, C-17, B-52, A-10, F-16, F-15, and others are aging and in many cases either exceeding their intended life or rapidly approaching  their intended life with no new aircraft purchases on the horizon.  One way to keep the aircraft flying is to use structural health monitoring (SHM) technologies.  SwRI has developed the magnetostrictive sensor (MsS) technology that has been successfully used to monitor piping, but has applications to plate geometries such as aircraft structure.  The MsS probe has a low profile (approximately 0.005 inch thick) and is bonded to the surface of the structure.  The MsS probe generates a guided wave that travels long distances from the probe into the plate or aircraft structure to provide a means of long range inspection and condition monitoring.  SwRI has conducted a wide range of laboratory tests to demonstrate the feasibility of MsS to detect defects under fasteners, quality of bond of patches, and defect growth under patches.  Recently, SwRI utilized the MsS technology on a C-141 test panel.  The MsS was bonded to various surfaces and then the surfaces were subjected to 20,000 ksi loads to study potential issues associated with sensor debonding and slight changes that might occur in the fastener holes.  Notches were introduced into several fastener holes and used the MsS to monitor changes in the defects.  

            The purpose of this paper is to describe the MsS technology and the results of the various laboratory experiments showing the potential for MsS aircraft structural health monitoring.

Validation of Nondestructive Testing Sensors Used in Structural Health Monitoring
D. S. Forsyth1, T. B. Mills2, J. I. Gonzalez1, C. L. Brooks2, (1)TRI/Austin, Austin, TX, (2)AP/ES Inc., Saint Louis, MO

There is considerable interest in aerospace and other industries in the use of sensors for structural health monitoring (SHM) that are derived from or are the same as sensors used for conventional nondestructive testing (NDT) applications. Texas Research Institute Austin (TRI/Austin) Inc. and Analytical Processes/Engineered Solutions (AP/ES) Inc. have collaborated to develop a process for the selection and validation of NDT and other sensors applied to SHM in aerospace structures.

AP/ES has developed and demonstrated a quantitative process for determining optimum sensor selection and application. This process carefully considers costs of implementation and support in operation of SHM, in comparison to existing procedures. Once a cost-effective SHM system has been designed for an application, validation of the SHM system is required just as validation of new NDT procedures is required.

In this work, we discuss the SHM design process, and describe in detail the validation studies being performed by TRI/Austin and AP/ES on sensors for corrosion damage and fatigue damage in aerospace structures. These studies are being performed to demonstrate both the SHM system reliability, as well as the damage detection reliability. Coupon tests using materials, loads, and environments typical of the target application are the key elements of the validation. Results will be presented from these coupon tests.

These efforts are supported by SBIR funding from the Air Force Research Laboratories Materials and Manufacturing Directorate.

Prognosis

Sensing, Life Prediction and Probabilistic Analysis Technologies for Turbine Engine Prognosis
S. J. Hudak Jr.1, R. C. McClung1, M. P. Enright1, H. Millwater2, (1)Southwest Research Institute, San Antonio, TX, (2)University of Texas at San Antonio, San Antonio, TX

The development and implementation of prognosis technology for integrated system health management (ISHM) has the potential to significantly enhance the reliability and readiness of high-value assets, while concurrently decreasing sustainment costs.  The systems approach includes the acquisition and fusion of on-line sensor information, combined with physics-based models for damage accumulation, and higher order reasoning for decision making. This presentation will summarize and demonstrate the benefits of several recently developed ISHM-enabling technologies. First, enhancements to the DARWIN® probabilistic fracture mechanics code that are relevant to military engine application will be summarized, and example applications will be given. These enhancements will be employed to assess the benefits of tracking actual engine usage and monitoring material damage (i.e. fatigue cracking) in assessing remaining fatigue life and forecasting probability of component failure. Specifically, an advanced fracture mechanics model, which explicitly treats crack nucleation, small crack propagation, and large crack propagation, will be described. This model will be used to demonstrate the benefits of usage tracking to the component level by assess the conservatism in employing Total Accumulated Cycles (TACs) versus actual usage data to predict fatigue life. A probabilistic method for mission identification will also be described and assessed using actual usage data from flight data recorders at USAF bases. The utility of this method for forecasting the impact of projected changes in mission mixing on future fatigue damage accumulation and probability of failure will also be discussed.   The development of a statistical model for sensor uncertainty, based on laboratory data on a thin film magnetostrictive sensor for crack detection, will also be described. This sensor model will then be combined with probabilistic simulation to assess the potential benefits of embedded sensors for on-line detection and monitoring of defects, as compared to the more traditional mid-life depot inspection.

Structural Prognosis During an EA-6B Outer Wing Panel Fatigue Test*
J. M. Papazian1, E. L. Anagnostou1, S. Engel1, D. Fridline1, J. Madsen1, J. Payne1, J. Nardiello1, R. Silberstein1, P. C. Hoffman2, A. Roerden3, G. Werczynski3, (1)Northrop Grumman, Bethpage, NY, (2)NAVAIR, Patuxent River, MD, (3)Navair, Patuxent River, MD

The Northrop Grumman/DARPA Structural Integrity Prognsosis System (SIPS) was applied to a full-scale fatigue test of a retired EA-6B outer wing panel.  The test was conducted by NAVAIR at Patuxent River, MD.  The panel had been retired from active service with a Fatigue Life Expended index of 185.  Laboratory fatigue testing of the entire panel was performed to evaluate several sensor systems, SIPS fatigue models, and the SIPS reasoning and prediction system.  Phased array ultrasonics was used as a non-destructive inspection system to evaluate the starting state, and pitch-catch ultrasonics, eddy current (MWM®-Array) and the electrochemical fatigue sensors were used to monitor fasteners on rib 1 during the test.  A FASTRAN-based modeling system was used to predict the evolution of cracking.  The SIPS reasoning system combined the model and sensor outputs to provide a probabilistic crack size prediction that was updated daily.  After the test, the panel was disassembled and actual crack sizes in the bores of the fastener holes were measured using scanning electron microscopy and compared to the sensor readings.  The entire system performed admirably, and much useful data was obtained.

 

 

*This work is partially sponsored by the Defense Advanced Research Projects Agency under contract HR0011-04-C-0003.  Dr. Leo Christodoulou is the DARPA Program Manger

Non-Destructive Evaluations and the Advance Life Prediction System
E. L. Suarez, Pratt & Whitney, East Hartford, CT

The Advanced Life Prediction System (ALPS) is a formidable new tool to incorporate into the Non-Destructive Evaluations (NDE) methodology. Testing in the aerospace industry is expensive and time consuming. The ALPS methodology has been develop as a maintenance tool for new engine programs. Using ALPS as part of the investigation would save testing funding and time to completion. Mission profiles exercised through production ready components and life-limited components demonstrated new applicability for this technology.

Scaled Turbine Engine Testing for Cost-effective Health Prognosis
R. Holmes1, E. Pope2, J. Hamler2, T. Brooks2, R. Tryon2, (1)VEXTEC, Brentwood, TN, (2)VEXTEC Corporation, Brentwood, TN

Full scale gas turbine engine testing is expensive and time consuming. An efficient alternative is the use of low cost subscale engine testing that can simulate the conditions of a full-scale engine and its failure mechanisms. VEXTEC has developed scaled turbine engine tests as a platform to gather probabilistic data on multiple material failure mechanisms such as thermal mechanical fatigue, biaxial crack growth, creep and foreign object damage. These tests are efficient in terms of cost and schedule and provide insight into full scale engine behavior. Complex multi-axial stress fields and thermal environment typically observed in gas turbine engines are naturally reproduced in the scaled engine testing. Subscale engine testing is validated by comparing the test data with full scale engine testing results. This paper discusses the capabilities of the scaled engine and its benefits compared to full scale engine testing.

Predicting Fatigue Crack Progression in Ti-6Al-4V Under Mini-Sweep Loading
M. J. Caton1, R. John2, (1)Air Force Research Laboratory, Wright-Patterson AFB, OH, (2)US Air Force Research Laboratory, Wright-Patterson AFB, OH

In the aerospace industry, rotating engine components are subject to resonant vibratory loads under various operating conditions.  These vibratory loads are typically experienced for only brief periods as the rotational speed of the engine traverses critical modes.  These relatively brief bursts of resonant vibration, referred to as “mini-sweeps,” can contribute to the initiation of fatigue cracks, or the propagation of existing fatigue damage.  This study investigates the propagation of long and small fatigue cracks in Ti-6Al-4V under mini-sweep loading conditions.  Bursts of variable amplitude loading were applied to cylindrical, dog-bone specimens and a compact-tension (C(T)) specimen under a frequency of 20 Hz at room temperature.  The loading profile is consistent with a typical mini-sweep experienced in rotating hardware during service.  Long crack growth rates under the mini-sweep loading profile were monitored in the C(T) specimen using direct current potential drop (DCPD) and optical observation.  The growth of small fatigue cracks, initiated from artificial notches, was monitored using a standard replication technique.  The fatigue crack growth behavior under these loading conditions will be presented and the implications for improved lifing methods of critical rotating components will be discussed.

Sustainment of Compressor Components Through Low Plasticity Burnishing (LPB)
N. Jayaraman1, D. J. Hornbach1, P. S. Prevey1, J. Sides2, R. Ravindranath2, R. Chan2, (1)Lambda Technologies, Cincinnati, OH, (2)NAVAIR, Patuxent River, MD

Use of compressive residual stresses in turbine engine compressor parts is proving to be very useful for sustainment of parts prone to different damage conditions. The leading and trailing edge of blades and vanes are subject to fatigue cracking and foreign object damage (FOD). Both the blade dovetail and the rotor disk post contact surfaces are vulnerable to fretting damage, which leads to microcracking and mode I fatigue cracks. Low plasticity burnishing (LPB) has been shown to introduce controlled magnitude and distribution of compressive residual stresses to completely mitigate either FOD on the edges of vanes and blades or fretting-induced microcracks at the edge of bedding on the contact faces of the dovetails and rotor disk posts. Residual stress field design, specialized LPB tooling, quality assurance (QA) of the process exceeding six-sigma, and the ease of application of LPB as a simple machining process on the shop floor will be described. Benefits due to current applications of LPB to the US Navy and other naval groups internationally in improved damage tolerance and reduced total ownership costs of turbine engines will be highlighted.

Probabilistic 3-D Crack Growth Analysis for Gas Turbine Engine Components
R. Holmes1, R. V. Pulikollu1, V. Ogarevic2, R. Tryon2, (1)VEXTEC, Brentwood, TN, (2)VEXTEC Corporation, Brentwood, TN

Traditional full scale engine tests are prohibitively expensive in terms of time and cost. In addition they provide limited insight into the probabilistic nature of fatigue crack growth in the components. VEXTEC Corporation has developed innovative 3-D probabilistic crack growth models in conjunction with scaled turbine testing to accurately capture crack growth behavior in turbine engine rotors. The models combine the automatic re-meshing in commercial available finite element tools with probabilistic crack growth techniques. The stochastic model has the capability to assess crack growth in multi-axial stress fields with random material properties along the crack front and accounts for crack kinking and branching. These models are evaluated based on test data gathered from scaled engine testing with the ultimate goal of predicting fatigue crack growth behavior in a full scale engine.

Titanium Alloy Technology

Titanum Processing/Metallurgical Characterization I

The Effect of Hydrogen on the Fracture Toughness of Ti-5Mo-5V-5Al-3Cr
J. D. Cotton1, D. J. Bryan2, T. Bayha2, M. Leder3, I. Levin3, (1)The Boeing Company, Seattle, WA, (2)ATI Allvac, Monroe, NC, (3)VSMPO-AVISMA, Verkhnaya Salda, Russia

Ti-5Mo-5V-5Al-3Cr (Ti-5-5-5-3) is an emerging near-β Ti alloy of significant commercial interest as a viable replacement for Ti-6Al-4V, Ti-10Al-2V-3Fe and some high strength steels in a variety of aerospace applications.  Ti-5-5-5-3 offers significantly improved thick section hardenability in a product capable of being extruded, rolled, forged, and/or cast.  In addition, Ti-5-5-5-3 can be heat treated in several ways to achieve high strength, high fracture toughness, high fatigue resistance, or a good combination of all of those properties.  Recently, evidence has emerged that hydrogen content strongly influences the fracture toughness, a critical aerospace design parameter, at all levels below typical specification limits for titanium alloys.  Positive identification of hydrogen as a prominent factor in fracture toughness control could have an impact in alloy specification limits, heat-treatment requirements, additional processing, and new alloy grades, all of which could lead to significant cost and/or value added for low hydrogen content material.  A wide variety of characterization tools, including light microscopy, SEM fractography, and TEM, were employed to explore the effects of hydrogen on the microstructure of Ti-5-5-5-3 and the resulting fracture toughness.  Hydrogen has been verified to have a strong effect, especially at low levels, on the fracture toughness of Ti-5-5-5-3.  The reduced fracture toughness appears to be largely associated with an increase in the amount and nature of boundary type fracture modes.  The exact mechanism for how hydrogen modifies boundary fracture behavior is still under investigation; however changes in α phase morphology have been observed as well, and may provide a key to further understanding.

Mechanical Properties of Heat Treated Ti-5Al-5V-5Mo-3Cr: an Attempt to Define Critical Properties of Various Microstructural Features
R. Panza-Giosa1, D. Embury2, Z. Wang3, X. Wang2, (1)Goodrich Landing Gear, Oakville, ON, Canada, (2)McMaster University, Hamilton, ON, Canada, (3)University of Toronto, Toronto, ON, Canada

The properties and microstructure of Ti-5Al-5V-5Mo-3Cr were characterized under various stress states after the following heat treatments: 1) beta anneal and air cool; 2) solution heat treatment in the alpha-beta range; 3) solution heat treatment and ageing in the alpha-beta range.   For each condition, the damage mechanisms and final fracture modes were evaluated and rationalized on the basis of microstructural features. The true fracture stresses for the various conditions are compared.   Beta annealed material exhibits intense localized slip deformation leading to early crack formation and fracture. This mechanism is explained in relation to the presence of fine metastable phase precipitates resulting from the air cool step. Grain size dependence of the yield stress is described in terms of the Hall-Petch relationship.

Heat treatment, microstructure, and properties of TIMETAL 555
J. Fanning, TIMET-R&D, Henderson, NV

TIMETAL 555 (Ti-5Al-5Mo-5V-3Cr-0.6Fe) is a titanium alloy that can achieve property combinations potentially useful for structural applications. The alloy is currently under evaluation for several major airframe programs. A wide variety of strength, ductility and fracture toughness values can be achieved depending on thermomechanical processing and heat treatment. This presentation provides recent results regarding the interactions between heat treatment, microstructures and properties. 

Evolution of Nanoscale Microstructures in Complex Beta Titanium Alloys
S. Nag1, A. Genc2, S. Rajagopalan2, R. Banerjee1, P. C. Collins3, H. L. Fraser4, (1)University of North Texas, Denton, TX, (2)The Ohio State University, Columbus, OH, (3)Quad City Manufacturing Lab, Rock Island, IL, (4)Center for Accelerated Maturation of Materials, Columbus, OH

The solid-state decomposition of the beta phase of titanium alloys is a rather complex phenomenon involving multiple competing instabilities which includes phase separation in the beta phase and precipitation of the omega and alpha phases. Interestingly, despite their widespread application, the microstructural evolution and resultant mechanical properties of these alloys are rather poorly understood. Furthermore, recent developments in advanced characterization techniques such as high-resolution scanning transmission electron microscopy and 3D atom probe tomography allow for unprecedented insights into the true atomic scale structure and chemistry changes associated with the instabilities in the beta phase of these complex alloys. Such detailed studies are being carried out on different beta titanium alloys including the Ti-5Al-5Mo-5V-3Cr-0.5Fe (TIMETAL-5553 or Ti-5553) alloy, used in aerospace applications, and the Ti-35Nb-7Zr-5Ta alloy, used in orthopedic implant applications. The results of these studies will form the basis of this presentation.

Preliminary Characterization of Processing-Microstructure-Property Relationships for Blended-Elemental, Powder-based, Canless Extrusions
S. M. El-Soudani1, O. Yu2, F. Sun3, A. Keskar4, V. S. Moxson5, V. Duz5, (1)The Boeing Company, Huntington Beach, CA, (2)RMI Titanium Company, Niles, OH, (3)RTI International Metals Inc., Niles, OH, (4)RTI International Metals, Inc.,, Houston, TX, (5)ADMA Products, Twinsburg, OH

Using the results of a workability study program in combination with prior extrusion experience at RTI, the feasibility of canless extrusion in ambient environment of hydride/dehydride blended elemental, Ti-6AL-4V ADMA-Processed powder, previously direct-consolidated by cold isostatic pressing (CIP), followed by vacuum sintering has been successfully demonstrated.  The workability tests of powder-based elevated temperature compression specimens showed that powder-based consolidated billets of similar baseline composition as for wrought ingot-based Ti-6AL-4V billets will require lower extrusion pressures at same extrusion temperatures and strain rates.  Laboratory analysis showed that the canless powder-based billet extrusion processing step conducted in air added no more than 200 ppm oxygen to the as-vacuum-sintered billet oxygen content.  Preliminary tensile properties of the blended-elemental ADMA powder-based extrusions of a Ti-6AL-4V composition processed both in the beta or alpha-beta ranges of extrusion temperatures showed at least equivalent tensile properties as compared to identically processed wrought, ingot-based and extruded Ti-6AL-4V billet materials.  In the blended elemental powder-based extrusions both nitrogen and carbon contents were within specification limits for Ti-6AL-4V alloy, while any excessive residual hydrogen was successfully vacuum degassed after extrusion to within specification limits. Further optimization for fracture toughness, stress-corrosion resistance and fatigue properties will build on these encouraging results, while monitoring and controlling powder-based product interstitial content, namely oxygen uptake during pre-extrusion powder-consolidation processing steps.

Titanium Processing/Metallurgical Characterization II

Processing and properties of TIMETAL 54M, a new alpha-beta alloy with improved machinability
S. Nyakana1, M. Harper2, J. Fanning2, (1)TIMET, Henderson, NV, (2)TIMET-R&D, Henderson, NV

TIMETAL 54M (Ti-5Al-4V-0.6Mo-0.4Fe) is an alpha-beta titanium alloy that was developed to improve upon the overall production costs of Ti-6Al-4V while providing similar properties.  TIMET has produced significant quantities of 54M via Electron-Beam Single-Melting (EBSM).  The alloy is being evaluated for both aerospace and non-aerospace applications. Prior studies have shown that 54M provides improved drill machinability using conventional carbide tools, indicating that 54M may enable improved cutting tool life and/or accommodate increased cutting speeds.  In a recent trial, a beta-extruded 54M shape was machined alongside a production Ti-6Al-4V airframe component; this experience reinforced the machinability benefit of 54M.  Mechanical properties of the machined component are comparable to typical properties for similarly processed Ti-6Al-4V.

Fatigue Performance of 0.030" thick Machined Ti-6Al-4V
K. Doering1, D. C. Van Aken1, R. L. Hanks2, K. A. Young2, R. J. Lederich2, (1)Missouri University of Science and Technology, Rolla, MO, (2)Advanced Manufacturing R&D, Boeing – Phantom Works, St. Louis, MO

Machining of titanium to less than 0.080” thickness is required to take full advantage of titanium's specific properties and make it competitive with other materials. These pocketed machined parts are often composed of thin rib-stiffeners coupled to a thin floor or web. As the machined thickness is decreased, machining has the potential to alter both static and fatigue properties as a result of surface deformation and residual stress. In this paper, Ti-6Al-4V plate was machined to various thicknesses (0.020” to 0.120”) to determine the change in static and dynamic properties. The most notable change in static properties with thickness is a loss of tensile ductility (~25% decrease) at gages thinner than 0.080”. A loss in ultimate tensile strength was observed at a gage thickness less than 0.040”. Fatigue performance was investigated using three different testing configurations on materials that had a nominal thickness of either 0.030” or 0.080”. A rib-stiffener machining practice was used to produce the axial fatigue specimens. The fatigue strength at 10^6 cycles of the 0.030” thick gage was approximately 7% lower than the 0.080” thick gage specimens and the thinner gage specimens had lower cyclic life at the higher stress ranges, which corroborates the lower ductility observed in static tests. Bending fatigue studies using Krouse-type specimens are being conducted to better assess the effects of machining on the surface. These tests are being conducted using a servohydraulic test frame in load control. Sub-component testing on a 0.030” nominal thickness pocketed web and rib specimen with 0.120” fillet radius was also conducted to quantify the performance improvement resulting from hand blending the machined surface. Finite element analysis was used to determine the surface stress as a function of applied load; and, modeling and test results will be presented at the conference.

Canless extrusion process development for blended-elemental powder-based titanium 6Al-4V alloy
S. M. El-Soudani1, M. Campbell2, J. Phillips2, V. S. Moxson3, V. Duz3, (1)The Boeing Company, Huntington Beach, CA, (2)Plymouth Engineered Shapes, Hopkinsville, KY, (3)ADMA Products, Twinsburg, OH

The feasibility of canless extrusion in ambient environment of hydride/dehydride blended elemental Ti-6AL-4V ADMA-processed powder previously direct-consolidated by cold isostatic pressing (CIP), followed by vacuum sintering has been successfully demonstrated.  In these extrusion process trials at Plymouth Engineered Shapes the extrusion processing sequence and parameters used were essentially similar to those used for billets prepared from wrought ingot-based Ti-6AL-4V material. Boeing Laboratory analysis showed that the canless powder-based billet extrusion processing step conducted in air added no more than 200 ppm oxygen to the as-vacuum-sintered billet oxygen content.  Preliminary tensile properties of the blended-elemental ADMA powder-based extrusions of a Ti-6AL-4V composition processed both in the beta or alpha-beta ranges of extrusion temperatures showed equivalent or superior tensile properties as compared to identically processed wrought, ingot-based and extruded Ti-6AL-4V billet materials.  In the blended elemental powder-based extrusions both nitrogen and carbon contents were within specification limits for Ti-6AL-4V alloy, while any excessive residual hydrogen was successfully vacuum degassed after extrusion to within specification limits.  Further optimization for fracture toughness, stress-corrosion resistance and fatigue properties will build on these encouraging results, while monitoring and controlling the only remaining powder-based interstitial element, namely oxygen uptake during pre-extrusion powder-consolidation processing steps.

Effect of Water-jet Cutting on Fatigue Performance of Ti-6Al-4V Sheet
D. C. Van Aken, K. Doering, B. Kudlacek, G. Galecki, Missouri University of Science and Technology, Rolla, MO

Water-jet cutting is an attractive process for the machining of titanium components, but little is known regarding how this cutting operation affects performance. In this paper, Ti-6Al-4V sheet was water-jet cut and the cyclic life determined by load control fatigue testing. Titanium sheet with nominal thickness 0.0415 inches was obtained in the annealed condition as MIL-T-9046J (AB-1). Fatigue specimens were water-jet cut from the Ti-6Al-4V sheet at a pressure of 40,000 psi, using a 80 mesh garnet abrasive of less than 180 ?m diameter, fed at a rate of 0.62 pounds per minute with linear cutting speeds of 5 and15 inches per minute. Specimens cut at the faster speed were randomly selected and the edges were polished using 600 and 800 grit metallographic papers. Fatigue tests were performed in load control with R(Smin/Smax) = 0.1 and using a sinusoidal waveform. All fatigue cracks initiated at the specimen edge and propagated across the gage section. Polishing the water jet surface improved the overall fatigue life and increased the fatigue strength at 10^6 by up to 40%. A modest 8% increase in the fatigue strength at 10^6 cycles was observed for the lower cutting speed. Post mortem analysis revealed that fatigue crack nucleation occurred at surface scars produced during water jet cutting.

Titanium Alloy Development Needs for Commercial Airframes
R. R. Boyer, J. D. Cotton, K. T. Slattery, G. R. Weber, The Boeing Company, Seattle, WA

There is continual pressure on the aircraft industry to reduce both manufacturing and operating costs. The former occurs in the form of pressure to reduce component and material costs; the latter in the form of reduced maintenance costs and aircraft weight. Weight and cost are thus interrelated, and sometimes at odds, in the design process.

 Titanium is historically utilized in airframes to solve specific problems related to high temperatures, specific strength or corrosion. For graphite-reinforced composites, the natural compatibility of titanium relative to aluminum or steel alloys has lead to an increase in the fraction of titanium alloys on the airframe, but with concordant increases in build costs. This has lead to an evolution in the needs of the airframe industry with respect to titanium alloy properties and utilization.

 This paper will provide an overview of typical applications of titanium alloys and what the design drivers are for these applications. The purpose of this paper is to relate these needs to the titanium industry so that better alloy development solutions can be conceived and offered.

Titanium processing - reduced buy:fly

Low Cost Near Net Shape Forgings from Ti-6-4
T. A. Witulski1, G. T. Terlinde1, M. Knuewer2, (1)Otto Fuchs KG, Meinerzhagen, Germany, (2)Airbus Deutschland, Bremen, Germany

Considering the high material and machining cost of titanium alloys the development of a near net shape forging technology for titanium alloys is very attractive since it allows reducing the cost both on input weight and on machining.

 Near net shape forgings can be produced by isothermal forging but this leads to high costs for the dies and very long processing times due to the low strain rates necessary to reduce the flow stresses during forging. An economic alternative to isothermal forging is beta forging. In this process the flow stress is significantly reduced by processing the material above the beta transus temperature which results in low forging forces and a good die filling behaviour.

 The process has been qualified on Airbus A340 roller tracks and subsequently extended to the serial production of roller tracks for the A380 and several forgings for the A400M military transport plane.

When Investment Casting is Good Value
R. Gerke-Cantow, Titan-Aluminium-Feinguss GmbH, Bestwig, Germany

The term casting often suggests products with properties generally inferior to wrought products. This is not true with titanium cast parts.
The main reason is the β to α+ β phase transformation at a temperature of about 1000 °C, which changes the cast structure completely, leading to an α+ β lamellar structure, which is also typical of β processed wrought alloy.
To reduce the material costs recycling of solid scrap and turnings as well as cold-hearth melting processes for the production of ingots are established in the industry. With this the titanium consumption of foundries related to their casting weight produced (buy-to-fly) can be reduced to values well below 2 (depending on the parts to be produced).
The increasing demand for titanium products in the past led to a substantial increase in the price for the metal.  Consequently, old and new designs are considered for a casting solution as the leading near-net-shape technology available. This in turn indicates that for geometrically complex parts with a high amount of human labour in production, casting is a cost effective alternative to milled products due to reduced material and lower machining costs.
Also the reduction of the well known casting factor is once again a topic on customers’ agendas. The investigations performed in TITAL show that the investment casting process is also in terms of process variability (coefficient of variation) on a level playing field with its wrought products competition.
In addition, the advantages of investment castings are the realization of complex structures, run through of load path, reduction of part numbers, minimized assembly, less milling, less drawing expenditure…

Mechanical Properties of Cast Ti-6Al-4V Lattice Block Structures
E. Y. Chen1, Q. Li2, D. R. Bice1, D. C. Dunand3, (1)Transition45 Technologies, Inc., Orange, CA, (2)University of Nevada, Reno, Reno, NV, (3)Northwestern University, Evanston, IL

Lattice block structures (LBS) - also called lattice-truss structures, truss-core sandwiches, and cellular lattices - are three-dimensional-periodic reticulated materials that derive their outstanding mechanical performance from a high-symmetry arrangement of internal trusses connected at nodes.  They are innovations that provide tremendous opportunities for weight and cost reduction in future aerospace systems, both commercial and military.  In this presentation, the structural and mechanical characterization of individual Ti-6Al-4V struts and complete Ti-6Al-4V LBS panels produced by investment casting are reported.  Testing in compression, bending, and impact show that high strength, ductility and energy absorption are achieved for both individual struts and full panels, despite the difficulties of casting such fine struts from a highly reactive liquid titanium alloy.  The experimental compressive stress-strain behavior of the LBS panels will be compared to finite-element modeling predictions.  This work was supported by NASA-Glenn Research Center.

Development of Advanced Titanium Welding Processes for Improved Material Utilization in Aerospace Manufacturing
P. Edwards1, G. Coleman2, D. G. Sanders1, G. L. Ramsey1, J. Bernath3, T. Trapp4, (1)The Boeing Company, Seattle, WA, (2)Boeing Commercial Aircraft Group, Seattle, WA, (3)EWI, Columbus, OH, (4)Edison Welding Institute, Columbus, OH

The use of Titanium by the aerospace industry has recently been driven to unprecedented levels, which has resulted in price escalations and temporary supply shortages.  Most titanium parts are machined out of plate, blocks, forgings or extrusions, which all result in wasted scrap material and unnecessarily high fabrication costs.  In order to reduce the buy-to-fly ratio of titanium parts, more efficient manufacturing techniques must be implemented.  Laser Welding of titanium 6Al-4V has been developed for producing near net shape structural components.  Process parameters have been identified for producing very repeatable, high quality welds on a variety of material thicknesses and joint configurations.  Extensive metallurgical examinations and preliminary mechanical property evaluations have been performed to qualify this process for fabricating structural parts.  It has been found that the mechanical properties of automated Laser Welded titanium joints are very close to being the same as the parent metal and that equivalent performance can be achieved with a minimal weight increase to the overall part.  Furthermore, the statistical variance in the mechanical test data is very low which is extremely important for efficiently designing any performance critical part as a welded structure. 

In addition to Laser Welding, Friction Stir Welding of titanium 6Al-4V is being developed for a variety of thicknesses and joint configurations.  Friction Stir Welding is a solid state welding process capable of retaining the microstructural integrity of the parent material.  This makes Friction Stir Welding very attractive for welding fatigue critical and damage tolerant primary air frame structure.  Preliminary mechanical test data has shown that the fatigue properties of Friction Stir Welded titanium butt joints are comparable to parent material. The primary difficulty in the development of heavy gage titanium Friction Stir Welding was to identify the tooling designs and process parameters for producing defect free joints. 

Finally, by combining one of these advanced welding techniques with Hot Forming, near net shape parts can be produced with aerospace quality dimensional tolerances at a dramatically improved material utilization level.  The main considerations for developing Hot Forming of welded titanium structures include tooling designs and processing techniques.

Development of the Hot Stretch Forming Process Technology
M. W. Moffat, Cyril Bath Co., Monroe, NC

Hot Stretch Forming of Near Net Shape Titanium Profiles

 

The development of Hot Stretch Forming was motivated by the need to design and manufacture Titanium airframe structures for new aircraft with carbon fiber fuselage skins.  Many of these structures are contoured to fit against the inside radius of the fuselage curvature.  By combining traditional stretch forming technology with hot metal forming techniques, the new technology of Hot Stretch Forming (HSF) was developed by the Cyril Bath Company.  This new forming technology allows design engineers to develop a variety of Titanium structure profiles that will be curved to a specific and precise radius prior to final machining.

 

This new technology is cost effective, repeatable, and available to be used for immediate production in volumes to meet aircraft build rates, now and in the future.  The Hot Stretch Forming process saves both material and machining time; both serious cost issues for today’s aircraft build budgets.  In addition, the process allows for consistent quality, assuring the sustainable attainment of delivery and build schedules.

 

A general description of the HSF process will be presented, including stretch press designs, control and heating systems, metallurgical issues, tooling issues, and material handling issues.  The benefits of this process in controlling and minimizing residual stress allowing consistent machining will be discussed.   

Titanium machining

Use the HSS Cutters for Titanium Alloys Machining!
P. Bach, Czech Technical University in Prague, Prague 2, Czech Republic

The paper is focused on milling of Titanium alloy Ti6Al4V using HSS cutters. This kind of material is obviously machined by carbide tools. But, it is possible to use also HSS tools and low cutting velocity. Under this condition performance of the HSS tools can be higher than the performance of the carbide tools. Performance of any machining operation is limited by chattering. When milling, stability diagram can be calculated to find stable depth of cut (DOC) and stable ranges of spindle speed. DOC level depends on dynamic stiffness of the tool – spindle mechanical system. Titanium milling needs a stiff tool-spindle structure powered by a strong motor. Stable DOC at low cutting speeds is significantly higher comparing to stable DOC available within high speed range. The paper shows stable diagrams as well as couple of curves referring the tool life under this condition. The results for tool materials obtained by the technology of Powder Metallurgy are promising.

Machining Titanium Alloy With Pulsed Injecting Coolant Technique To Improve a Eco-Friendly Enviornment in Industries
S. Ramesh1, L. Karunamoorthy2, K. Palanikumar1, K. Elangovan1, (1)SATHYABAMA UNIVERSITY, Chennai, India, (2)ANNA UNIVERSITY, Chennai, India

Machining plays a predominant role in making of components in many critical applications such as aerospace, transportation industries, and biomedical engineering. Environmental concerns call for the reduced use of cutting fluids in machining practices. New cutting techniques are to be investigated to achieve this objective. In the present work a specially formulated cutting fluid was applied as a high velocity, thin pulsed jet at the immediate cutting zones at an extremely low discharge with high speed using a fluid application system developed for this purpose during turning of titanium alloy. Aerospace material machining in complement with a plentiful supply of cutting fluid is the normal practice on the shop floor, which is supposed to exploit the cooling, lubrication and chip removal action of cutting fluids. However recent concepts and awareness of sustainable manufacture are often on a collision course with the use of cutting fluids. Large quantity use of cutting fluids pose problems of procurement, storage, disposal and maintenance. In other words, apart from the cost, flood application is not environment or people friendly. This factor assumes considerable significance in the recent climate of strict work safety and environmental protection. According to the Occupational Safety and Health Administration (OSHA) regulations, the permissible exposure Level for mist within the plant (PEL) is 5 mg/m3 and is likely to be reduced to 0.5 mg/m3. This paper aimed at studying the performance of CBN tool inserts in the machining of Titanium alloy. Machining of titanium alloy is investigated in conventional dry turning and wet turning with minimal fluid application methods by varying parameters such as speed and feed, maintaining constant depth of cut. The cutting performance in turning of titanium alloy with pulsed jet coolant system is evaluated by using the performance investigators such as tool flank wear, surface roughness, and cutting force.

Improved Titanium Machining: Modeling and Analysis of 5-Axis Tool Paths via Physics-Based Methods
T. Marusich, D. A. Stephenson, S. Usui, L. N. Zamorano, Third Wave Systems, Minneapolis, MN

The manufacturing of monolithic aerospace structures entails development of complicated 5-axis tool paths containing thousands of lines of code and dozens of tool changes for milling and drilling operations.  In-cut machining cycle times of 50 -100 hours time are common. Meaningful reduction of cycle time while maintaining part quality is predicated upon the ability to model the physics of the machining operations. A methodology to predict forces and temperatures used for analyzing large, complicated 5-axis tool paths for aerospace structure machining is presented. The ability to accurately model lengths scales from the chip load (~100 microns), part thickness (~2 mm), cutter depths of cut (~10 mm) and over part dimensions (~10 m) is provided. Forces and temperatures are predicted over the entire tool path using analytical and numerical techniques to extend an empirical database to generalized cutting conditions. Comparison between measure and predicted forces are provided for validation. Primary barriers to achieving high metal removal rates of titanium and other hard to machine materials include: 1) lack of validated analytical development tools to reduce dependency on testing trial and error methods, 2) high cost and inefficient methods for testing new machining concepts, 3) inherently different machining characteristics (i.e. material characteristics and behavior during machining) of titanium and other hard to machine materials, and 4) high cost of raw materials.
This presentation will also demonstrate the application of new and existing modeling technology  to cost effectively reduce the first 3 of 4 barriers identified above. This will be accomplished by:  use of validated process modeling technology specifically developed for modeling metal cutting, use of process modeling techniques to significantly reduce the need (and cost) for testing while increasing the efficiency and successful implementation of new concepts, and use of validated material modeling technology already developed specifically for machining applications.

Progress in Deposited Titanium: Drafting MAI
B. Slaughter1, K. T. Slattery2, R. Martin1, D. Heck3, A. M. Helvey3, R. R. Boyer2, (1)Boeing Phantom Works, St. Louis, MO, (2)The Boeing Company, Seattle, WA, (3)The Boeing Company, St. Louis, MO

The field of deposited metals continues to grow at a rapid pace.  While the technologies face their share of technical challenges, arguably the greatest challenge for these technologies is acceptance.  This presentation will give an overview of the technical challenges and progress, acceptance challenges and approaches, and how the past work (e.g.: Metals Affordability Inititive) are being leveraged to qualify new technologies.

CNC Code Generation for Electron Beam Free Form Fabrication
W. J. Seufzer, K. M. Taminger, NASA Langley Research Center, Hampton, VA

Generating CNC (Computer Numerical Control) code for a layer additive process is fundamentally different from a subtractive process. In a subtractive process, tool paths and tool changes are computed to remove material from a billet leaving behind the specified shape. In a layer additive process tool paths and tool changes need to fulfill the opposite goal of building a part in empty space. In the case of Electron Beam Free Form Fabrication (EBF3) another degree of freedom exists, which is changing the tool ‘on-the-fly'. The electron beam parameters can change while the deposition moves along the tool path. The need for changing EBF3 parameters along the tool path arise from three requirements. First, EBF3 parameters may need to change to ensure a uniform deposit as the positioning systems accelerate and decelerate along their axes of motion. Second, parameters may need to change to correct geometry errors from previous deposits such as slight variations in planned versus actual build layer heights (variations will occur without a closed loop control system). Third, parameters may need to change to facilitate a functional gradient in either geometry or material properties. This presentation will summarize effort that has been made in two functional areas: tool path generation and parameter variation along the tool path.

Titanium processing - Direct Titanium Manufacturing

Electron Beam Freeform Fabrication Alliance to Reduce Buy-to-Fly Ratios for Titanium Components
K. M. B. Taminger, NASA Langley Research Center, Hampton, VA

NASA Langley is attempting to catalyze a national capability to build metallic industrial components without the huge waste of current large scale milling process.  Electron Beam Freeform Fabrication (EBF3) is an additive metal process using an electron beam, wire feed, and computer controls to build near net shaped components, either by addition of details onto a simplified preform or by fabricating the entire component.  The EBF3 process can be used to reduce high buy-to-fly ratios (12:1 to 20:1 are not uncommon for some components) down to less than 5:1, offering significant savings in resources such as raw materials, energy consumed, fewer chemicals (cutting fluids), and lead time as compared with current practices of machining large volumes of chips out of a solid billet.  Researchers at NASA Langley have led research and development of the EBF3 process since 2002.  NASA’s goals in developing this technology include process controls for unattended operation and repeatability, certification of EBF3 processed materials for space hardware applications, demonstration of space-qualified hardware to support long duration human exploration missions, and development of tailored structures with integrated multifunctionality for aerostructural applications.  Industrial applications of the EBF3 process include the production of replacement components for aging aircraft as well as reducing cost, lead time, and environmental responsibility for production of new aircraft components more efficiently than hogging out components from oversized billets of metal.  An innovative alliance between NASA and industry has recently been formed to accelerate the certification and standards process and stimulate the growth of a competitive supply chain for providing commercial EBF3 services within the next 4 to 5 years.  This talk will discuss the alliance technical goals and progress towards those goals as they relate to inserting the EBF3 process into the industrial sector.

The Approach to Solving the EBFFF Aluminum Loss Issue by Operating at Higher Chamber Pressures
B. Woods, R. Nasserrafi, H. Ehlers, Spirit AeroSystems, Inc., Wichita, KS

EBFFF uses an electron beam as an energy source to melt weld wire to build titanium components in a layer by layer fashion. The typical operating environment is done at very low pressures (~1 x 10-4 torr or lower), unlike almost any other welding or additive manufacturing process, which operate under an inert gas. EBFFF has been touted as having deposition rates as high as 40 pounds per hour due to the large available power and high efficiency of the electron beam system.

 

This presentation will focus on the DOE that Spirit AeroSystems completed at Sciaky Inc. The approach of this DOE was to show that operating pressure, the temperature, size/geometry of the melt pool and time at temperature are the major causes of the aluminum loss. Of the above factors, we could only directly measure the operating pressure. Therefore efforts were initiated to gain fundamental understanding of factors that we believed could be affecting melt pool geometry and the time above liquidous temperature. A look at the vapor pressure curves of aluminum, titanium, vanadium, and Ti 6Al-4V will be considered, as well as the coupling of temperature and pressure which places the molten metal above the vapor pressure of this alloy causing aluminum burn-off. 

 

To gain a better understanding of the impact of power and energy on melt pool geometry, different power settings were applied to alpha-beta forged base plates for different time spans. The test was performed to form both spots and lines, with and without the addition of wire. The information obtained will be used to develop controls to eliminate or reduce the aluminum burn-off and to validate finite element models.

Microstructural and Microanalytical Study of the Effect of Processing Parameters on the Al Loss and Deposition Efficiency of EBF3 Ti-6Al-4V Alloys
S. N. Sankaran1, K. M. Taminger2, R. A. Hafley2, C. L. Lach2, (1)Lockheed Martin, Hampton, VA, (2)NASA Langley Research Center, Hampton, VA

Electron beam freeform fabrication (EBF3) represents a significant paradigm shift in the manufacture of metallic aerospace structures from integrally-stiffened structures designed for assembly to novel unitized structures designed for multi-functional performance optimization. EBF3 feeds metal wire into a molten pool formed and maintained by an electron beam in a high vacuum environment (10-5 torr). The challenges of molten pool processing of Ti-6Al-4V in a high vacuum are due to the differences in the vapor pressures of the alloy constituents at the melting point of titanium which result in selective vaporization of aluminum, and make control of the chemical composition and mechanical properties difficult.

A three-factor, three-level Taguchi design of experiments (DOE) study was conducted to rank the importance of processing parameters, identify any nonlinear parameter couplings, and define the optimal metal deposition parameters to maintain the Aerospace Material Specification (AMS) compositional requirements for aluminum content in Ti6Al-4V. A broad range of values for each process parameter (beam power, translation speed, wire feed rate) was selected for the study, to produce deposits with chemistries spanning the entire AMS Ti6A-4V composition range for aluminum. Bulk compositions of 27 single-bead deposits were determined by the Direct Current Plasma technique (DCP). By applying DOE response surface methodology (RSM) on the bulk chemistry data, three-dimensional response surface and contour plots enable the prediction of aluminum content, as a function of critical EBF3 processing parameters. The sharpest rising gradient of the response surface design for a given set of processing parameters will indicate the direction of optimum EBF3 operating conditions to maximize the aluminum content of the Ti6Al-4V deposits.

Compositional analysis conducted on a subset of the test matrix (three-factor, two-level) confirmed that EBF3 of Ti6Al-4V in a high vacuum had a negligible effect on the vanadium and H2 content in the single-bead deposits.

Characterization of Electron Beam Free Form Fabrication Systems Using Enhanced Beam Diagnostics
K. W. Lachenberg1, S. D. Stecker1, R. C. Salo1, J. W. Elmer2, (1)Sciaky, Inc., Chicago, IL, (2)Lawrence Livermore National Laboratory, Livermore, CA

Introduction

The development of diagnostic tools for characterizing electron beams has been growing in prominence.  The Enhanced Modified Faraday Cup (EMFC) also known as EB-Profiler, developed at Lawrence Livermore National Laboratory (LLNL) and licensed by Sciaky to build, provides measurements of the general size and shape of the beam and the power density distribution across its width.  This tool has been utilized in a number of applications, including the characterization of machine performance and repeatability for electron beam welding (EBW) equipment, the transfer of parameters between welders at remote locations, and as a process control tool.  The EB-Profiler is proving to be a useful tool in monitoring & diagnosing EBFFF performance. 

Results/Discussion

Previous work with the EB-Profiler has been limited to high voltage (150 kV) machines with fixed guns.  In this work, the use of the EB-Profiler tool has been expanded to include enhanced low voltage (60 kV) EBW/EBFFF machines with moveable gun configurations designed and manufactured by Sciaky, Inc.  Tests have been performed at Sciaky on machines with different configurations and process conditions.  Variations in the characteristics of the beams produced by the different generation machines and the differences in sharp focus beams at various work distances will be discussed.  The utility of the diagnostic tool in providing a better understanding of the operation of the equipment to improve, monitor and control the EBFFF process will be presented.  The outputs from the EB-Profiler include peak power density and through computer tomographic reconstruction, a 3D model of the energy distribution.  Differences in output can be a result of many factors including differences in vacuum levels and other operating conditions. Once a process has been qualified, diagnostic tools of this type will insure that the process is properly maintained in production.

Microstructure and Mechanical Properties of Ti-6Al-4V Components Fabricated by Shaped Metal Deposition
B. Baufeld1, O. Van der Biest1, R. Gault2, (1)Katholieke Universiteit Leuven, Leuven, Belgium, (2)University of Sheffield, Rotherham, United Kingdom

Shaped Metal Deposition (SMD) is an innovative time-compression technology, which creates near-net shaped components in a variety of materials by weld deposition. Especially for Ti alloys, which are difficult to shape by traditional methods such as forging, machining and casting and for which the loss of material during the shaping process is also very dear, SMD promises great advantages.

Ti alloys are very sensitive on the thermal history and this method introduces for each welding step another temperature gradient leading to a particular microstructure. The microstructure Ti-6Al-4V components will be correlated with the SMD process. Furthermore, the mechanical properties of the material, elastic modulus, ultimate tensile stress, and plastic deformation will be presented.

Determining Melt Pool Temperature in Ti-6-4 Electron Beam Freeform Fabrication Deposition
R. A. Hafley1, K. M. B. Taminger1, E. K. Hoffman1, S. N. Sankaran2, K. Butcher2, (1)NASA Langley Research Center, Hampton, VA, (2)Lockheed Martin, Hampton, VA

The electron beam freeform fabrication (EBF3) process uses an electron beam and wire to fabricate metallic structures directly from computer aided design data in a layer-additive process. The EBF3 process is capable of bulk metal deposition at deposition rates in excess of 150 in3/hr or finer detail at lower deposition rates, depending upon the desired application. This process offers the potential for rapidly adding structural details to simpler cast or forged structures. In contrast to the conventional approach of machining large volumes of chips to produce a monolithic metallic structure, selective addition of metal onto simpler blanks of material promises significant reduction in lead time, material expenditure and machining costs. However, before the process can be industrially applied and certified for use in flight hardware, the properties of the deposited material and the interfaces between the base and the deposit must be thoroughly characterized. This paper will present tensile, fatigue and fracture data for thin-walled Ti-6-4 EBF3 deposits and compare the data to typical wrought material properties.

Plasma Transferred Arc Rapid Additive Manufacturing
R. S. Storm, V. Shapovalov, J. C. Withers, R. O. Loutfy, MER Corporation, Tucson, AZ

The use of a plasma transferred arc welding torch as the high energy source for additive manufacturing results in several advantages vs. alternate high energy beams.  These advantages will be discussed and examples of demonstrated capabilities presented. For example, MER has produced billets of Ti-6Al-4V for Spirit AeroSystems for their testing to evaluate the PTA process for manufacturing of aircraft components.  In addition to the low cost fabrication of metallic structures, this technology has also been utilized to form very hard surface layers of a cermet composition which are functionally graded to the substrate.  These layers have excellent wear and corrosion resistance.  Graded composites have also been produced for structural applications.  In both the structural and coating applications, the gradation results in an exceptionally strong bond.  For the case of titanium alloys, a new very low cost approach will be discussed which utilizes a cold rolled “quasi” wire formed from Ti sponge and prealloyed Al-V powder.  High strength titanium foam has also been produced to near net shape and with in-situ skins for structures.

Welding and Joining

Welding & Joining #1

Ti-6Al-4V Alloy Welding using a High Power Continuous Wave Nd:YAG Laser
X. Cao1, M. Jahazi1, J. Cuddy2, A. Birur2, (1)NRC Institute for Aerospace, Montreal, QC, Canada, (2)Standard Aero Ltd, Winnipeg, MB, Canada

Ti-6Al-4V is the most widely used titanium alloy and falls in the α + β category.  Due to its high strength and light weight, along with good tensile and creep properties up to about 300ºC, it is widely used for turbine disks, blades, and airframe structural components. Conventionally, TIG and plasma arc welding techniques are used to weld titanium alloys. CO2 laser welding of Ti-6Al-4V alloy has also been reported. However, little has been published about the weldability of Ti-6Al-4V alloy using high power solid-state Nd:YAG laser. This work reports on the laser weldability of Ti-6Al-4V alloy with four thicknesses ranging from 0.8 to 3 mm using a 4 kW Nd:YAG laser welding system. The effects of main processing parameters including laser power, welding speed and defocusing distance on surface morphologies, welding defects, microstructure, microindentation hardness and tensile properties are investigated. The optimized process windows are determined indicating that Nd:YAG laser welding is an attractive method for Ti-6Al-4V alloy. However, the welding quality of the thinnest sheets is very sensitive to laser processing parameters and the right combination of laser power and welding speed is highly required. Very little porosity was observed in the welded joints of the thin sheets while more microporosity was observed in the thicker titanium alloy sheets. No detectable cracks are observed in all thicknesses used in the present study. The microstructure of the fusion zone revealed a needle-like martensite α’ structure formed from β phase due to the high cooling rate associated with laser beam process, leading to the increase of fusion zone hardness compared with the base metal. The microstructure of the heat-affected zone is a mixture of martenstic α’ and primary α. The effects of selected processing parameters on tensile properties are also discussed in detail.

High Power Continuous Wave Nd:YAG Laser Welding of Inconel 718 Alloy
X. Cao1, B. Rivaux2, M. Jahazi1, J. Cuddy3, A. Birur3, (1)NRC Institute for Aerospace, Montreal, QC, Canada, (2)Ecole des Mines de Paris, Sophia-Antipolis, France, (3)Standard Aero Ltd, Winnipeg, MB, Canada

Inconel 718 alloy is a precipitation-hardened nickel-iron base superalloy widely used in gas turbines, rocket motors, spacecraft, nuclear reactors, pumps and tooling due to its good corrosion resistance, high strength, and stable microstructure at elevated temperature. It has excellent weldability but suffers from liquation cracking in the heat-affected zone. However, very little has been reported on high power Nd:YAG laser welding of IN718 alloy. In this study, the weldability of IN718 alloy in two thicknesses (0.76 and 3.18 mm) was investigated using a 4 kW Nd:YAG laser system. The effects of laser power, welding speed, defocusing distance, heat treatment prior to welding and post-weld heat treatment conditions on butt joint quality are characterized from surface morphologies, joint shapes, welding defects, microstructure, hardness and tensile properties. It is found that (sound) welds without macrocracks and with minor (macro) porosity can be obtained, indicating that solid-state Nd:YAG laser welding is a suitable method for IN718 alloy. Optimum process window for welding of IN718 was constituted and sound weld joints with joint efficiencies of 90-100% were obtained. Tensile failure occurred predominantly in the fusion zone. There is a significant increase in hardness in the fusion zone probably due to the presence of the interdendritic Nb-rich Laves and the NbC precipitates inside the dendrites. The HAZ hardness was found to lie between the fusion zone hardness and that of the base material. Higher hardness values measured in the HAZ are probably due to the re-precipitation of the principal strengthening phases (γ’ and γ’’) during post weld cooling. The fusion zone is composed of fine and elongated dendrites. The heat affected zone has similar microstructure to that of the base metal but slight grain growth is observed.

Laser Welding of Advanced High Strength Steel DP980 and Joint Property Restoration by Heat Treatment
D. Lin1, M. S. Yang1, M. F. Kong1, P. D. R. Kovacevic1, R. Ruokolainen2, D. X. (. Gayden2, (1)Southern Methodist University, Dallas, TX, (2)General Motors Corporation, Warren, MI

Dual phase steel DP980, one of the advanced high strength steels, has attracted great attention from automobile industry since it has high strength, high-energy absorption in the crash testing, and good formability. Feasibility study of laser welding of DP980 at butt-joint configuration has demonstrated that the welded joint of this material are characterized by the high strength but with the low toughness and the low formability. Higher welding speed can increase the joint strength since it reduces the size of heat-affected zone, but it cannot effectively improve the toughness of the welded joint. To restore the original material properties at the welded joint, various post-welding heat treatment processes have been tested, including: (1) step quench with heating performed in a furnace followed by quenching in various media, (2) local heat treatment done by direct diode laser beam, and (3) heat treatment using defocused fiber laser beam. The investigations have shown that: (1) step quench can soften the welded joint which results in a decreased joint strength and an extremely high elongation, (2) direct diode laser beam, characterized with a uniform heat input, can soften the weld and the heat affected zone vertically through the thickness of the specimen, so that the strength of the welded joint decreases slightly, but with significantly modified toughness, and (3) a defocused fiber laser beam can re-melt the welded joint such that the joint strength is still high, but with little toughness improvement. Selection of the post-welding heat treatment process strongly depends on the anticipated manufacturing processes following the welding operation. A further investigation has shown that the volume fraction and the distribution of martensite in the weld/heat affected zone play a critical role in the joint strength, and the final tempering of martensite in the weld zone contributes to the improvement of the toughness.

Laser Beam Welding of Titanium – A Comparison of CO2 and Fiber Laser for Potential Aerospace Applications
S. Mueller1, C. Bratt1, J. Cuddy2, M. K. Shanker2, (1)Fraunhofer USA, Plymouth, MI, (2)Standard Aero Ltd, Winnipeg, MB, Canada

The Laser welding process is increasingly being considered for joining titanium alloy airplane structures and also for manufacture, repair and overhaul of titanium aeroengine components. Recent advancement in gas and solid state laser technology has resulted in the availability of higher beam quality Lasers which can produce narrow welds with low heat input and high weld speeds. This paper describes a study of Laser welding of the Titanium alloys Ti6-4 and Ti5553 using two types of high power Laser - a CO2 Slab Laser and an Ytterbium-Fiber Laser. The differences between both Lasers and their effect on weld quality and performance will be explained. The weld results are evaluated referring to AWS weld quality standards, which particular reference to porosity appearance and weld profile. In addition, micro hardness measurements and tensile test data will be shown.

Gas Metal Arc Weld (GMAW) Repair of Titanium Alloys for Turbine Engine Applications
D. A. Hartman, M. J. Cola, V. R. Dave, Beyond6 Sigma, Santa Fe, NM

Integrally Bladed Rotors – IBRs – are an important part of current and future military aeroengines. The use of IBR allows lower weight rotors with decreased drag and improved compressor efficiency. Repair of these parts however is currently problematic. The repair process selected must have the following attributes in order to be successful: i) it must not compromise the remaining life of the IBR; ii) it must be amenable to flexible operations that could be located globally; and iii) it must be cost-effective vs. the price of replacement.      Arc welding technologies are very cost-effective and are amenable to automated robotic operations, but there are significant process control and weld quality challenges that are barriers to entry for such technologies.
In this work we show a path to develop and validate a prototype process for Titanium Gas Metal Arc Welding (GMAW) for IBR weld repair. Titanium GMAW is challenging on account of the tendency for the cathode spot to wander, thereby creating an arc instability that impacts the weld bead geometry as well as weld quality.   Additionally, there are challenges in the synchronization of pulses in the power supply to assure good bead geometry as well as uniform material transfer. To overcome these challenges and to meet the stringent quality requirements for IBRs, a novel monitoring and control methodology known as In – Process quality Assurance – IPQA – is implemented to sense and control vital aspects of the welding process not possible with current approaches.      Practical examples are shown and the progress towards a viable GMAW repair process is reviewed, including metallurgical and weld quality aspects, weld parameters and weld process stability, and the end-goal of integration of the technology into commercially available power supplies.

Friction Stir Welding Process Evaluation

Flaws in Aluminium Alloy Friction Stir Welds
M. F. Gittos1, A. J. Leonard2, (1)TWI, Cambridge, United Kingdom, (2)BP Exploration Company Ltd, Middlesex, United Kingdom

Process variables affect joint quality. Successful, reproducible welds may be produced by operating within process “windows”. However, problems arise when welding conditions deviate from the operating window. A need exists to understand the types of flaws that may be generated and their causes. Welds were made in 6mm thick 2014A, in which processing parameters were varied outside of the operating window. They were assessed using radiography, ultrasonic inspection and light microscopy. The types of flaw produced could be categorised either as voids or joint line remnants. The former were produced in two ways: forging pressure exerted on the workpiece was reduced and welding speed was increased, reducing the working of the metal and the heat input. A joint line remnant was introduced by using a tool that was too short for the plate thickness. This left a region of the original interface that had not been adequately disrupted by tool rotation. A root flaw could be very small and may not be detected by NDE. A joint line remnant could also consist of a line of oxide particles from the original interface extending through the weld. This was achieved by anodising the surfaces, prior to welding.

It was found that voids may be formed when insufficient forging pressure is applied to the weld or the welding speed is too high. A joint gap of up to 2mm could be tolerated. Joint line remnants occurred when pre-weld cleaning was inadequate but machining, prior to welding, is effective in restricting their occurrence. Joint line remnants, as root flaws, are introduced when either insufficient pin depth or tool plunge depth is selected, or when there is poor tool-to-joint alignment. Appropriate selection of such parameters may eliminate these flaws. However, for critical applications, machining of the weld root may be advisable.

Joint Quality Evaluation and System Verification of Friction Stir Welds
M. J. Soron, J. Norström, ESAB AB Welding Equipment, Laxå, Sweden

For more than a decade, high quality seams have been joined using Friction Stir Welding (FSW) in the aerospace and aircraft industries. The seams have, so far, been joined using large customized machines devoted to single task operations. Although providing a high quality output the lack of flexibility of such machine, mainly caused by the limited dextrous workspace, has limited the process from being used to a greater extent. By introducing a more flexible solution based on an industrial robot, modified to fulfil the requirements of the process to a certain extend, opportunities to join complex shaped objects with FSW is provided. In this paper we investigate the use of an industrial robot to apply FSW, the quality of the joints applied and the limitations of such system.

Degradation Studies of Friction Stir Welds
D. Larson, D. B. Mitton, Z. Huq, M. Cavalli, University of North Dakota, Grand Forks, ND

Recently some commercial aircraft have been fabricated with more than 60% of the rivets replaced with FSW joins. The replacement locations have included the cabin, aft fuselage, wings and engine mounts. Benefits include a reduction in painting preparation time, a lighter airframe and smoother structure. In addition, fatigue resistance and durability are comparable with single-row riveted joints. Nevertheless, the degradation in FSW joins is known to be asymmetrical in nature, with the advancing and retreating side of the same weld behaving differently from the electrochemical and corrosion standpoint. During this work, the behavior of aluminum alloys with and without FSW joins has been investigated in an aggressive chloride containing aqueous environment. Joins were assessed for degradation properties using traditional electrochemical methods, EIS, SVET, microscopy and in-situ corrosion fatigue monitoring.

Assessment of Friction Stir Weld Integrity for Process Control
D. Levesque1, L. Dubourg2, C. Mandache3, P. Gougeon1, X. Cao4, M. Jahazi4, (1)National Research Council Canada, Boucherville, QC, Canada, (2)National Research Council Canada, Ottawa, ON, Canada, (3)Institute for Aerospace Research, National Research Council of Canada, Ottawa, ON, Canada, (4)NRC Institute for Aerospace, Montreal, QC, Canada

This paper reports on the development of innovative inspection methods for the detection of typical defects in friction stir welds (FSW). The defects related to changes in material conditions or welding parameters are lack of penetration, worm holes and kissing bonds (vertical) in butt joints, and hooking, worm holes and kissing bonds (horizontal) in lap and T joints. Kissing bonds originate from the remnants of trapped oxide layers and are known as the most challenging problem for inspection of FSW joints. Ultrasonic immersion or laser-ultrasonics combined with the synthetic aperture focusing technique (SAFT) is investigated. Laser-ultrasonics uses lasers for the generation and detection of ultrasound and is therefore non-contact, ultimately for weld assessment during welding. Another promising method is pulsed eddy current (PEC) technique, which induces electrical currents in conductive parts, while measuring the direction and magnitude of the resulting magnetic fields as an indication of material condition. Various FSW lap and butt joints for aerospace applications are examined, including dissimilar metal welds. Very good performances are achieved with the two methods for lack of penetration in butt joints, the limit of detectability coinciding with the conditions of reduced mechanical properties. Also, discontinuities such as wormholes, hooking and voids in lap joints are clearly detected using SAFT. The detection of kissing bonds seems to be possible in lap joints using high frequency laser-ultrasonics.

Friction Stir Weld Restart Plus Reweld Repair Allowables
A. Clifton, Lockheed Martin Space Systems Company, New Orleans, LA

A friction stir weld (FSW) repair method has been developed and successfully implemented on Al 2195 plate material for the Space Shuttle External Fuel Tank (ET).  The method includes restarting the friction stir weld in the termination hole of the original weld followed by two reweld passes.  Room temperature and cryogenic temperature mechanical properties exceeded minimum FSW design strength and compared well with the development data.  Simulated service test results also compared closely to historical data and were in family with legacy FSW data for normal FSW, confirming no change to the critical flaw size for the repaired welds or inspection requirements. Testing of FSW/VPPA fusion intersection weld specimens exhibited acceptable strength and exceeded the minimum design strength.  Porosity, when present at the intersection was on the toe of the fusion weld, the “worst case” being 0.700 inch long. These “worst case” porosity conditions were tested “as is” and demonstrated that porosity did not negatively affect the strength of the intersections. Larger, 15-inch “wide panels” were tested to demonstrate strength and evaluate residual stress using photo stress analysis.  All results exceeded design minimums, and photo stress analysis showed no stress gradients due to the presence of a restart and multiple rewelds in the wide panels.

Friction Stir Welding Processing

FSW of Ti Alloys - An Update on Recent Developments
M. Nunn, M. J. Russell, R. Freeman, I. M. Norris, TWI Ltd, Cambridge, United Kingdom

This presentation will describe recent developments at TWI on the joining of Ti alloys using the novel Stationary Shoulder Friction Stir Welding (SSFSW) method. In SSFSW, heat is generated by a rotating tool probe, which is separate from a non-rotating tool shoulder component. The tool shoulder component provides containment to the weld area, but adds no heat to the top surface of the joint.

The SSFSW approach is designed to provide uniform heat input throughout the thickness of the welded material, allowing very stable, high quality, solid-phase joints to be made in Ti alloys. SSFSW has been shown to be a valuable new development of the FSW process, which is particularly suitable for a range of high temperature, low thermal conductivity, materials.

This presentation will review the recent development of the SSFSW technique, and its application to Ti alloys. Examples will be shown of the specialist systems that have been produced to carry out this process, and possible applications will be illustrated via a range of demonstration weld samples.

The development and exploitation of SSFSW offers the potential for a reliable solid-phase welding method for Ti components. Possible applications of this technique include: joining of Ti components, additive manufacture of Ti prototypes and/or machining pre-forms, selective local reprocessing of Ti parts, and repair of damaged areas in Ti structures.

In summary this presentation will provide an overview of recent development work on the FSW of Ti alloys, including examples of demonstration parts produced using the new SSFSW approach.

Nylon-11 based Sealants for Friction Stir Welded Lap Joints
D. C. Van Aken1, R. J. Lederich2, (1)Missouri University of Science and Technology, Rolla, MO, (2)Advanced Manufacturing R&D, Boeing – Phantom Works, St. Louis, MO

Corrosion prevention of friction stir welded joints is an enabling technology for aerospace structures. In this paper, a lap joint sealant based upon the polyamide nylon -11 will be discussed. Nylon-11 is a thermoplastic that can be applied to the faying surfaces of a lap joint and friction stir welded without masking the weld tool path. The nylon-11 melts during welding and bonds the faying surfaces together forming a seal. T-joint assemblies were produced with 2024-T8 top-skins welded to cast A357-T6 stringers in both bare and anodized conditions, with and with out sealants. Joints with the nylon-11 sealant had higher stiffness resulting from adhesive bonding of the lap joint. Bond strength was greatest for the bare aluminum and decreased as the thickness of the anodized layer increased. Limited fatigue testing was performed on nylon-11 sealed friction stir welded T-joints. These assemblies were made using standard sulfuric acid anodized aluminum components and as such the nylon-11 bond was prone to failure. However, these sealed joints had 1 % failure lives comparable to the bare aluminum welds and markedly better fatigue lives than the anodized aluminum welds without sealants. The improved fatigue performance of the sealed joints is attributed to the increase in joint stiffness created by bonding the faying surfaces with the thermoplastic sealant. This bonded configuration also shields the notches created by the junction of the faying surfaces and the weld nugget. In situ corrosion-fatigue tests were also conducted by immersing the bare and anodized specimens in a neutral 3.5% salt solution during fatigue loading. The in situ testing produced a 75% reduction in cyclic life. Addition of a sealant produced only a marginal improvement in life.

Friction Stir Spot Welding of Aluminum Alloys – Process Parameters Optimization Using GONNS
H. Atharifar, D. Lin, R. Kovacevic, Southern Methodist University, Dallas, TX

Friction stir spot welding (FSSW) is a derivative process of friction stir welding (FSW) in which a solid-state joint is made between adjacent materials at overlap configuration. Feasibility studies of the FSSW process have been performed for more than a decade for materials applied in the aerospace industries. However, for a mass production environment, the selection of optimum process parameters is rather less discussed.

In this study, a method based on genetically optimized neural network system (GONNS) is introduced for selecting the optimized FSSW parameters. In this method for a known FSSW setup, type of material, and plate thickness, an artificial neural network (ANN) is designed with the process parameters as inputs and the weld tensile strength, maximum plunging load, and the process duration as outputs. Experiments are performed in order to train the selected ANN. Afterwards, an optimization algorithm is introduced based on the genetic algorithm heuristic search bundled with the trained ANN that aids the algorithm in predicting the value of the target functions. The target functions of the optimization problem are considered as normalized and weighted equations of the weld tensile strength, maximum plunging load, and the process duration.

Eventually, the minimization of the target function yields the optimum FSSW parameters which are verified by additional experiments. Results affirm that the analytically obtained optimum of the FSSW parameters is valid, and using the optimum parameters, the higher weld strength, lower plunging load, and shorter process duration are obtained. 

Progress at Alcan Aerospace on the friction stir welding of Al-Li 2050
P. Lequeu1, J. C. Ehrstrom2, I. Bordesoules3, C. Hantrais2, (1)Alcan Rhenalu, Issoire, France, (2)Alcan, Voreppe, France, (3)Alcan CRV, Voreppe, France

Alcan Aerospace have been very active in the recent past in developing low density Al-Li 3rd generation of alloys, in a collaborative effort with airframers. AA2050 is one such alloy which has received commercial interest for its behaviour in the medium gauge range, where it outperforms reference alloys like 2024 or 2027, with significantly higher static, F&DT and corrosion performance, in addition to lower density and higher modulus. For higher gauges, AA2050 also offers an interesting low density alternative to 7050.
One of the challenges to the extensive use of Al-Li alloys by airframers has traditionally been the extra cost per kilo saved offered by such alloys. This is the reason why work has been performed to decrease their buy-to-fly ratio, among other cost reduction activities. One way of improving this buy-to-fly ratio consists in replacing integrally machined items by assembled parts, each being adjusted to the local thickness needs. When developing such concepts, one has to consider using as much as practical a low cost assembly technique, like what is offered by friction stir welding instead of standard riveting.

 In an attempt to answer such a cost challenge, Alcan Aerospace have performed friction stir welding trials of 17m long structural parts made of 2050 alloy, in collaboration with the Institut de Soudure of Metz, France.

 The presentation will provide the details of the implementation of such project, which proved to be very successful in all aspects, and which is believed to be a world first as far as welding duration is concerned. Extensive static & F&DT properties within the weld and in the heat-affected-zone will also be reported and compared to those of the base-metal.

Development of a Novel Friction Stir Welding/Forging Process
C. B. Smith1, R. Anderson2, (1)Friction Stir Link, Waukesha, WI, (2)Keystone Synergistic, Palm Beach Gardens, FL

A novel friction stir welding (FSW) technique has been developed that is a combined welding and forging process.   This technique is an additive manufacturing process that can be used for manufacture of fabricated shapes or structural assemblies, and can dramatically reduce buy-to-fly ratios.  The welding process is used to join flat (or curved) shapes into tee or I-beam configurations and the forging process is used to form an integral fillet at the intersection of these individual components.  A development and testing program was undertaken to develop a viable welding / forging process.  The results of this development and testing program will be discussed.  Using the process various prototype shapes and assemblies have been fabricated.  These and other potential applications will be discussed.