High-Temperature Spallation Behaviour of High-Entropy System in Thermal Barrier Coatings
Coatings
Michelle Vincent Xavier1, Hamideh Vakilifard1, Farnaz Bayat1
, Rogerio S. Lima2
, Hossein Shahbazi1
, Martin D. Pugh1, Christian Moreau1
1 Department of Mechanical, Industrial and Aerospace Engineering, Concordia University,
Montreal, QC, H3G 1M8, Canada
2 National Research Council of Canada, 75 de Mortagne Blvd, Boucherville, QC, J4B 6Y4,
Canada
Corresponding: michellevincent.xavier@mail.concordia.ca, christian.moreau@concordia.ca
Abstract:
Thermal barrier coating (TBC) systems are multilayer coatings designed to protect hot-section
gas turbine components from extreme temperatures and oxidation; however, conventional
MCrAlY bond coat and yttria-stabilized zirconia (YSZ) topcoat systems exhibit durability
limitations under prolonged high-temperature thermal cycling, motivating the development of
next-generation TBC concepts. In this study, a high entropy TBC system composed of an
HVOF-deposited high entropy alloy bond coat (FeCoNiCrAl) and a suspension plasma sprayed
(SPS) high entropy zirconate (HEZ) topcoat with the chemical composition
(Y0.2Nd0.2Sm0.2Gd0.2Dy0.2)2Zr2O7was studied. In-625 was used as a substrat. A thin YSZ
interlayer was incorporated to improve interfacial compatibility. The high entropy TBC system
was subjected to 1-hour cyclic thermal exposures at 1150 °C until failure to assess its spallation
behaviour and structural stability. A conventional two-layered TBC with comparable
microstructures were used as a reference. These samples comprise an HVOF MCrAlY bond
coat and a SPS YSZ topcoat. The results provide insight into the influence of high entropy bond
coats and topcoats on the spallation resistance and thermal cycling durability of advanced TBC
systems.
Keywords:
Thermal spray, Suspension Plasma Spray, Thermal Barrier Coating, Topcoat, High Entropy
Zirconate, Spallation.
See more of: Thermal Spray Society (TSS) at IMAT
