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Tuesday, May 15, 2007 - 8:20 AM

Residual Stresses in HVOF-Sprayed Ceramic Coatings

G. Bolelli, L. Lusvarghi, F. Pighetti Mantini, University of Modena and Reggio Emilia, Modena, Italy; E. Turunen, T. Varis, VTT Technical Research Centre of Finland, Espoo, Finland; M. Leoni, P. Scardi, M. D'Incau, University of Trento, Trento, Italy

Recently emerging wear resistant HVOF-sprayed ceramic coatings have already been proven to possess superior mechanical and tribological properties compared to conventional plasma-sprayed ones. In order to apply such dense ceramic coatings over steel components, the stress stages and distribution must be controlled. Coatings on AISI 1040 steel substrates were manufactured by H2-fuelled HVOF torch using commercial fused and crushed Al2O3 and Cr2O3 powders and agglomerated nanostructured Al2O3 powder. Stress formation during coating build-up and final residual stresses after cooling were monitored by in-situ curvature sensor, assessing curvature-temperature relations. Stresses in the coatings surface layers were also measured by X-ray diffraction. By dissolving the substrate in HCl+HNO3 solution and measuring the free-standing coating curvature, a significant stress gradient was found in Cr2O3 coating. Gradients were more precisely measured by hole-drilling method. Results obtained by different measurement techniques were compared and discussed in the paper. Stresses were also compared to those measured on atmospheric plasma sprayed Al2O3 and Cr2O3 manufactured with similar commercial powders.


Summary: The development of residual stresses in HVOF-sprayed ceramic coatings during deposition on steel substrates and during cooling has been monitored by in-situ curvature sensor. Stress on as-deposited coatings has also been measured by conventional methods such as X-ray diffraction and hole drilling. Results from different measurement techniques are compared. Stresses on conventional APS ceramics are also evaluated for comparison.