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Tuesday, October 19, 2004 - 10:30 AM
STO 4.5

Thermal, Mechanical, and Electrical Properties of Sodium Alanate

D. E. Dedrick, B. C. Replogle, Sandia National Laboratories, Livermore, CA

Engineering properties characterization of sodium alanate was performed to gain an understanding of how complex hydrides behave within a storage system. Thermal properties were measured using the thermal probe method and analyzed using analytical and numerical methods. The thermal conductivity of sodium alanate was found to vary >90% depending on material phase and gas pressures ranging from 1 to 100 atm. Mechanical properties, specifically pressure exerted on a vessel wall by volumetric expansion, were investigated by measuring the strain of a stainless steel membrane. The expansion pressure was characterized as a function of initial packing density, varying from 0.7 to 1.2 g/cc. Design recommendations for initial packing density (and thus, energy storage density) result from this testing. The DC electrical resistance was also measured as a function of phase. Doped and cycled sodium alanate was found to be a moderate electrical conductor due to free aluminum.

Summary: The thermal, mechanical, and electrical properties of sodium alanate have been characterized to understand the behavior of complex hydrides in storage systems. This effort provides the framework and expertise to measure the engineering properties of new materials as they become viable for hydrogen storage applications.