Surface Engineering Home      Exposition      To Register      ASM Homepage
Back to "Session 3: High Temperature Corrosion 1" Search
  Back to "Surface Engineering for Corrosion Protection" Search  Back to Main Search

Tuesday, May 16, 2006 - 1:50 PM
SECP3.2

Electrically Conductive, Corrosion-Resistant Coatings for Metallic Interconnects in Solid Oxide Fuel Cell

G. V. Pattarkine, N. Dasgupta, A. V. Virkar, University of Utah, Salt Lake City, UT

              Solid oxide fuel cells (SOFC) are electrically connected in series to obtain high electrical output using metallic foils as interconnects. Interconnect materials must exhibit the following properties :(1)Good oxidation resistance (2) Dense and adherent oxide scale formation. (3) Matching thermal expansion coefficient with anode, cathode of SOFC.  (4) Low electrical resistance. (5) Low cost.
             Fe-Cr and Ni-Cr metal alloys have been widely used as interconnect materials. However, due to high operating temperatures (around 800oC), these materials readily oxidize, forming chromia and chromium-containing oxide scale. The oxide scales exhibit high electrical resistance and tend to spall off, both of which make the use of above alloys as interconnect materials problematic without the application of effective ceramic coatings. Prospective ceramic coatings must exhibit low electronic resistivity but a very high resistance to oxygen transport. Many perovskite or spinels are potential candidates as coatings, provided oxygen transport is suppressed through effective doping.  
            Metal alloy foils were sputter deposited with ceramic coatings of desired thickness. Coated foils along with uncoated foils were oxidized in furnace at 800oC for various periods of time and subsequently characterized using scanning electron microscopy (SEM). Area specific resistance (ASR) was measured using a DC technique. It was observed that coated foils were very effective in suppressing oxidation kinetics as compared to uncoated foils. Oxidation of coated foils exhibits linear behavior unlike uncoated foils which follows parabolic behavior.

Summary: Fe-Cr and Ni-Cr metal alloys have been widely used as interconnect materials in Solid Oxide Fuel Cells. However, due to high operating temperatures, these materials readily oxidize, forming chromium-containing oxide scale. This paper deals with fabrication and characterization of coatings, for interconnect materials, to slow down the oxidation kinetics.