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Monday, December 3, 2007 - 2:20 PM
9.2

Magnetic and Electric Properties Under High Magnetic Field in NiCoMnIn Metamagnetic Shape Memory Alloy

W. Ito, R. Y. Umetsu, K. Ito, K. Koyama, A. Fujita, K. Watanabe, R. Kainuma, K. Ishida, Tohoku University, Sendai, Japan

Recently, we reported that in the NiMnIn and NiMnSn based Heusler alloys, an unusual martensitic transformation from the ferromagnetic parent phase to the antiferromagnetic-like martensite phase occurs and magnetic field induced reverse martensitic transformation (MFIRT) is obtained in a magnetic field. In the present study, the martensitic transformation, magnetic and electrical resistivity (ER) properties under a large external magnetic field in the Ni45Co5Mn36.7In13.3 meta-magnetic shape memory alloy were investigated by extraction-type magnetometer with superconducting magnet, superconducting quantum interference device (SQUID) and conventional four-probe method. A drastic change of ER due to martensitic transformation was observed in the vicinity of 280 K under 0.05 T, 250 K under 3 T and 210 K under 5 T, which is consistent with the large magnetization change. The ER change under 0.05 T was extremely large over about 80 % ( = [r(200 K)-r(270 K)]/r(200 K)). A giant magnetoresistance (GMR) effect of about -80~90% was also confirmed accompanying the MFIRT. On the other hand, it was observed that the martensitic transformation always stops in the vicinity of 150 K even during the transformation, and that magnetic hysteresis, which was determined by magnetization and ER changes due to the large magnetic field, drastically increases with decreasing test temperature.

Summary: Recently, we reported that in the NiMnIn and NiMnSn based Heusler alloys, an unusual martensitic transformation from the ferromagnetic parent phase to the antiferromagnetic-like martensite phase occurs and magnetic field induced reverse martensitic transformation (MFIRT) is obtained in a magnetic field. In the present study, the martensitic transformation, magnetic and electrical resistivity (ER) properties under a large external magnetic field in the Ni45Co5Mn36.7In13.3 meta-magnetic shape memory alloy were investigated by extraction-type magnetometer with superconducting magnet, superconducting quantum interference device (SQUID) and conventional four-probe method. A drastic change of ER due to martensitic transformation was observed in the vicinity of 280 K under 0.05 T, 250 K under 3 T and 210 K under 5 T, which is consistent with the large magnetization change. The ER change under 0.05 T was extremely large over about 80 % ( = [ĉ(200 K)-ĉ(270 K)]/ĉ(200 K)). A giant magnetoresistance (GMR) effect of about -80~90% was also confirmed accompanying the MFIRT. On the other hand, it was observed that the martensitic transformation always stops in the vicinity of 150 K even during the transformation, and that magnetic hysteresis, which was determined by magnetization and ER changes due to the large magnetic field, drastically increases with decreasing test temperature.