Visco-Chemo-Rheological Behavior in High Tg Shape Memory Polymers
The purpose of this research is to study the chemo-rheological degradation of SMPs and its effects on the shape memory behavior and develop a design space to predict the useful operating range for particular applications. We present an experimental study of the degradation of the uniaxial thermo-mechanical behavior in a commercially available epoxy SMP, Veriflex-E (Tg~100°C), subjected to temperature conditions of 110-150°C. Extending the approach originated by Tobolsky, the effects of scission and recross-linking of the macromolecular network on the shape memory behavior is deduced by performing intermittent shape memory cycles during constant strain and intermittent stretch-relaxation experiments. The intermittent stretch-relaxation tests are also used to study the interpenetrative characteristics of visco-chemo-rheological behavior. These results are finally used to calibrate a constitutive model within a continuum multi-network framework to predict the evolution of behavior for general cyclic thermo-mechanical histories.